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Open up: An (Ir(COD)Cl)2/ (S)‐NMDPP (COD=1,5‐cyclooctadiene; NMDPP=neomenthyldiphenylphosphine) complex catalyzes asymmetric ring‐opening reactions of oxabenzonorbornadienes with phenolic or naphtholic nucleophiles efficiently. Up to 96 % yield and 88 % ee was achieved. DMF=N,N‐dimethylformamide.
Asian Journal of Organic Chemistry – Wiley
Published: Jun 1, 2013
Keywords: ; ; ; ;
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