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Iron‐Catalyzed Anti‐Markovnikov Hydroamination of Vinylpyridines

Iron‐Catalyzed Anti‐Markovnikov Hydroamination of Vinylpyridines An efficient, green and atom‐economical iron‐catalyzed hydroamination of vinylpyridines with azoles has been developed. This reaction works smoothly for a diverse range of vinylpyridines and azoles, including diazoles and triazoles. The reaction was catalyzed by 5 mol % FeCl3 in toluene at 110 °C for 3 h to afford the anti‐Markovnikov hydroamination products in moderate to excellent yields and excellent selectivities. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Asian Journal of Organic Chemistry Wiley

Iron‐Catalyzed Anti‐Markovnikov Hydroamination of Vinylpyridines

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References (29)

Publisher
Wiley
Copyright
© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2193-5807
eISSN
2193-5815
DOI
10.1002/ajoc.201700072
Publisher site
See Article on Publisher Site

Abstract

An efficient, green and atom‐economical iron‐catalyzed hydroamination of vinylpyridines with azoles has been developed. This reaction works smoothly for a diverse range of vinylpyridines and azoles, including diazoles and triazoles. The reaction was catalyzed by 5 mol % FeCl3 in toluene at 110 °C for 3 h to afford the anti‐Markovnikov hydroamination products in moderate to excellent yields and excellent selectivities.

Journal

Asian Journal of Organic ChemistryWiley

Published: Jun 1, 2017

Keywords: ; ; ; ;

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