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Guangming Yang, Chao Su, Huangang Shi, Yinlong Zhu, Yufei Song, Wei Zhou, Zongping Shao (2020)
Toward Reducing the Operation Temperature of Solid Oxide Fuel Cells: Our Past 15 Years of Efforts in Cathode DevelopmentEnergy & Fuels
Yucun Zhou, E. Liu, Yu Chen, Yuchen Liu, Lei Zhang, Weilin Zhang, Zheyu Luo, N. Kane, Bote Zhao, Luke Soule, Ying-Hua Niu, Yong Ding, Hanping Ding, D. Ding, Meilin Liu (2021)
An Active and Robust Air Electrode for Reversible Protonic Ceramic Electrochemical CellsACS energy letters
Ye Lin, R. Ran, Yao Zheng, Zongping Shao, W. Jin, N. Xu, J. Ahn (2008)
Evaluation of Ba0. 5Sr0. 5Co0. 8Fe0. 2O3-δ as a Potential Cathode for an Anode-Supported Proton-Conducting Solid-Oxide Fuel CellJournal of Power Sources, 180
Wei Wang, D. Medvedev, Zongping Shao (2018)
Gas Humidification Impact on the Properties and Performance of Perovskite‐Type Functional Materials in Proton‐Conducting Solid Oxide CellsAdvanced Functional Materials, 28
H. Shimada, Y. Yamaguchi, H. Sumi, Y. Mizutani (2020)
Performance Comparison of Perovskite Composite Cathodes with BaZr0.1Ce0.7Y0.1Yb0.1O3–δ in Anode-Supported Protonic Ceramic Fuel CellsJournal of The Electrochemical Society, 167
Jun-young Kim, Areum Jun, O. Gwon, Seonyoung Yoo, Meilin Liu, Jeeyoung Shin, Tak-Hyoung Lim, Guntae Kim (2018)
Hybrid-solid oxide electrolysis cell: A new strategy for efficient hydrogen productionNano Energy, 44
Jung-Hyun Kim, A. Manthiram (2008)
LnBaCo2O5+δ oxides as cathodes for intermediate-temperature solid oxide fuel cellsJournal of The Electrochemical Society, 155
H. Shimada, Y. Yamaguchi, H. Sumi, Y. Mizutani (2021)
Enhanced La0.6Sr0.4Co0.2Fe0.8O3–-based cathode performance by modification of BaZr0.1Ce0.7Y0.1Yb0.1O3– electrolyte surface in protonic ceramic fuel cellsCeramics International
Kai Pei, Yucun Zhou, Yong Ding, K. Xu, Hua Zhang, W. Yuan, K. Sasaki, YongMan Choi, Meilin Liu, Yu Chen (2021)
An improved oxygen reduction reaction activity and CO2-tolerance of La0.6Sr0.4Co0.2Fe0.8O3-δ achieved by a surface modification with barium cobaltite coatingsJournal of Power Sources
Yanxiang Zhang, Yu Chen, Mei Li, M. Yan, M. Ni, C. Xia (2016)
A high-precision approach to reconstruct distribution of relaxation times from electrochemical impedance spectroscopyJournal of Power Sources, 308
K. Lee, E. Wachsman (2014)
Role of nanostructures on SOFC performance at reduced temperaturesMRS Bulletin, 39
Ying-Hua Niu, Yucun Zhou, Weiqiang Lv, Yu Chen, Yanxiang Zhang, Weilin Zhang, Zheyu Luo, N. Kane, Yong Ding, Luke Soule, Yuchen Liu, Weidong He, Meilin Liu (2021)
Enhancing Oxygen Reduction Activity and Cr Tolerance of Solid Oxide Fuel Cell Cathodes by a Multiphase Catalyst CoatingAdvanced Functional Materials, 31
Mingi Choi, Seo Kim, Wonyoung Lee (2020)
Effects of water atmosphere on chemical degradation of PrBa0.5Sr0.5Co1.5Fe0.5O5+δ electrodesCeramics International
Yufei Song, Yubo Chen, Meigui Xu, Wei Wang, Y. Zhang, Guangming Yang, R. Ran, Wei Zhou, Zongping Shao (2020)
A Cobalt‐Free Multi‐Phase Nanocomposite as Near‐Ideal Cathode of Intermediate‐Temperature Solid Oxide Fuel Cells Developed by Smart Self‐AssemblyAdvanced Materials, 32
Chuancheng Duan, R. Kee, Huayang Zhu, N. Sullivan, Liangzhu Zhu, L. Bian, D. Jennings, R. O'Hayre (2019)
Highly efficient reversible protonic ceramic electrochemical cells for power generation and fuel productionNature Energy, 4
Hanping Ding, Wei Wu, C. Jiang, Yong Ding, Wenjuan Bian, Boxun Hu, Prabhakar Singh, Christopher Orme, Lu-Cun Wang, Yunya Zhang, D. Ding (2020)
Self-sustainable protonic ceramic electrochemical cells using a triple conducting electrode for hydrogen and power productionNature Communications, 11
