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References (6)
-
H. Hirsch (1967)
Ein neues Verfahren zur Synthese von Aminalen und EnaminenChemische Berichte, 100
-
K. Seppelt, D. Lentz, H. Eysel (1978)
Oxidchloride des Arsen(V): AsOCl3 und (As2O3Cl4)nZeitschrift für anorganische und allgemeine Chemie, 439
-
M. Jansen (1976)
Na3NO3 — kein OrthonitritAngewandte Chemie, 88
-
John Donoghue, R. Drago (1963)
Non-aqueous Coördination Phenomena-Complexes of Hexamethyl-phosphoramide. II. Pseudo-tetrahedral Complexes of Nickel(II) and Cobalt(II)Inorganic Chemistry, 2
-
Z. Berkovitch-yellin, L. Leiserowitz (1984)
The Role Played by C-H...O and C-H-..N Interactions in Determining Molecular Packing and ConformationActa Crystallographica Section B-structural Science, 40
-
C. Wilkins, K. Hagen, L. Hedberg, Q. Shen, K. Hedberg (1975)
Electron diffraction investigation of the molecular structures of gaseous trimethylphosphine oxide, trimethylphosphine sulfide, trimethylarsine oxide, and trimethylarsine sulfideJournal of the American Chemical Society, 97
- Publisher
- Wiley
- Copyright
- Copyright © 1991 Wiley Subscription Services
- ISSN
- 1042-7163
- eISSN
- 1098-1071
- DOI
- 10.1002/hc.520020604
- Publisher site
- See Article on Publisher Site
Abstract
OAs(NMe2)3 (HMAsT) is obtained in low yields by reacting OAsCl3 with excess HNMe2 or by ozonolysis of As(NMe2)3; however, it is formed in yields >65% by using (Me3Si)2O2 and As(NMe2)3 in hydrocarbon solution. The structure of HMAsT was established by IR/Raman, NMR and mass spectroscopy, and single crystal X‐ray structure analysis. The structure determination revealed (sp3C)‐H…O–hydrogen bonding in the solid state. Acid‐base reaction by methanolysis affords ionic [Me2NH2] [O2As(OMe)2] while iodide is oxidized to iodine.
Journal
Heteroatom Chemistry – Wiley
Published: Jan 1, 1991