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Yicheng Zhao, Jiyun Zhang, Zhengwei Xu, Shijing Sun, S. Langner, N. Hartono, Thomas Heumueller, Yi Hou, J. Elia, Ning Li, G. Matt, Xiaoyang Du, Wei Meng, A. Osvet, Kaicheng Zhang, T. Stubhan, Yexin Feng, J. Hauch, E. Sargent, T. Buonassisi, C. Brabec (2021)
Discovery of temperature-induced stability reversal in perovskites using high-throughput robotic learningNature Communications, 12
Yang Bai, Xiangyue Meng, Shihe Yang (2018)
Interface Engineering for Highly Efficient and Stable Planar p‐i‐n Perovskite Solar CellsAdvanced Energy Materials, 8
Kevin Bush, Colin Bailie, Ye Chen, A. Bowring, Wei Wang, W. Ma, T. Leijtens, F. Moghadam, M. McGehee (2016)
Thermal and Environmental Stability of Semi‐Transparent Perovskite Solar Cells for Tandems Enabled by a Solution‐Processed Nanoparticle Buffer Layer and Sputtered ITO ElectrodeAdvanced Materials, 28
Seongrok Seo, Seonghwa Jeong, Changdeuck Bae, N. Park, Hyunjung Shin (2018)
Perovskite Solar Cells with Inorganic Electron‐ and Hole‐Transport Layers Exhibiting Long‐Term (≈500 h) Stability at 85 °C under Continuous 1 Sun Illumination in Ambient AirAdvanced Materials, 30
L. Wen, Y. Rao, Mingzhe Zhu, Ruitao Li, Jingbo Zhan, Linbao Zhang, Li Wang, Ming Li, S. Pang, Zhongmin Zhou (2021)
Reducing defects density and enhancing hole extraction for efficient perovskite solar cells enabled by π-Pb2+ interaction.Angewandte Chemie
Xiaodong Li, Wenxiao Zhang, Xuemin Guo, Chunyan Lu, Jiyao Wei, Junfeng Fang (2022)
Constructing heterojunctions by surface sulfidation for efficient inverted perovskite solar cellsScience, 375
Renxing Lin, K. Xiao, Zhengyuan Qin, Qiaolei Han, Chunfeng Zhang, Mingyang Wei, M. Saidaminov, Yuan Gao, Jun Xu, M. Xiao, Aidong Li, Jia Zhu, E. Sargent, H. Tan (2019)
Monolithic all-perovskite tandem solar cells with 24.8% efficiency exploiting comproportionation to suppress Sn(ii) oxidation in precursor inkNature Energy, 4
Jiabao Yang, Qipeng Cao, Ziwei He, Xingyu Pu, Tongtong Li, Bingyu Gao, Xuanhua Li (2021)
The poly(styrene-co-acrylonitrile) polymer assisted preparation of high-performance inverted perovskite solar cells with efficiency exceeding 22%Nano Energy, 82
Q. Han, Y. Hsieh, L. Meng, Jyh-Lih Wu, Pengyu Sun, E. Yao, Sheng-Yung Chang, Sang-Hoon Bae, T. Kato, V. Bermudez, Yang Yang (2018)
High-performance perovskite/Cu(In,Ga)Se2 monolithic tandem solar cellsScience, 361
Hao Chen, S. Teale, Bin Chen, Yi Hou, Luke Grater, Tong Zhu, Koen Bertens, So Park, H. Atapattu, Yajun Gao, Mingyang Wei, Andrew Johnston, Qilin Zhou, Kaimin Xu, Danni Yu, Congcong Han, Tengli Cui, E. Jung, Chun Zhou, Wenjia Zhou, Andrew Proppe, S. Hoogland, F. Laquai, T. Filleter, K. Graham, Zhijun Ning, E. Sargent (2022)
Quantum-size-tuned heterostructures enable efficient and stable inverted perovskite solar cellsNature Photonics, 16
Xilai He, Jiangzhao Chen, X. Ren, Lu Zhang, Yucheng Liu, Jiangshan Feng, Junjie Fang, K. Zhao, S. Liu (2021)
40.1% Record Low‐Light Solar‐Cell Efficiency by Holistic Trap‐Passivation using Micrometer‐Thick Perovskite FilmAdvanced Materials, 33
