Access the full text.
Sign up today, get DeepDyve free for 14 days.
Suihan Cui, Yi Wei, Tongchao Liu, Wenjun Deng, Zongxiang Hu, Yantao Su, Hao Li, Maofan Li, H. Guo, Y. Duan, Weidong Wang, M. Rao, Jiaxin Zheng, Xinwei Wang, F. Pan (2016)
Optimized Temperature Effect of Li‐Ion Diffusion with Layer Distance in Li(NixMnyCoz)O2 Cathode Materials for High Performance Li‐Ion BatteryAdvanced Energy Materials, 6
Sung‐Kyun Jung, Hyeokjo Gwon, Jihyun Hong, Kyu‐Young Park, D. Seo, Haegyeom Kim, J. Hyun, Woo-young Yang, K. Kang (2014)
Understanding the Degradation Mechanisms of LiNi0.5Co0.2Mn0.3O2 Cathode Material in Lithium Ion BatteriesAdvanced Energy Materials, 4
C. Vaalma, D. Buchholz, M. Weil, S. Passerini (2018)
A cost and resource analysis of sodium-ion batteriesNature Reviews Materials, 3
A. Varzi, D. Bresser, Jan Zamory, F. Müller, S. Passerini (2014)
ZnFe2O4-C/LiFePO4-CNT: A Novel High-Power Lithium-Ion Battery with Excellent Cycling PerformanceAdvanced Energy Materials, 4
Guk‐Tae Kim, Sangsik Jeong, M. Joost, E. Rocca, M. Winter, S. Passerini, A. Balducci (2011)
Use of natural binders and ionic liquid electrolytes for greener and safer lithium-ion batteriesJournal of Power Sources, 196
T. Ohzuku, A. Ueda, M. Nagayama, Yasunobu Iwakoshi, H. Komori (1993)
Comparative study of LiCoO2, LiNi12Co12O2 and LiNiO2 for 4 volt secondary lithium cellsElectrochimica Acta, 38
Jie Li, Sangsik Jeong, Richard Kloepsch, M. Winter, S. Passerini (2013)
Improved electrochemical performance of LiMO2 (M=Mn, Ni, Co)–Li2MnO3 cathode materials in ionic liquid-based electrolyteJournal of Power Sources, 239
Williams Appiah, Joon-gi Park, Seonghyun Song, Seoungwoo Byun, Myung-Hyun Ryou, Y. Lee (2016)
Design optimization of LiNi 0.6 Co 0.2 Mn 0.2 O 2 /graphite lithium-ion cells based on simulation and experimental dataJournal of Power Sources, 319
D. Bresser, Kei Hosoi, D. Howell, Hong Li, Herbert Zeisel, K. Amine, S. Passerini (2018)
Perspectives of automotive battery R&D in China, Germany, Japan, and the USAJournal of Power Sources, 382
Yoojung Kim, Jaephil Cho (2007)
Lithium-Reactive Co3 ( PO4 ) 2 Nanoparticle Coating on High-Capacity LiNi0.8Co0.16Al0.04O2 Cathode Material for Lithium Rechargeable BatteriesJournal of The Electrochemical Society, 154
Zhen Chen, Dongliang Chao, Jilei Liu, M. Copley, Jianyi Lin, Zexiang Shen, Guk‐Tae Kim, S. Passerini (2017)
1D nanobar-like LiNi0.4Co0.2Mn0.4O2 as a stable cathode material for lithium-ion batteries with superior long-term capacity retention and high rate capabilityJournal of Materials Chemistry, 5
S. Menne, T. Vogl, A. Balducci (2015)
The synthesis and electrochemical characterization of bis(fluorosulfonyl)imide-based protic ionic liquids.Chemical communications, 51 17
G. Elia, Ulderico Ulissi, Sangsik Jeong, S. Passerini, J. Hassoun (2016)
Exceptional long-life performance of lithium-ion batteries using ionic liquid-based electrolytesEnergy and Environmental Science, 9
M. Dixit, M. Kosa, Onit Lavi, B. Markovsky, D. Aurbach, D. Major (2016)
Thermodynamic and kinetic studies of LiNi0.5Co0.2Mn0.3O2 as a positive electrode material for Li-ion batteries using first principles.Physical chemistry chemical physics : PCCP, 18 9
Woosuk Cho, Sang-Min Kim, Ko-woon Lee, J. Song, Y. Jo, Taeeun Yim, Hyuntae Kim, Jeom‐Soo Kim, Young‐Jun Kim (2016)
Investigation of new manganese orthophosphate Mn3(PO4)2 coating for nickel-rich LiNi0.6Co0.2Mn0.2O2 cathode and improvement of its thermal propertiesElectrochimica Acta, 198
Lingjun Li, Lingjun Li, Zhaoyong Chen, Qiaobao Zhang, Ming Xu, Xiaoping Zhou, Huali Zhu, Kaili Zhang (2015)