Yi-Wei Lai, Kan-Rong Lee, Seng-Yu Yang, Chung‐Jen Tseng, Shian-Ching Jang, I-You Tsao, Szu-yuan Chen, Sheng-wei Lee (2019)
Production of La0.6Sr0.4Co0.2Fe0.8O3-δ cathode with graded porosity for improving proton-conducting solid oxide fuel cellsCeramics International, 45
S. Min, R. Song, Jin Lee, Myoung-Geun Park, K. Ryu, Yukwon Jeon, Y. Shul (2014)
Fabrication of anode-supported tubular Ba(Zr0.1Ce0.7Y0.2)O3−δ cell for intermediate temperature solid oxide fuel cellsCeramics International, 40
Lei Yang, Ze Liu, Shizhong Wang, YongMan Choi, C. Zuo, Meilin Liu (2010)
A mixed proton, oxygen ion, and electron conducting cathode for SOFCs based on oxide proton conductorsJournal of Power Sources, 195
Guntae Kim, S. Wang, A. Jacobson, L. Reimus, P. Brodersen, C. Mims (2007)
Rapid oxygen ion diffusion and surface exchange kinetics in PrBaCo2O5+x with a perovskite related structure and ordered A cationsJournal of Materials Chemistry, 17
Ce Sun, Shaojing Yang, Yang Lu, Jianjun Wen, X. Ye, Z. Wen (2020)
Tailoring a micro-nanostructured electrolyte-oxygen electrode interface for proton-conducting reversible solid oxide cellsJournal of Power Sources, 449
Libin Lei, Jihao Zhang, Zhihao Yuan, Jianping Liu, M. Ni, F. Chen (2019)
Progress Report on Proton Conducting Solid Oxide Electrolysis CellsAdvanced Functional Materials, 29
N. Bausá, C. Solís, Ragnar Strandbakke, J. Serra (2017)
Development of composite steam electrodes for electrolyzers based on barium zirconateSolid State Ionics, 306
Yu Chen, Seonyoung Yoo, Xiaxi Li, D. Ding, Kai Pei, Dongchang Chen, Yong Ding, Bote Zhao, Ryan Murphy, Ben deGlee, Jiang Liu, Meilin Liu (2018)
An effective strategy to enhancing tolerance to contaminants poisoning of solid oxide fuel cell cathodesNano Energy, 47
Yu Chen, Seonyoung Yoo, Kai Pei, Dongchang Chen, Lei Zhang, Ben deGlee, Ryan Murphy, Bote Zhao, Yanxiang Zhang, Yan Chen, Meilin Liu (2018)
An In Situ Formed, Dual‐Phase Cathode with a Highly Active Catalyst Coating for Protonic Ceramic Fuel CellsAdvanced Functional Materials, 28
Yucun Zhou, Weilin Zhang, N. Kane, Zheyu Luo, Kai Pei, K. Sasaki, YongMan Choi, Yu Chen, Dong Ding, Meilin Liu (2021)
An Efficient Bifunctional Air Electrode for Reversible Protonic Ceramic Electrochemical CellsAdvanced Functional Materials, 31
B. Koo, Kyeounghak Kim, Jun Kim, Hyunguk Kwon, J. Han, Woochul Jung (2018)
Sr Segregation in Perovskite Oxides: Why It Happens and How It ExistsJoule
Sewook Lee, S. Park, Seokeun Wee, H. Baek, Dongwook Shin (2018)
One-dimensional structured La0.6Sr0.4Co0.2Fe0.8O3−δ - BaCe0.5Zr0.35Y0.15O3−δ composite cathode for protonic ceramic fuel cellsSolid State Ionics
Yang Yu, K. Ludwig, J. Woicik, Srikanth Gopalan, U. Pal, T. Kaspar, S. Basu (2016)
Effect of Sr Content and Strain on Sr Surface Segregation of La1-xSrxCo0.2Fe0.8O3-δ as Cathode Material for Solid Oxide Fuel Cells.ACS applied materials & interfaces, 8 40
Kai Pei, Yucun Zhou, K. Xu, Zuyun He, Yan Chen, Weilin Zhang, Seonyoung Yoo, Bote Zhao, Weiliang Yuan, Meilin Liu, Yu Chen (2020)
Enhanced Cr-tolerance of an SOFC cathode by an efficient electro-catalyst coatingNano Energy, 72
Yu Chen, YongMan Choi, Seonyoung Yoo, Yong Ding, Ruiqiang Yan, Kai Pei, Chong Qu, Lei Zhang, Ikwhang Chang, Bote Zhao, Yanxiang Zhang, Huijun Chen, Yan Chen, Chenghao Yang, Ben deGlee, Ryan Murphy, Jiang Liu, Meilin Liu (2018)
A Highly Efficient Multi-phase Catalyst Dramatically Enhances the Rate of Oxygen ReductionJoule, 2
S. Choi, Junsung Ahn, Ji-won Son, Jong-Ho Lee, Byung‐Kook Kim, K. Yoon, Ho-Il Ji (2018)
Comprehensive Understanding of Cathodic and Anodic Polarization Effects on Stability of Nanoscale Oxygen Electrode for Reversible Solid Oxide Cells.ACS applied materials & interfaces, 10 46
