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- Publisher
- Wiley
- Copyright
- © 2021 SIOC, CAS, Shanghai, & WILEY‐VCH GmbH
- ISSN
- 1001-604X
- eISSN
- 1614-7065
- DOI
- 10.1002/cjoc.202100005
- Publisher site
- See Article on Publisher Site
Abstract
A redox‐neutral Fe‐catalyzed intramolecular C—H amidation of N‐benzoyloxyureas is described. This methodology employs a simple iron complex in situ generated from Fe(OTf)2 and bipyridine as the catalyst and N‐benzoyloxyureas as the nitrene precursors without using exogenous oxidants. An array of cyclic ureas were synthesized via aliphatic C(sp3)—H amidation in excellent yields. In addition, this catalytic system is also amenable to aryl C(sp2)—H nitrene insertion to provide benzimidazolones in moderate yields.
Journal
Chinese Journal of Chemistry – Wiley
Published: Apr 1, 2021
Keywords: ; ; ; ;