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References (12)
-
D. Powell, G. Fu (2004)
Nickel-catalyzed cross-couplings of organosilicon reagents with unactivated secondary alkyl bromides.Journal of the American Chemical Society, 126 25
-
J. Grobe, W. Hildebrandt, R. Martin, A. Walter (1991)
Alternativ‐Liganden. XXI. Neue Donor/Akzeptor‐Liganden Me2PCH2CH2SiFnMe3‐n, Me2PCH2CH2SiR(C6H4F)2 und (2‐Me2PC6H4)SiXMe2Zeitschrift für anorganische und allgemeine Chemie, 592
-
D. Cory, A. Wong, W. Ritchey (1982)
I. Additive relations in alkylhalosilanesJournal of Organometallic Chemistry, 235
-
N. Kano, F. Komatsu, M. Yamamura, T. Kawashima (2006)
Reversible photoswitching of the coordination numbers of silicon in organosilicon compounds bearing a 2-(phenylazo)phenyl group.Journal of the American Chemical Society, 128 21
-
A. Toshimitsu, T. Saeki, K. Tamao (2001)
Phosphonium sila-ylide: reaction pathway different from ammonium sila-ylide but similar to phosphonium ylide.Journal of the American Chemical Society, 123 37
-
F. Carré, R. Corriu, A. Kpoton, M. Poirier, G. Royo, J. Young, C. Belin (1994)
Pentacoordinate silicon compounds: Stereochemical non-rigidity of chelates formed by intramolecular ring-closure. Crystal structure of 8-dimethylamino-1-trifluorosilylnaphthaleneJournal of Organometallic Chemistry, 470
-
J. Foster, F. Weinhold (1980)
Natural hybrid orbitalsJournal of the American Chemical Society, 102
-
D. Stephan (2010)
Activation of dihydrogen by non-metal systems.Chemical communications, 46 45
-
D. Stephan, G. Erker (2010)
Frustrated Lewis pairs: metal-free hydrogen activation and more.Angewandte Chemie, 49 1
-
Tzu-Pin Lin, P. Gualco, Sonia Ladeira, Abderrahmane Amgoune, D. Bourissou, F. Gabbaï (2010)
Dative P→Sn interactions in ortho-phenylene phosphine-stannanesComptes Rendus Chimie, 13
-
K. Tamao, M. Asahara, T. Saeki, A. Toshimitsu (2000)
Enhanced nucleophilicity of ambiphilic silylene and silylenoid bearing 8-(dimethylamino)-1-naphthyl groupJournal of Organometallic Chemistry, 600
-
Omar Farooq (1998)
Nucleophilic fluorination of alkoxysilane with alkali metal salts of perfluorinated complex anions. 1a Part 2 1bJournal of The Chemical Society-perkin Transactions 1
- Publisher
- Wiley
- Copyright
- Copyright © 2012 Wiley Periodicals, Inc.
- ISSN
- 1042-7163
- eISSN
- 1098-1071
- DOI
- 10.1002/hc.21044
- Publisher site
- See Article on Publisher Site
Abstract
The synthesis and structure of 1‐diphenylphosphino‐2‐(fluorodiphenylsilyl) benzene 1 and 1‐diphenylphosphino‐2‐(difluorophenylsilyl)‐ benzene 2 are reported. An X‐ray crystal structure analysis of 1 shows a weak interaction between the silicon and phosphorus moieties, producing a hypervalent state at the silicon. The hypervalent state of the silicon is also supported by a natural bond orbital calculation. However, despite having a difluorosilyl group, 2 does not show a hypervalent state for the silicon, based on an X‐ray crystal structure analysis. © 2012 Wiley Periodicals, Inc. Heteroatom Chem 00:1–5, 2012; View this article online at wileyonlinelibrary.com. DOI 10.1002/hc.21044
Journal
Heteroatom Chemistry – Wiley
Published: Nov 1, 2012