Deying Luo, Wenqiang Yang, Zhiping Wang, A. Sadhanala, Qin Hu, Rui Su, R. Shivanna, G. Trindade, J. Watts, Zhaojian Xu, Tanghao Liu, Ke Chen, Fengjun Ye, Pan Wu, Lichen Zhao, Jiang Wu, Yongguang Tu, Yifei Zhang, Xiaoyu Yang, Wei Zhang, R. Friend, Q. Gong, H. Snaith, Rui Zhu (2018)
Enhanced photovoltage for inverted planar heterojunction perovskite solar cellsScience, 360
Jiwei Liang, Xuzhi Hu, Chen Wang, Chao Liang, Cong Chen, Meng Xiao, Jiashuai Li, Chen Tao, Guichuan Xing, Rui Yu, Weijun Ke, G. Fang (2022)
Origins and influences of metallic lead in perovskite solar cellsJoule
Nengxu Li, S. Tao, Yihua Chen, Xiuxiu Niu, Chidozie Onwudinanti, Chen Hu, Zhiwen Qiu, Ziqi Xu, Guanhaojie Zheng, Ligang Wang, Yu Zhang, Liang Li, Huifen Liu, Y. Lun, Jiawang Hong, Xueyun Wang, Yuquan Liu, Haipeng Xie, Yongli Gao, Yang Bai, Shihe Yang, G. Brocks, Qi Chen, Huanping Zhou (2019)
Cation and anion immobilization through chemical bonding enhancement with fluorides for stable halide perovskite solar cellsNature Energy, 4
Ayan Zhumekenov, M. Saidaminov, Azimul Haque, E. Alarousu, S. Sarmah, B. Murali, I. Dursun, Xiaohe Miao, A. Abdelhady, Tom Wu, O. Mohammed, O. Bakr (2016)
Formamidinium Lead Halide Perovskite Crystals with Unprecedented Long Carrier Dynamics and Diffusion LengthACS energy letters, 1
M. Green (1982)
Accuracy of analytical expressions for solar cell fill factorsSolar Cells, 7
Qipeng Cao, Tong Wang, Jiabao Yang, Yixin Zhang, Yuke Li, Xingyu Pu, Junsong Zhao, Hui Chen, Xiaoqiang Li, Ilhom Tojiboyev, Jiangzhao Chen, L. Etgar, H. Salari, Xuanhua Li (2022)
Environmental‐Friendly Polymer for Efficient and Stable Inverted Perovskite Solar Cells with Mitigating Lead LeakageAdvanced Functional Materials, 32
Senyun Ye, Haixia Rao, Ziran Zhao, Lin-juan Zhang, Hong-liang Bao, Weihai Sun, Yunlong Li, Feidan Gu, Jianqiang Wang, Zhiwei Liu, Z. Bian, Chunhui Huang (2017)
A Breakthrough Efficiency of 19.9% Obtained in Inverted Perovskite Solar Cells by Using an Efficient Trap State Passivator Cu(thiourea)I.Journal of the American Chemical Society, 139 22
Shengfan Wu, Jie Zhang, Zhen Li, Danjun Liu, Minchao Qin, S. Cheung, Xinhui Lu, D. Lei, S. So, Zonglong Zhu, A. Jen (2020)
Modulation of Defects and Interfaces through Alkylammonium Interlayer for Efficient Inverted Perovskite Solar CellsJoule, 4
Tzu‐Sen Su, F. Eickemeyer, M. Hope, F. Jahanbakhshi, Marko Mladenović, Jun Li, Zhiwen Zhou, Aditya Mishra, Jun‐Ho Yum, Dan Ren, Anurag Krishna, O. Ouellette, Tzu‐Chien Wei, Hua Zhou, Hsin-Hsiang Huang, M. Mensi, K. Sivula, S. Zakeeruddin, Jovana Milić, A. Hagfeldt, U. Rothlisberger, L. Emsley, Hong Zhang, M. Grätzel (2020)
Crown Ether Modulation Enables over 23% Efficient Formamidinium-Based Perovskite Solar Cells.Journal of the American Chemical Society
Gwisu Kim, Hanul Min, K. Lee, Do Lee, Songhak Yoon, S. Seok (2020)
Impact of strain relaxation on performance of α-formamidinium lead iodide perovskite solar cellsScience, 370
Xinliang Fu, Tingwei He, Shifu Zhang, Xiaojuan Lei, Yuanzhi Jiang, Di Wang, Pingchuan Sun, Dongbing Zhao, Hsien‐Yi Hsu, Xiaofang Li, Mei Wang, Mingjian Yuan (2021)
Halogen-halogen bonds enable improved long-term operational stability of mixed-halide perovskite photovoltaicsChem
Qipeng Cao, Yongjiang Li, Hong Zhang, Jiabao Yang, Jian Han, Ting Xu, Shuangjie Wang, Zishuai Wang, Bingyu Gao, Junsong Zhao, Xiaoqiang Li, Xiaoyan Ma, S. Zakeeruddin, W. Sha, Xuanhua Li, M. Grätzel (2021)
