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- Publisher
- Wiley
- Copyright
- Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 2192-6506
- eISSN
- 2192-6506
- DOI
- 10.1002/cplu.201200085
- Publisher site
- See Article on Publisher Site
Abstract
Avoiding negative charge: Combined experimental and theoretical evidence shows that neutral, nine‐atom tin‐bismuth clusters adopt structures of closely related tin (poly)anions (see figure; Sn gray, Bi blue). These clusters exhibit similar bonding arrangements as known from Zintl ions. Hence, element substitution can be used to eliminate the negative charge without affecting the bonding or structural motif.
Journal
ChemPlusChem – Wiley
Published: Jul 1, 2012