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References (70)
-
R. Younesi, M. Hahlin, F. Björefors, P. Johansson, K. Edström (2013)
Li–O2 Battery Degradation by Lithium Peroxide (Li2O2): A Model StudyChemistry of Materials, 25
-
K. Yao, David Kwabi, R. Quinlan, A. Mansour, A. Grimaud, Yueh-Lin Lee, Yi‐Chun Lu, Y. Shao-horn (2013)
Thermal Stability of Li2O2 and Li2O for Li-Air Batteries: In Situ XRD and XPS StudiesJournal of The Electrochemical Society, 160
-
Francis Amalraj, M. Talianker, B. Markovsky, L. Burlaka, N. Leifer, G. Goobes, Evan Erickson, Ortal Haik, J. Grinblat, E. Zinigrad, D. Aurbach, J. Lampert, Ji‐Yong Shin, M. Schulz-Dobrick, A. Garsuch (2013)
Studies of Li and Mn-Rich Lix[MnNiCo]O2 Electrodes: Electrochemical Performance, Structure, and the Effect of the Aluminum Fluoride CoatingJournal of The Electrochemical Society, 160
-
Xiqian Yu, Yingchun Lyu, L. Gu, Huimin Wu, Seong‐Min Bak, Yong-ning Zhou, K. Amine, S. Ehrlich, Hong Li, K. Nam, Xiao‐Qing Yang (2014)
Understanding the Rate Capability of High‐Energy‐Density Li‐Rich Layered Li1.2Ni0.15Co0.1Mn0.55O2 Cathode MaterialsAdvanced Energy Materials, 4
-
M. Sathiya, M. Sathiya, A. Abakumov, Dominique Foix, G. Rousse, G. Rousse, G. Rousse, K. Ramesha, M. Saubanère, M. Saubanère, M. Doublet, M. Doublet, H. Vezin, C. Laisa, A. Prakash, A. Prakash, D. Gonbeau, G. Vantendeloo, J. Tarascon, J. Tarascon (2015)
Origin of voltage decay in high-capacity layered oxide electrodes.Nature materials, 14 2
-
S. Figueroa, F. Requejo, E. Lede, Luciano Lamaita, M. Peluso, J. Sambeth (2005)
XANES study of electronic and structural nature of Mn-sites in manganese oxides with catalytic propertiesCatalysis Today, 107
-
J. Reed, G. Ceder (2004)
Role of electronic structure in the susceptibility of metastable transition-metal oxide structures to transformation.Chemical reviews, 104 10
-
She-huang Wu, Ming-tlau Yu (2007)
Preparation and characterization of o-LiMnO2 cathode materialsJournal of Power Sources, 165
-
M. Saubanère, E. McCalla, J. Tarascon, M. Doublet (2016)
The intriguing question of anionic redox in high-energy density cathodes for Li-ion batteriesEnergy and Environmental Science, 9
-
P. Yan, Liang Xiao, Jianming Zheng, Yungang Zhou, Yang He, X. Zu, S. Mao, Jie Xiao, Fei Gao, J. Zhang, Chongmin Wang (2015)
Probing the Degradation Mechanism of Li2MnO3 Cathode for Li-Ion BatteriesChemistry of Materials, 27
-
(2002)
Understanding the Anomalous Capacity of Li / Li [ Ni x Li ( 1 / 3 − 2x / 3 ) Mn ( 2 / 3 − x / 3 ) ] O 2 Cells Using In Situ X-Ray Diffraction and Electrochemical Studies -
Dominique Foix, M. Sathiya, E. McCalla, J. Tarascon, D. Gonbeau (2016)
X-ray Photoemission Spectroscopy Study of Cationic and Anionic Redox Processes in High-Capacity Li-Ion Battery Layered-Oxide ElectrodesJournal of Physical Chemistry C, 120
-
E. McCalla, A. Prakash, E. Berg, M. Saubanère, A. Abakumov, Dominique Foix, B. Klobes, M. Sougrati, G. Rousse, Florent Lepoivre, S. Mariyappan, M. Doublet, D. Gonbeau, P. Novák, G. Tendeloo, R. Hermann, J. Tarascon (2015)
Reversible Li-Intercalation through Oxygen Reactivity in Li-Rich Li-Fe-Te Oxide MaterialsJournal of The Electrochemical Society, 162
-
E. McCalla, A. Abakumov, M. Saubanère, Dominique Foix, E. Berg, G. Rousse, M. Doublet, D. Gonbeau, P. Novák, G. Tendeloo, R. Dominko, J. Tarascon (2015)
Visualization of O-O peroxo-like dimers in high-capacity layered oxides for Li-ion batteriesScience, 350
