Access the full text.
Sign up today, get DeepDyve free for 14 days.
Xiulei Ji, Kyu Lee, R. Holden, Lei Zhang, Jiujun Zhang, G. Botton, M. Couillard, L. Nazar (2010)
Nanocrystalline intermetallics on mesoporous carbon for direct formic acid fuel cell anodes.Nature chemistry, 2 4
H. Ogasawara, Masatoki Ito (1994)
Hydrogen adsorption on Pt(100), Pt(110), Pt(111) and Pt(1111) electrode surfaces studied by in situ infrared reflection absorption spectroscopyChemical Physics Letters, 221
R. Kamai, K. Kamiya, K. Hashimoto, Shuji Nakanishi (2016)
Oxygen-Tolerant Electrodes with Platinum-Loaded Covalent Triazine Frameworks for the Hydrogen Oxidation Reaction.Angewandte Chemie, 55 42
Xiaofeng Yang, Aiqin Wang, B. Qiao, Jun Li, J. Liu, Tao Zhang (2013)
Single-atom catalysts: a new frontier in heterogeneous catalysis.Accounts of chemical research, 46 8
Sungeun Yang, Hyunjoon Lee (2013)
Atomically Dispersed Platinum on Gold Nano-Octahedra with High Catalytic Activity on Formic Acid OxidationACS Catalysis, 3
F. Lucci, Jilei Liu, Matthew Marcinkowski, Ming Yang, L. Allard, M. Flytzani-Stephanopoulos, E. Sykes (2015)
Selective hydrogenation of 1,3-butadiene on platinum–copper alloys at the single-atom limitNature Communications, 6
Sungeun Yang, Jiwhan Kim, Y. Tak, Aloysius Soon, Hyunjoon Lee (2016)
Single-Atom Catalyst of Platinum Supported on Titanium Nitride for Selective Electrochemical Reactions.Angewandte Chemie, 55 6
J. Liu, S. Duan, Jia Xu, B. Qiao, Yang Lou (2016)
Catalysis by Supported Single Metal AtomsMicroscopy and Microanalysis, 22
Jilei Liu, F. Lucci, Ming Yang, Sungsik Lee, Matthew Marcinkowski, A. Therrien, Christopher Williams, E. Sykes, M. Flytzani-Stephanopoulos (2016)
Tackling CO Poisoning with Single-Atom Alloy Catalysts.Journal of the American Chemical Society, 138 20
Sang-Il Choi, J. Herron, J. Scaranto, Hongwen Huang, Yi Wang, Xiaohu Xia, Tian Lv, Jinho Park, Hsin‐Chieh Peng, M. Mavrikakis, Younan Xia (2015)
A Comprehensive Study of Formic Acid Oxidation on Palladium Nanocrystals with Different Types of Facets and Twin DefectsChemCatChem, 7
Sungeun Yang, Y. Tak, Jiwhan Kim, Aloysius Soon, Hyunjoo Lee (2017)
Support Effects in Single-Atom Platinum Catalysts for Electrochemical Oxygen ReductionACS Catalysis, 7
B. Qiao, Aiqin Wang, Xiaofeng Yang, L. Allard, Zheng Jiang, Yitao Cui, J. Liu, Jun Li, Tao Zhang (2011)
Single-atom catalysis of CO oxidation using Pt1/FeOx.Nature chemistry, 3 8
Y. Zhai, D. Pierre, R. Si, Wei Deng, P. Ferrin, A. Nilekar, G. Peng, J. Herron, D. Bell, H. Saltsburg, M. Mavrikakis, M. Flytzani-Stephanopoulos (2010)
Alkali-Stabilized Pt-OHx Species Catalyze Low-Temperature Water-Gas Shift ReactionsScience, 329
Xiaoteng Liu, Kui Zhang, Jianwei Lu, K. Luo, Jinlong Gong, V. Puthiyapura, K. Scott (2015)
Determining the Effect of Plasma Pre‐Treatment on Antimony Tin Oxide to Support Pt@Pd and the Oxygen Reduction Reaction ActivityChemCatChem, 7
Shuhui Sun, Gaixia Zhang, N. Gauquelin, N. Chen, Jigang Zhou, Songlan Yang, Weifeng Chen, Xiangbo Meng, D. Geng, M. Banis, Ruying Li, S. Ye, S. Knights, G. Botton, T. Sham, X. Sun (2013)