A hydrolysis-hydrothermal route for the synthesis of ultrathin LiAlO2-inlaid LiNi0.5Co0.2Mn0.3O2 as a high-performance cathode material for lithium ion batteriesJournal of Materials Chemistry, 3
Joon-Gon Lee, Taegon Kim, Byungwoo Park (2007)
Metal-phosphate coating on LiCoO2 cathodes with high cutoff voltagesMaterials Research Bulletin, 42
A. Balducci, Sangsik Jeong, G. Kim, S. Passerini, M. Winter, M. Schmuck, G. Appetecchi, R. Marcilla, D. Mecerreyes, V. Barsukov, V. Khomenko, I. Cantero, I. Meatza, M. Holzapfel, Nguyet Tran (2011)
Development of safe, green and high performance ionic liquids-based batteries (ILLIBATT project)The Lancet
D. Uzun, Mehbare Dogrusoz, Muhsin Mazman, Emre Biçer, E. Avci, T. Şener, T. Kaypmaz, Rezan Demir‐Cakan (2013)
Effect of MnO2 coating on layered Li(Li0.1Ni0.3Mn0.5Fe0.1)O2 cathode material for Li-ion batteriesSolid State Ionics, 249
T. Ohzuku, Y. Makimura (2001)
Layered Lithium Insertion Material of LiCo1/3Ni1/3Mn1/3O2 for Lithium-Ion BatteriesChemistry Letters, 30
Jaephil Cho, Hyemin Kim, Byungwoo Park (2004)
Comparison of Overcharge Behavior of AlPO4-Coated LiCoO2 and LiNi0.8Co0.1Mn0.1 O 2 Cathode Materials in Li-Ion CellsJournal of The Electrochemical Society, 151
Guo-rong Hu, Xin Deng, Zhongdong Peng, K. Du (2008)
Comparison of AlPO4- and Co3(PO4)2-coated LiNi0.8Co0.2O2 cathode materials for Li-ion batteryElectrochimica Acta, 53
Yang‐Kook Sun, Dong-Hui Kim, C. Yoon, Seung‐Taek Myung, J. Prakash, K. Amine (2010)
A Novel Cathode Material with a Concentration‐Gradient for High‐Energy and Safe Lithium‐Ion BatteriesAdvanced Functional Materials, 20
Shan Yang, B. Yan, Jiaxiong Wu, Li Lu, K. Zeng (2017)
Temperature-Dependent Lithium-Ion Diffusion and Activation Energy of Li1.2Co0.13Ni0.13Mn0.54O2 Thin-Film Cathode at Nanoscale by Using Electrochemical Strain Microscopy.ACS applied materials & interfaces, 9 16
Hyunjung Lee, Min Kim, Jaephil Cho (2007)
Olivine LiCoPO4 phase grown LiCoO2 cathode material for high density Li batteriesElectrochemistry Communications, 9
Jaephil Cho, Tae-Joon Kim, Jisuk Kim, Mijung Noh, Byungwoo Park (2004)
Synthesis, Thermal, and Electrochemical Properties of AlPO4-Coated LiNi0.8Co0.1Mn0.1 O 2 Cathode Materials for a Li-Ion CellJournal of The Electrochemical Society, 151
Yan Huang, F. Jin, Fang-Jie Chen, Li Chen (2014)
Improved cycle stability and high-rate capability of Li3VO4-coated Li[Ni0.5Co0.2Mn0.3]O2 cathode material under different voltagesJournal of Power Sources, 256
D. Mohanty, Kevin Dahlberg, D. King, L. David, A. Sefat, D. Wood, Claus Daniel, S. Dhar, V. Mahajan, Myongjai Lee, F. Albano (2016)
Modification of Ni-Rich FCG NMC and NCA Cathodes by Atomic Layer Deposition: Preventing Surface Phase Transitions for High-Voltage Lithium-Ion BatteriesScientific Reports, 6
D. Aurbach, B. Markovsky, G. Salitra, E. Markevich, Yossi Talyossef, Maxim Koltypin, L. Nazar, B. Ellis, D. Kovacheva (2007)
Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteriesJournal of Power Sources, 165
Jicheng Zhang, Zheng-Yao Li, Rui Gao, Zhong-bo Hu, Xiangfeng Liu (2015)
High Rate Capability and Excellent Thermal Stability of Li+-Conductive Li2ZrO3-Coated LiNi1/3Co1/3Mn1/3O2 via a Synchronous Lithiation StrategyJournal of Physical Chemistry C, 119
Dong-Qiang Liu, Ze-Zhen He, Xingquan Liu (2007)
Increased cycling stability of AlPO4-coated LiMn2O4 for lithium ion batteriesMaterials Letters, 61
J. Ngala, Natasha Chernova, Miaomiao Ma, M. Mamak, P. Zavalij, M. Whittingham (2004)
The synthesis, characterization and electrochemical behavior of the layered LiNi0.4Mn0.4Co0.2O2 compoundJournal of Materials Chemistry, 14