Efficient and stable inverted perovskite solar cells with very high fill factors via incorporation of star-shaped polymerScience Advances, 7
Chunqing Ma, N. Park (2020)
A Realistic Methodology for 30% Efficient Perovskite Solar CellsChem
Randi Azmi, Naufan Nurrosyid, Sanghun Lee, Muhibullah Mubarok, Wooseop Lee, Sun-Na Hwang, Wenping Yin, T. Ahn, Tae-Wook Kim, D. Ryu, Y. Do, S. Jang (2020)
Shallow and Deep Trap State Passivation for Low-Temperature Processed Perovskite Solar CellsACS energy letters, 5
Zhen Li, Bo-Ting Li, Xin Wu, S. Sheppard, Shoufeng Zhang, Danpeng Gao, N. Long, Zonglong Zhu (2022)
Organometallic-functionalized interfaces for highly efficient inverted perovskite solar cellsScience, 376
Shangshang Chen, Xun Xiao, Hangyu Gu, Jinsong Huang (2021)
Iodine reduction for reproducible and high-performance perovskite solar cells and modulesScience Advances, 7
Lisa Krückemeier, Benedikt Krogmeier, Zhifa Liu, U. Rau, T. Kirchartz (2021)
Understanding Transient Photoluminescence in Halide Perovskite Layer Stacks and Solar CellsAdvanced Energy Materials, 11
Jia Yang, Cong Liu, Chunsheng Cai, Xiaotian Hu, Zengqi Huang, Xiaopeng Duan, Xiangchuan Meng, Zhongyi Yuan, L. Tan, Yiwang Chen (2019)
High‐Performance Perovskite Solar Cells with Excellent Humidity and Thermo‐Stability via Fluorinated PerylenediimideAdvanced Energy Materials, 9
Hisahiro Sasabe, T. Chiba, Shi-jian Su, Yong‐Jin Pu, K. Nakayama, J. Kido (2008)
2-Phenylpyrimidine skeleton-based electron-transport materials for extremely efficient green organic light-emitting devices.Chemical communications, 44
Dongtao Liu, Deying Luo, Affan Iqbal, Kieran Orr, T. Doherty, Zhenghong Lu, S. Stranks, Wei Zhang (2021)
Strain analysis and engineering in halide perovskite photovoltaicsNature Materials, 20
Jie Liu, Mingyu Hu, Zhenghong Dai, W. Que, N. Padture, Yuanyuan Zhou (2021)
Correlations between Electrochemical Ion Migration and Anomalous Device Behaviors in Perovskite Solar CellsACS energy letters, 6
Xiaopeng Zheng, Yi Hou, Chunxiong Bao, Jun Yin, Fanglong Yuan, Ziru Huang, Kepeng Song, Jiakai Liu, J. Troughton, N. Gasparini, Chun Zhou, Yuanbao Lin, D. Xue, Bin Chen, Andrew Johnston, N. Wei, M. Hedhili, Mingyang Wei, Abdullah Alsalloum, P. Maity, Bekir Turedi, Chen Yang, D. Baran, T. Anthopoulos, Yu Han, Zhenghong Lu, O. Mohammed, F. Gao, E. Sargent, O. Bakr (2020)
Managing grains and interfaces via ligand anchoring enables 22.3%-efficiency inverted perovskite solar cellsNature Energy, 5
D. Cruz, José Cerrillo, B. Kumru, Ning Li, J. Perea, B. Schmidt, I. Lauermann, C. Brabec, M. Antonietti (2019)
Influence of Thiazole-modified Carbon Nitride Nanosheets with Feasible Electronic Properties on Inverted Perovskite Solar Cells.Journal of the American Chemical Society
Chenxiao Zhou, A. Tarasov, E. Goodilin, Pengwan Chen, Hao Wang, Qi Chen (2022)
Recent strategies to improve moisture stability in metal halide perovskites materials and devicesJournal of Energy Chemistry, 65
Yulan Huang, Tanghao Liu, Bingzhe Wang, Jielei Li, Dongyang Li, Guoliang Wang, Qing Lian, Abbas Amini, Shi Chen, Chun Cheng, G. Xing (2021)