Single-atom Catalysis Using Pt/Graphene Achieved through Atomic Layer DepositionScientific Reports, 3
S. Uhm, H. Lee, Youngkook Kwon, Jaeyoung Lee (2008)
A stable and cost-effective anode catalyst structure for formic acid fuel cells.Angewandte Chemie, 47 52
N. Kristian, Yaolun Yu, Poernomo Gunawan, R. Xu, Weiqiao Deng, Xue‐Wei Liu, Xin Wang (2009)
Controlled synthesis of Pt-decorated Au nanostructure and its promoted activity toward formic acid electro-oxidationElectrochimica Acta, 54
Á. Cuesta, M. Escudero, B. Lanova, H. Baltruschat (2009)
Cyclic voltammetry, FTIRS, and DEMS study of the electrooxidation of carbon monoxide, formic acid, and methanol on cyanide-modified Pt(111) electrodes.Langmuir : the ACS journal of surfaces and colloids, 25 11
M. Yin, Junyuan Xu, Qingfeng Li, J. Jensen, Yunjie Huang, L. Cleemann, N. Bjerrum, W. Xing (2014)
Highly active and stable Pt electrocatalysts promoted by antimony-doped SnO2 supports for oxygen reduction reactionsApplied Catalysis B-environmental, 144
E. Peterson, A. DeLaRiva, Sen Lin, Ryan Johnson, Hua Guo, Jeffrey Miller, Ja Kwak, C. Peden, B. Kiefer, L. Allard, F. Ribeiro, A. Datye (2014)
Low-temperature carbon monoxide oxidation catalysed by regenerable atomically dispersed palladium on aluminaNature Communications, 5
Matthew Boucher, B. Zugic, George Cladaras, James Kammert, Matthew Marcinkowski, T. Lawton, E. Sykes, M. Flytzani-Stephanopoulos (2013)
Single atom alloy surface analogs in Pd0.18Cu15 nanoparticles for selective hydrogenation reactions.Physical chemistry chemical physics : PCCP, 15 29
G. Kyriakou, Matthew Boucher, A. Jewell, E. Lewis, T. Lawton, A. Baber, Heather Tierney, M. Flytzani-Stephanopoulos, E. Sykes (2012)
Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous HydrogenationsScience, 335
D.‐F. Zhang, L. Sun, Jialu Yin, C. Yan (2003)
Low‐Temperature Fabrication of Highly Crystalline SnO2 NanorodsAdvanced Materials, 15
A. Bruix, Y. Lykhach, I. Matolínová, A. Neitzel, T. Skála, N. Tsud, M. Vorokhta, V. Stetsovych, K. Ševčíková, J. Mysliveček, R. Fiala, M. Václavů, K. Prince, S. Bruyère, V. Potin, F. Illas, V. Matolín, J. Libuda, Konstantin Neyman (2014)
Maximum noble-metal efficiency in catalytic materials: atomically dispersed surface platinum.Angewandte Chemie, 53 39
C. Choi, Minho Kim, H. Kwon, S. Cho, Seongho Yun, Heebong Kim, K. Mayrhofer, Hyungjun Kim, Minkee Choi (2016)
Tuning selectivity of electrochemical reactions by atomically dispersed platinum catalystNature Communications, 7
Xingwen Yu, P. Pickup (2008)
Recent advances in direct formic acid fuel cells (DFAFC)Journal of Power Sources, 182
S. Zhang, Yuyan Shao, Geping Yin, Yuehe Lin (2010)
Electrostatic self-assembly of a Pt-around-Au nanocomposite with high activity towards formic acid oxidation.Angewandte Chemie, 49 12
B. Peng, Jin-yi Wang, H. Zhang, Yanghui Lin, W. Cai (2009)
A versatile electroless approach to controlled modification of Sb on Pt surfaces towards efficient electrocatalysis of formic acidElectrochemistry Communications, 11