Jingfa Li, S. Xiong, Yurong Liu, Zhicheng Ju, Yitai Qian (2013)
Uniform LiNi1/3Co1/3Mn1/3O2 hollow microspheres: Designed synthesis, topotactical structural transformation and their enhanced electrochemical performanceNano Energy, 2
K. Ryu, Sang Lee, B. Koo, Ju Lee, Kwang Kim, Y. Park (2008)
Effects of Co3(PO4)2 coatings on LiNi0.8Co0.16Al0.04O2 cathodes during application of high currentJournal of Applied Electrochemistry, 38
G. Kim, Y. Park (2013)
Enhanced electrochemical and thermal properties of Sm2O3 coated Li[Li1/6Mn1/2Ni1/6Co1/6]O2 for Li-ion batteriesJournal of Electroceramics, 31
Xianzhong Sun, Xiong Zhang, B. Huang, Haitao Zhang, Dacheng Zhang, Yanwei Ma (2013)
(LiNi0.5Co0.2Mn0.3O2 + AC)/graphite hybrid energy storage device with high specific energy and high rate capabilityJournal of Power Sources, 243
Electrochem
Jizhou Kong, C. Ren, G. Tai, Xiang Zhang, Aidong Li, Di Wu, Hui Li, Fei Zhou (2014)
Ultrathin ZnO coating for improved electrochemical performance of LiNi0.5Co0.2Mn0.3O2 cathode materialJournal of Power Sources, 266
Seung‐Taek Myung, Ki-Soo Lee, C. Yoon, Yang‐Kook Sun, K. Amine, H. Yashiro (2010)
Effect of AlF3 Coating on Thermal Behavior of Chemically Delithiated Li0.35[Ni1/3Co1/3Mn1/3]O2Journal of Physical Chemistry C, 114
Wei Wang, D. Choi, Z. Yang (2012)
Li-Ion Battery with LiFePO4 Cathode and Li4Ti5O12 Anode for Stationary Energy StorageMetallurgical and Materials Transactions A, 44
Xueliang Liu, Lizhong Kou, Ting Shi, Kun Liu, Li Chen (2014)
Excellent high rate capability and high voltage cycling stability of Y2O3-coated LiNi0.5Co0.2Mn0.3O2Journal of Power Sources, 267
Zhen Chen, Guk‐Tae Kim, Dongliang Chao, Nicholas Loeffler, M. Copley, Jianyi Lin, Zexiang Shen, S. Passerini (2017)
Toward greener lithium-ion batteries: Aqueous binder-based LiNi0.4Co0.2Mn0.4O2 cathode material with superior electrochemical performanceJournal of Power Sources, 372
Xiaowei Miao, Huan Ni, Han Zhang, Chunguang Wang, Jian-hui Fang, Gang Yang (2014)
Li2ZrO3-coated 0.4Li2MnO3·0.6LiNi1/3Co1/3Mn1/3O2 for high performance cathode material in lithium-ion batteryJournal of Power Sources, 264
Xiuli Su, Jingyuan Liu, Congcong Zhang, Tao Huang, Yonggang Wang, A. Yu (2016)
High power lithium-ion battery based on a LiMn2O4 nanorod cathode and a carbon-coated Li4Ti5O12 nanowire anodeRSC Advances, 6
Zheng Li, C. Ban, Natasha Chernova, Zhuangchun Wu, S. Upreti, A. Dillon, M. Whittingham (2014)
Towards understanding the rate capability of layered transition metal oxides LiNiyMnyCo1−2yO2Journal of Power Sources, 268
Rosamaría Fong, U. Sacken, J. Dahn (1990)
Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical CellsJournal of The Electrochemical Society, 137
K. Tan, M. Reddy, G. Rao, B. Chowdari (2005)
Effect of AlPO4-coating on cathodic behaviour of Li(Ni0.8Co0.2)O2Journal of Power Sources, 141
J. Gim, Jinju Song, Sungjin Kim, Jeonggeun Jo, Seokhun Kim, Jaegu Yoon, Donghan Kim, Suk-Gi Hong, Jinhwan Park, V. Mathew, Junhee Han, Sun-Ju Song, Jaekook Kim (2016)
An in-situ gas chromatography investigation into the suppression of oxygen gas evolution by coated amorphous cobalt-phosphate nanoparticles on oxide electrodeScientific Reports, 6
Dong-Ju Lee, B. Scrosati, Yang‐Kook Sun (2011)
Ni3(PO4)2-coated Li[Ni0.8Co0.15Al0.05]O2 lithium battery electrode with improved cycling performance at 55 °CJournal of Power Sources, 196
Zhen Chen, Dongliang Chao, Jianyi Lin, Zexiang Shen (2017)
Recent progress in surface coating of layered LiNixCoyMnzO2 for lithium-ion batteriesMaterials Research Bulletin, 96
