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Hydrolysis‐Initiated Domino Process on the Rim of Open‐Cage C60 Derivatives Including Decarbonylation and Double Dehydration

Hydrolysis‐Initiated Domino Process on the Rim of Open‐Cage C60 Derivatives Including... Hydrolysis of an open‐cage C60 derivative in a mixture of HCl/AcOH/H2O resulted in removal of two hydroxyl groups, one carbonyl group and one aniline group in one step. A domino mechanism is proposed for the process. The newly formed open‐cage C60 derivative has three carbonyl groups on the rim of the orifice, one of which could be converted into an oxime group by treatment with hydroxylamine. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png ChemPlusChem Wiley

Hydrolysis‐Initiated Domino Process on the Rim of Open‐Cage C60 Derivatives Including Decarbonylation and Double Dehydration

ChemPlusChem , Volume 82 (7) – Aug 1, 2017

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References (13)

Publisher
Wiley
Copyright
© 2017 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2192-6506
eISSN
2192-6506
DOI
10.1002/cplu.201700198
Publisher site
See Article on Publisher Site

Abstract

Hydrolysis of an open‐cage C60 derivative in a mixture of HCl/AcOH/H2O resulted in removal of two hydroxyl groups, one carbonyl group and one aniline group in one step. A domino mechanism is proposed for the process. The newly formed open‐cage C60 derivative has three carbonyl groups on the rim of the orifice, one of which could be converted into an oxime group by treatment with hydroxylamine.

Journal

ChemPlusChemWiley

Published: Aug 1, 2017

Keywords: ; ;

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