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Nickel Complexes Modified by O,N,O’‐Ligands as Synthons for the Straightforward Synthesis of Highly Efficient Precatalysts for CC Bond Formation

Nickel Complexes Modified by O,N,O’‐Ligands as Synthons for the Straightforward Synthesis of... A nickel goes a long way: Nickel‐catalyzed cross coupling reactions of aryl halides with organometallic zinc reagents were examined. Excellent catalyst activity was obtained with nickel complexes modified by O,N,O′‐ligands. Interestingly, the activity could be easily boosted by in situ modification of the precatalyst with primary amines. dmap=4‐dimethylaminopyridine. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Asian Journal of Organic Chemistry Wiley

Nickel Complexes Modified by O,N,O’‐Ligands as Synthons for the Straightforward Synthesis of Highly Efficient Precatalysts for CC Bond Formation

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References (34)

Publisher
Wiley
Copyright
Copyright © 2012 Wiley Subscription Services, Inc., A Wiley Company
ISSN
2193-5807
eISSN
2193-5815
DOI
10.1002/ajoc.201200089
Publisher site
See Article on Publisher Site

Abstract

A nickel goes a long way: Nickel‐catalyzed cross coupling reactions of aryl halides with organometallic zinc reagents were examined. Excellent catalyst activity was obtained with nickel complexes modified by O,N,O′‐ligands. Interestingly, the activity could be easily boosted by in situ modification of the precatalyst with primary amines. dmap=4‐dimethylaminopyridine.

Journal

Asian Journal of Organic ChemistryWiley

Published: Dec 1, 2012

Keywords: ; ; ; ;

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