-
S. Amalraj, B. Markovsky, Daniel Sharon, M. Talianker, E. Zinigrad, Rachel Persky, Ortal Haik, J. Grinblat, J. Lampert, M. Schulz-Dobrick, A. Garsuch, L. Burlaka, D. Aurbach (2012)
Study of the electrochemical behavior of the “inactive” Li2MnO3Electrochimica Acta, 78
-
M. Rossouw, M. Thackeray (1991)
Lithium manganese oxides from Li2MnO3 for rechargeable lithium battery applicationsMaterials Research Bulletin, 26
-
A. Andersson, D. Abraham, R. Haasch, S. Maclaren, Jun Liu, K. Amine (2002)
Surface Characterization of Electrodes from High Power Lithium-Ion BatteriesJournal of The Electrochemical Society, 149
-
A. Grosvenor, M. Biesinger, R. Smart, N. McIntyre (2006)
New interpretations of XPS spectra of nickel metal and oxidesSurface Science, 600
-
P. Kalyani, S. Chitra, T. Mohan, S. Gopukumar (1999)
Lithium metal rechargeable cells using Li2MnO3 as the positive electrodeJournal of Power Sources, 80
-
Christopher Fell, M. Chi, Y. Meng, Jacob Jones (2012)
In situ X-ray diffraction study of the lithium excess layered oxide compound Li[Li0.2Ni0.2Mn0.6]O2 during electrochemical cyclingSolid State Ionics, 207
-
M. Thackeray, Christopher Johnson, J. Vaughey, Naichao Li, S. Hackney (2005)
Advances in manganese-oxide ‘composite’ electrodes for lithium-ion batteriesJournal of Materials Chemistry, 15
-
A. Watanabe, Futoshi Matsumoto, Mika Fukunishi, G. Kobayashi, Atsushi Ito, M. Hatano, Y. Ohsawa, Yuichi Sato (2012)
Relationship between Electrochemical Pre-Treatment and Cycle Performance of a Li-Rich Solid-Solution Layered Li1−α[Ni0.18Li0.20+αCo0.03Mn0.58]O2 Cathode for Li-Ion Secondary BatteriesElectrochemistry, 80
-
Y. Wu, A. Manthiram (2006)
High Capacity, Surface-Modified Layered Li [ Li ( 1 − x ) ∕ 3Mn ( 2 − x ) ∕ 3Nix ∕ 3Cox ∕ 3 ] O2 Cathodes with Low Irreversible Capacity LossElectrochemical and Solid State Letters, 9
-
K. Kanamura, H. Tamura, Z. Takehara (1992)
XPS analysis of a lithium surface immersed in propylene carbonate solution containing various saltsJournal of Electroanalytical Chemistry, 333
-
Atsushi Ito, De-cheng Li, Y. Ohsawa, Yuichi Sato (2008)
A new approach to improve the high-voltage cyclic performance of Li-rich layered cathode material by electrochemical pre-treatmentJournal of Power Sources, 183
-
J. Croy, Donghan Kim, M. Balasubramanian, K. Gallagher, Sun‐Ho Kang, M. Thackeray (2012)
Countering the Voltage Decay in High Capacity xLi2MnO3•(1–x)LiMO2 Electrodes (M=Mn, Ni, Co) for Li+-Ion BatteriesJournal of The Electrochemical Society, 159
-
C. Ghanty, B. Markovsky, Evan Erickson, M. Talianker, Ortal Haik, Y. Talyossef, A. Mor, D. Aurbach, J. Lampert, A. Volkov, Ji‐Yong Shin, A. Garsuch, F. Chesneau, C. Erk (2015)
Li+‐Ion Extraction/Insertion of Ni‐Rich Li1+x(NiyCozMnz)wO2 (0.005, 2
-
M. Biesinger, L. Lau, A. Gerson, R. Smart (2010)
Resolving surface chemical states in XPS analysis of first row transition metals, oxides and hydroxides: Sc, Ti, V, Cu and ZnApplied Surface Science, 257
-
Nathalie Andreu, D. Flahaut, R. Dedryvère, Marie Minvielle, Hervé Martinez, D. Gonbeau (2015)
XPS investigation of surface reactivity of electrode materials: effect of the transition metal.ACS applied materials & interfaces, 7 12
-
A. Boulineau, L. Simonin, J. Colin, C. Bourbon, S. Patoux (2013)
First evidence of manganese-nickel segregation and densification upon cycling in Li-rich layered oxides for lithium batteries.Nano letters, 13 8
-
T. Ohzuku, Y. Makimura (2001)