B. Peng, Hui-Fang Wang, Zhipan Liu, W. Cai (2010)
Combined Surface-Enhanced Infrared Spectroscopy and First-Principles Study on Electro-Oxidation of Formic Acid at Sb-Modified Pt ElectrodesJournal of Physical Chemistry C, 114
Jin-Yeon Lee, Da-hee Kwak, Young-Woo Lee, Seul Lee, Kyung‐Won Park (2015)
Synthesis of cubic PtPd alloy nanoparticles as anode electrocatalysts for methanol and formic acid oxidation reactions.Physical chemistry chemical physics : PCCP, 17 14
M. Neurock, M. Janik, A. Wiȩckowski (2008)
A first principles comparison of the mechanism and site requirements for the electrocatalytic oxidation of methanol and formic acid over Pt.Faraday discussions, 140
Guangxian Pei, Xiaoyan Liu, Aiqin Wang, A. Lee, M. Isaacs, Lin Li, Xiaoli Pan, Xiaofeng Yang, Xiaodong Wang, Zhijun Tai, K. Wilson, Zhang Tao (2015)
Ag Alloyed Pd Single-Atom Catalysts for Efficient Selective Hydrogenation of Acetylene to Ethylene in Excess EthyleneACS Catalysis, 5
Jing Lu, C. Aydin, N. Browning, B. Gates (2012)
Imaging isolated gold atom catalytic sites in zeolite NaY.Angewandte Chemie, 51 24
Joseph Kistler, N. Chotigkrai, P. Xu, Bryan Enderle, P. Praserthdam, Cong-yan Chen, N. Browning, B. Gates (2014)
A single-site platinum CO oxidation catalyst in zeolite KLTL: microscopic and spectroscopic determination of the locations of the platinum atoms.Angewandte Chemie, 53 34
Haisheng Wei, Xiaoyan Liu, Aiqin Wang, Leilei Zhang, B. Qiao, Xiaofeng Yang, Yanqiang Huang, S. Miao, J. Liu, Tao Zhang (2014)
FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenesNature Communications, 5
J. Bauer, Xiaole Chen, Qingsheng Liu, T. Phan, R. Schaak (2008)
Converting nanocrystalline metals into alloys and intermetallic compounds for applications in catalysisJournal of Materials Chemistry, 18
F. Lucci, Matthew Marcinkowski, T. Lawton, E. Sykes (2015)
H2 Activation and Spillover on Catalytically Relevant Pt–Cu Single Atom AlloysJournal of Physical Chemistry C, 119
Leilei Zhang, Aiqin Wang, Jeffrey Miller, Xiaoyan Liu, Xiaofeng Yang, Wentao Wang, Lin Li, Yanqiang Huang, C. Mou, Tao Zhang (2014)
Efficient and Durable Au Alloyed Pd Single-Atom Catalyst for the Ullmann Reaction of Aryl Chlorides in WaterACS Catalysis, 4
Kug‐Seung Lee, In-Su Park, Yong‐Hun Cho, Dae-Sik Jung, Namgee Jung, Hee-Young Park, Y. Sung (2008)
Electrocatalytic activity and stability of Pt supported on Sb-doped SnO2 nanoparticles for direct alcohol fuel cellsJournal of Catalysis, 258
H. Yang, H. Zeng (2004)
Self-construction of hollow SnO(2) octahedra based on two-dimensional aggregation of nanocrystallites.Angewandte Chemie, 43 44
G. Samjeské, A. Miki, S. Ye, M. Osawa (2006)
Mechanistic study of electrocatalytic oxidation of formic acid at platinum in acidic solution by time-resolved surface-enhanced infrared absorption spectroscopy.The journal of physical chemistry. B, 110 33
Melanie Moses-DeBusk, M. Yoon, L. Allard, D. Mullins, Zili Wu, Xiaofan Yang, G. Veith, G. Stocks, C. Narula (2013)