Zhen Chen, Jin Wang, Dongliang Chao, T. Baikie, Linyi Bai, Shi Chen, Yanli Zhao, T. Sum, Jianyi Lin, Zexiang Shen (2016)
Hierarchical Porous LiNi1/3Co1/3Mn1/3O2 Nano-/Micro Spherical Cathode Material: Minimized Cation Mixing and Improved Li+ Mobility for Enhanced Electrochemical PerformanceScientific Reports, 6
S. Shi, J. Tu, Yu Tang, Yongqi Zhang, X. Liu, X. Wang, C. Gu (2013)
Enhanced electrochemical performance of LiF-modified LiNi1/3Co1/3Mn1/3O2 cathode materials for Li-ion batteriesJournal of Power Sources, 225
Peng Yue, Zhixing Wang, W. Peng, Lingjun Li, Wei Chen, Huajun Guo, Xinhai Li (2011)
Spray-drying synthesized LiNi0.6Co0.2Mn0.2O2 and its electrochemical performance as cathode materials for lithium ion batteriesPowder Technology, 214
J. Vetter, P. Novák, M. Wagner, C. Veit, K. Möller, J. Besenhard, M. Winter, M. Wohlfahrt‐Mehrens, C. Vogler, A. Hammouche (2005)
Ageing mechanisms in lithium-ion batteriesJournal of Power Sources, 147
Q. Qiu, Xi Huang, Yanmei Chen, Tan Yan, Weizhong Lv (2014)
Al2O3 coated LiNi1/3Co1/3Mn1/3O2 cathode material by sol–gel method: Preparation and characterizationCeramics International, 40
Xiaoyu Liu, Jali Liu, Tao Huang, A. Yu (2013)
CaF2-coated Li1.2Mn0.54Ni0.13Co0.13O2 as cathode materials for Li-ion batteriesElectrochimica Acta, 109
J. Shi, Cheol-Woo Yi, Keon Kim (2010)
Improved electrochemical performance of AlPO4-coated LiMn1.5Ni0.5O4 electrode for lithium-ion batteriesJournal of Power Sources, 195
Bo Xu, Danna Qian, Ziying Wang, Y. Meng (2012)
Recent progress in cathode materials research for advanced lithium ion batteriesMaterials Science & Engineering R-reports, 73
S. Sivakkumar, Jawahar Nerkar, A. Pandolfo (2010)
Rate capability of graphite materials as negative electrodes in lithium-ion capacitorsElectrochimica Acta, 55
Jili Li, C. Cao, Xingyan Xu, Youqi Zhu, Ruimin Yao (2013)
LiNi1/3Co1/3Mn1/3O2 hollow nano-micro hierarchical microspheres with enhanced performances as cathodes for lithium-ion batteriesJournal of Materials Chemistry, 1
Herein, the successful synthesis of MnPO4‐coated LiNi0.4Co0.2Mn0.4O2 (MP‐NCM) as a lithium battery cathode material is reported. The MnPO4 coating acts as an ideal protective layer, physically preventing the contact between the NCM active material and the electrolyte and, thus, stabilizing the electrode/electrolyte interface and preventing detrimental side reactions. Additionally, the coating enhances the lithium de‐/intercalation kinetics in terms of the apparent lithium‐ion diffusion coefficient. As a result, MP‐NCM‐based electrodes reveal greatly enhanced C‐rate capability and cycling stability—even under exertive conditions like extended operational potential windows, elevated temperature, and higher active material mass loadings. This superior electrochemical behavior of MP‐NCM compared to as‐synthesized NCM is attributed to the superior stability of the electrode/electrolyte interface and structural integrity when applying a MnPO4 coating. Employing an ionic liquid as an alternative, intrinsically safer electrolyte system allows for outstanding cycling stabilities in a lithium‐metal battery configuration with a capacity retention of well above 85% after 2000 cycles. Similarly, the implementation in a lithium‐ion cell including a graphite anode provides stable cycling for more than 2000 cycles and an energy and power density of, respectively, 376 Wh kg−1 and 1841 W kg−1 on the active material level.
Advanced Energy Materials – Wiley
Published: Jan 1, 2018
Keywords: ; ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.