Layered Lithium Insertion Material of LiCo1/3Ni1/3Mn1/3O2 for Lithium-Ion BatteriesChemistry Letters, 30
-
F. Capitaine, P. Gravereau, C. Delmas (1996)
A new variety of LiMnO2 with a layered structureSolid State Ionics, 89
-
Evan Erickson, C. Ghanty, D. Aurbach (2014)
New Horizons for Conventional Lithium Ion Battery Technology.The journal of physical chemistry letters, 5 19
-
P. Nayak, J. Grinblat, E. Levi, B. Markovsky, D. Aurbach (2016)
Effect of cycling conditions on the electrochemical performance of high capacity Li and Mn-rich cathodes for Li-ion batteriesJournal of Power Sources, 318
-
M. Sathiya, G. Rousse, K. Ramesha, C. Laisa, H. Vezin, M. Sougrati, M. Doublet, Dominique Foix, D. Gonbeau, W. Walker, A. Prakash, M. Hassine, L. Dupont, J. Tarascon (2013)
Reversible anionic redox chemistry in high-capacity layered-oxide electrodes.Nature materials, 12 9
-
Chuang Yu, Guangshe Li, X. Guan, Jing Zheng, Dong Luo, Liping Li (2012)
The impact of upper cut-off voltages on the electrochemical behaviors of composite electrode 0.3Li2MnO3·0.7LiMn1/3Ni1/3Co1/3O2.Physical chemistry chemical physics : PCCP, 14 35
-
L. Croguennec, P. Deniard, R. Brec (1997)
Electrochemical Cyclability of Orthorhombic LiMnO2 Characterization of Cycled MaterialsJournal of The Electrochemical Society, 144
-
Christopher Johnson, Naichao Li, Christina Lefief, J. Vaughey, M. Thackeray (2008)
Synthesis, Characterization and Electrochemistry of Lithium Battery Electrodes: xLi2MnO3·(1 − x)LiMn0.333Ni0.333Co0.333O2 (0 ≤ x ≤ 0.7)Chemistry of Materials, 20
-
J. Croy, K. Gallagher, M. Balasubramanian, Brandon Long, M. Thackeray (2014)
Quantifying Hysteresis and Voltage Fade in xLi2MnO3●(1-x)LiMn0.5Ni0.5O2 Electrodes as a Function of Li2MnO3 ContentJournal of The Electrochemical Society, 161
-
E. Zhecheva, R. Stoyanova, R. Alcántara, P. Lavela, J. Tirado (2002)
Cation order/disorder in lithium transition-metal oxides as insertion electrodes for lithium-ion batteriesPure and Applied Chemistry, 74
-
P. Nayak, J. Grinblat, M. Levi, B. Markovsky, D. Aurbach (2014)
Structural and Electrochemical Evidence of Layered to Spinel Phase Transformation of Li and Mn Rich Layered Cathode Materials of the Formulae xLi[Li1/3Mn2/3]O2.(1-x)LiMn1/3Ni1/3Co1/3O2 (x = 0.2, 0.4, 0.6) upon CyclingJournal of The Electrochemical Society, 161
-
Jeom‐Soo Kim, Christopher Johnson, J. Vaughey, M. Thackeray, S. Hackney, W. Yoon, C. Grey (2004)
Electrochemical and Structural Properties of xLi2M‘O3·(1−x)LiMn0.5Ni0.5O2 Electrodes for Lithium Batteries (M‘ = Ti, Mn, Zr; 0 ≤ x ⩽ 0.3)Chemistry of Materials, 16
-
M. Richard, E. Fuller, J. Dahn (1994)
The effect of ammonia reduction on the spinel electrode materials, LiMn2O4 and Li(Li1/3Mn5/3)O4Solid State Ionics, 73
-
W. O'grady, K. Pandya, K. Swider, D. Corrigan (1996)
In Situ X‐Ray Absorption Near‐Edge Structure Evidence for Quadrivalent Nickel in Nickel Battery ElectrodesJournal of The Electrochemical Society, 143
-
Sun‐Ho Kang, K. Amine (2005)
Layered Li(Li0.2Ni0.15 + 0.5zCo0.10Mn0.55 − 0.5z)O2 − zFz cathode materials for Li-ion secondary batteriesJournal of Power Sources, 146
-
S. Mizuno, H. Tochihara, T. Kadowaki, H. Minagawa, K. Hayakawa, I. Toyoshima, C. Oshima (1992)
Formation of a linear LiOH compound on Cu(001): reaction of H2O with Li adatoms at low coveragesSurface Science, 264
-
E. McCalla, M. Sougrati, G. Rousse, E. Berg, A. Abakumov, Nadir Recham, K. Ramesha, M. Sathiya, R. Dominko, G. Tendeloo, P. Novák, J. Tarascon (2015)