CO oxidation on supported single Pt atoms: experimental and ab initio density functional studies of CO interaction with Pt atom on θ-Al2O3(010) surface.Journal of the American Chemical Society, 135 34
Baeck Choi, Woo-Hyun Nam, D. Chung, In-Su Park, S. Yoo, Jaechun Song, Y. Sung (2015)
Enhanced methanol tolerance of highly Pd rich Pd-Pt cathode electrocatalysts in direct methanol fuel cellsElectrochimica Acta, 164
Zhaolin Liu, L. Hong, M. Tham, T. Lim, Huixin Jiang (2006)
Nanostructured Pt/C and Pd/C catalysts for direct formic acid fuel cellsJournal of Power Sources, 161
P. Aich, Haojuan Wei, Bridget Basan, A. Kropf, Neil Schweitzer, Christopher Marshall, Jeffrey Miller, R. Meyer (2015)
Single-Atom Alloy Pd–Ag Catalyst for Selective Hydrogenation of AcroleinJournal of Physical Chemistry C, 119
B.Y. Xia, H. Wu, Nan Li, Ya Yan, X. Lou, Xin Wang (2015)
One-pot synthesis of Pt-Co alloy nanowire assemblies with tunable composition and enhanced electrocatalytic properties.Angewandte Chemie, 54 12
Kaiwalya Sabnis, M. Akatay, Yanran Cui, Fred Sollberger, E. Stach, Jeffrey Miller, W. Delgass, F. Ribeiro (2015)
Probing the active sites for water–gas shift over Pt/molybdenum carbide using multi-walled carbon nanotubesJournal of Catalysis, 330
Xinrui Cao, Q. Fu, Yi Luo (2014)
Catalytic activity of Pd-doped Cu nanoparticles for hydrogenation as a single-atom-alloy catalyst.Physical chemistry chemical physics : PCCP, 16 18
Hongtao Wang, Qingxiao Wang, Yingchun Cheng, Kun Li, Yingbang Yao, Qiang Zhang, C. Dong, Peng Wang, U. Schwingenschlögl, Wei Yang, Xixiang Zhang (2012)
Doping monolayer graphene with single atom substitutions.Nano letters, 12 1
Single atomic Pt catalyst can offer efficient utilization of the expensive platinum and provide unique selectivity because it lacks ensemble sites. However, designing such a catalyst with high Pt loading and good durability is very challenging. Here, single atomic Pt catalyst supported on antimony‐doped tin oxide (Pt1/ATO) is synthesized by conventional incipient wetness impregnation, with up to 8 wt% Pt. The single atomic Pt structure is confirmed by high‐angle annular dark field scanning tunneling electron microscopy images and extended X‐ray absorption fine structure analysis results. Density functional theory calculations show that replacing Sb sites with Pt atoms in the bulk phase or at the surface of SbSn or ATO is energetically favorable. The Pt1/ATO shows superior activity and durability for formic acid oxidation reaction, compared to a commercial Pt/C catalyst. The single atomic Pt structure is retained even after a harsh durability test, which is performed by repeating cyclic voltammetry in the range of 0.05–1.4 V for 1800 cycles. A full cell is fabricated for direct formic acid fuel cell using the Pt1/ATO as an anode catalyst, and an order of magnitude higher cell power is obtained compared to the Pt/C.
Advanced Energy Materials – Wiley
Published: Jan 1, 2018
Keywords: ; ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.