Nikolai Tsvetkov, Qiyang Lu, Lixin Sun, E. Crumlin, B. Yildiz (2016)
Improved chemical and electrochemical stability of perovskite oxides with less reducible cations at the surface.Nature materials, 15 9
Zongping Shao, S. Haile (2004)
A high-performance cathode for the next generation of solid-oxide fuel cellsNature, 431
Fei Zhao, C. Jin, Chenghao Yang, Siwei Wang, F. Chen (2011)
Fabrication and characterization of anode-supported micro-tubular solid oxide fuel cell based on BaZr0.1Ce0.7Y0.1Yb0.1O3−δ electrolyteJournal of Power Sources, 196
Lei Yang, Shizhong Wang, Kevin Blinn, Mingfei Liu, Ze Liu, Zhe Cheng, Meilin Liu (2009)
Enhanced Sulfur and Coking Tolerance of a Mixed Ion Conductor for SOFCs: BaZr0.1Ce0.7Y0.2–xYbxO3–δScience, 326
Yunfeng Tian, Yun Liu, Wenjie Wang, L. Jia, J. Pu, B. Chi, Jian Li (2020)
High performance and stability of double perovskite-type oxide NdBa0.5Ca0.5Co1.5Fe0.5O5+ as an oxygen electrode for reversible solid oxide electrochemical cellJournal of Energy Chemistry
D. Ding, Xiaxi Li, Samson Lai, K. Gerdes, Meilin Liu (2014)
Enhancing SOFC cathode performance by surface modification through infiltrationEnergy & Environmental Science, 7
Chuancheng Duan, Jake Huang, N. Sullivan, R. O'Hayre (2020)
Proton-conducting oxides for energy conversion and storageApplied physics reviews, 7
Yanxiang Zhang, Yu Chen, M. Yan, F. Chen (2015)
Reconstruction of relaxation time distribution from linear electrochemical impedance spectroscopyJournal of Power Sources, 283
Changcheng Chen, Mingfei Liu, Yaohui Bai, Lei Yang, E. Xie, Meilin Liu (2011)
Anode-supported tubular SOFCs based on BaZr0.1Ce0.7Y0.1Yb0.1O3 − δ electrolyte fabricated by dip coatingElectrochemistry Communications, 13
Yufei Song, Yubo Chen, Wei Wang, Chuan Zhou, Yijun Zhong, Guangming Yang, W. Zhou, Meilin Liu, Zongping Shao (2019)
Self-Assembled Triple-Conducting Nanocomposite as a Superior Protonic Ceramic Fuel Cell CathodeJoule
Dengjie Chen, R. Ran, Kun Zhang, Jun Wang, Zongping Shao (2009)
Intermediate-temperature electrochemical performance of a polycrystalline PrBaCo2O5+δ cathode on samarium-doped ceria electrolyteJournal of Power Sources, 188
The commercialization of reversible protonic ceramic electrochemical cells is hindered by the lack of highly active and durable air electrodes exposed to high concentration of steam under operating conditions. Here, findings that dramatically enhance the electrocatalytic activity and stability of a conventional (La0.6Sr0.4)0.95Co0.2Fe0.8O3−δ (LSCF) air electrode by a multiphase catalyst coating composed of a conformal Pr1−xBaxCoO3−δ thin film and exsolved BaCoO3−δ nanoparticles, are reported. At 600 °C, the catalyst coating decreases the polarization resistance of the LSCF air electrode by a factor of 25 (from 1.09 to 0.043 Ω cm2) in air and the degradation rate by two orders of magnitude (from 1.0 × 10−2 to 1.8 × 10−4 Ω cm2 h−1 in humidified air with 30 vol% H2O). Further, a single cell with the catalyst‐coated LSCF air electrode at 600 °C demonstrates a high peak power density of 1.04 W cm−2 in the fuel cell mode and a high current density of 1.82 A cm−2 at 1.3 V in the electrolysis mode. The significantly enhanced performance of the LSCF air electrode is attributed mainly to the high rate of surface oxygen exchange, fast surface proton diffusion, and the rapid H2O and O2 dissociation on the catalysts.
Advanced Energy Materials – Wiley
Published: Mar 1, 2022
Keywords: air electrodes; bifunctional catalysts; protonic ceramic electrochemical cells; solid oxide cells; water electrolysis
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