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References (5)
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Shengyu Feng, D. Feng, C. Deng (1993)
Theoretical studies on the structures and reactivity of silylenoids. III. The structures and isomerization of silylenoid H2SiNaFChemical Physics Letters, 214
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K. Dobbs, W. Hehre (1986)
Molecular orbital theory of the properties of inorganic and organometallic compounds 4. Extended basis sets for third‐and fourth‐row, main‐group elementsJournal of Computational Chemistry, 7
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M. Gordon, J. Binkley, J. Pople, W. Pietro, W. Hehre (1980)
Self-consistent molecular-orbital methods. 22. Small split-valence basis sets for second-row elementsJournal of the American Chemical Society, 102
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O. Nefedow, M. Manakow (1964)
Entstehung und Reaktionen des Dimethylsilylens, eines Siliciumanalogons der CarbeneAngewandte Chemie, 76
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T. Clark, P. Schleyer (1980)
The isomeric structures of SiH2LiFJournal of Organometallic Chemistry, 191
- Publisher
- Wiley
- Copyright
- Copyright © 1995 Wiley Subscription Services, Inc., A Wiley Company
- ISSN
- 1001-604X
- eISSN
- 1614-7065
- DOI
- 10.1002/cjoc.19950130602
- Publisher site
- See Article on Publisher Site
Abstract
The isomeric structures, isomerization and decomposition of silylenoids H2SiMX (MXKF, KC1, LiBr, NaBr and KBr) have been investigated by ab initio molecular orbital theory. These silylenoids have four kinds of very similar equilibrium structures. The three‐membered ring and p‐complex structures should be stable and experimentally detectable. The lifetime of σ‐complex and tetrahedral structures would be very short and experimentally undetectable.
Journal
Chinese Journal of Chemistry – Wiley
Published: Nov 1, 1995
Keywords: ; ; ;