Antisolvent Engineering to Optimize Grain Crystallinity and Hole‐Blocking Capability of Perovskite Films for High‐Performance PhotovoltaicsAdvanced Materials, 33
Danni Yu, Yue Hu, Jiangjian Shi, Haoying Tang, Wenhao Zhang, Q. Meng, Hongwei Han, Zhijun Ning, H. Tian (2019)
Stability improvement under high efficiency—next stage development of perovskite solar cellsScience China Chemistry, 62
Xiwen Gong, Ziru Huang, Randy Sabatini, Chih-Shan Tan, Golam Bappi, G. Walters, Andrew Proppe, M. Saidaminov, O. Voznyy, S. Kelley, E. Sargent (2019)
Contactless measurements of photocarrier transport properties in perovskite single crystalsNature Communications, 10
Yi Hou, Erkan Aydin, M. Bastiani, C. Xiao, Furkan Isikgor, D. Xue, Bin Chen, Hao Chen, B. Bahrami, A. Chowdhury, Andrew Johnston, S. Baek, Ziru Huang, Mingyang Wei, Yitong Dong, J. Troughton, Rawan Jalmood, Alessandro Mirabelli, Thomas Allen, E. Kerschaver, M. Saidaminov, D. Baran, Q. Qiao, K. Zhu, S. Wolf, E. Sargent (2020)
Efficient tandem solar cells with solution-processed perovskite on textured crystalline siliconScience, 367
Elizabeth Lee, W. Tisdale (2015)
Determination of Exciton Diffusion Length by Transient Photoluminescence Quenching and Its Application to Quantum Dot FilmsJournal of Physical Chemistry C, 119
Kuiyuan Zhang, Yaxin Deng, Xiangrong Shi, Xin Li, Dianpeng Qi, B. Jiang, Yudong Huang (2021)
Interface chelation induced by pyridine-based polymer for efficient and durable air-processed perovskite solar cells.Angewandte Chemie
S. Habisreutinger, Nakita Noel, H. Snaith, R. Nicholas (2017)
Investigating the Role of 4‐Tert Butylpyridine in Perovskite Solar CellsAdvanced Energy Materials, 7
Because of the compatibility with tandem devices and the ability to be manufactured at low temperatures, inverted perovskite solar cells have generated far‐ranging interest for potential commercial applications. However, their efficiency remains inadequate owing to various traps in the perovskite film and the restricted hole blocking ability of the electron transport layer. Thus, in this work, a wide‐bandgap n‐type semiconductor, 4,6‐bis(3,5‐di(pyridin‐4‐yl)phenyl)‐2‐phenylpyrimidine (B4PyPPM), to modify a perovskite film via an anti‐solvent method is introduced. The nitrogen sites of pyrimidine and pyridine rings in B4PyPPM exhibit strong interactions with the undercoordinated lead ions in the perovskite material. These interactions can reduce the trap state densities and inhibit nonradiative recombination of the perovskite bulk. Moreover, B4PyPPM can partially aggregate on the perovskite surface, leading to an improvement in the hole‐blocking ability at its interface. This modification can also increase the built‐in potential and upshift the Fermi level of the modified perovskite film, promoting electron extraction to the electron transport layer. The champion device achieves a high efficiency of 23.51%. Meantime, the sealed device retains ≈80% of its initial performance under a maximum power point tracking for nearly 2400 h, demonstrating an excellent operational stability.
Advanced Energy Materials – Wiley
Published: Sep 1, 2022
Keywords: antisolvent engineering; conductive small molecules; high efficiency; inverted PSCs; operational stability
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