Understanding the roles of anionic redox and oxygen release during electrochemical cycling of lithium-rich layered Li4FeSbO6.Journal of the American Chemical Society, 137 14
-
Christopher Johnson, Naichao Li, Christina Lefief, M. Thackeray (2007)
Anomalous capacity and cycling stability of xLi2MnO3 · (1 − x)LiMO2 electrodes (M = Mn, Ni, Co) in lithium batteries at 50 °CElectrochemistry Communications, 9
-
H. Hantsche (1993)
High resolution XPS of organic polymers, the scienta ESCA300 database. By G. Beamson and D. Briggs, Wiley, Chichester 1992, 295 pp., hardcover, £ 65.00, ISBN 0‐471‐93592‐1Advanced Materials, 5
-
D. Aurbach, Onit Srur-Lavi, C. Ghanty, M. Dixit, Ortal Haik, M. Talianker, Y. Grinblat, N. Leifer, R. Lavi, D. Major, G. Goobes, E. Zinigrad, Evan Erickson, M. Kosa, B. Markovsky, J. Lampert, A. Volkov, Ji‐Yong Shin, A. Garsuch (2015)
Studies of Aluminum-Doped LiNi0.5Co0.2Mn0.3O2: Electrochemical Behavior, Aging, Structural Transformations, and Thermal CharacteristicsJournal of The Electrochemical Society, 162
-
Han Zhang, Q. Qiao, G. Li, S. Ye, X. Gao (2012)
Surface nitridation of Li-rich layered Li(Li0.17Ni0.25Mn0.58)O2 oxide as cathode material for lithium-ion batteryJournal of Materials Chemistry, 22
-
Christopher Johnson, S. Korte, J. Vaughey, M. Thackeray, T. Bofinger, Y. Shao-horn, S. Hackney (1999)
Structural and electrochemical analysis of layered compounds from Li2MnO3Journal of Power Sources, 81
-
F. Schipper, Evan Erickson, C. Erk, Ji‐Yong Shin, F. Chesneau, D. Aurbach (2017)
Review—Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes I. Nickel-Rich, LiNixCoyMnzO2Journal of The Electrochemical Society, 164
-
A. Armstrong, P. Bruce (1996)
Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteriesNature, 381
-
Haijun Yu, Hyunjeong Kim, Yarong Wang, P. He, D. Asakura, Yumiko Nakamura, Haoshen Zhou (2012)
High-energy 'composite' layered manganese-rich cathode materials via controlling Li2MnO3 phase activation for lithium-ion batteries.Physical chemistry chemical physics : PCCP, 14 18
-
M. Newville (2001)
IFEFFIT: interactive XAFS analysis and FEFF fitting.Journal of synchrotron radiation, 8 Pt 2
-
J. Pérez–Ramírez, E. Kondratenko (2007)
Mechanism of ammonia oxidation over oxides studied by temporal analysis of productsJournal of Catalysis, 250
-
T. Ohzuku, A. Ueda, M. Nagayama (1993)
Electrochemistry and Structural Chemistry of LiNiO2 (R3̅m) for 4 Volt Secondary Lithium CellsJournal of The Electrochemical Society, 140
-
P. Rozier, J. Tarascon (2015)
Review—Li-Rich Layered Oxide Cathodes for Next-Generation Li-Ion Batteries: Chances and ChallengesJournal of The Electrochemical Society, 162
-
J. Wong, F. Lytle, R. Messmer, D. Maylotte (1984)
A Study of the K-edge Absorption Spectra of Selected Vanadium Compounds. -
B. Ravel, M. Newville (2005)
ATHENA, ARTEMIS, HEPHAESTUS: data analysis for X-ray absorption spectroscopy using IFEFFIT.Journal of synchrotron radiation, 12 Pt 4
-
F. Schipper, D. Aurbach (2016)
A brief review: Past, present and future of lithium ion batteriesRussian Journal of Electrochemistry, 52
-
Ortal Haik, N. Leifer, Zvi Samuk-Fromovich, E. Zinigrad, B. Markovsky, Liraz Larush, Yossi Goffer, G. Goobes, D. Aurbach (2010)
On the Surface Chemistry of LiMO2 Cathode Materials (M = [ MnNi ] and [MnNiCo]): Electrochemical, Spectroscopic, and Calorimetric StudiesJournal of The Electrochemical Society, 157
-
Evan Erickson, F. Schipper, T. Penki, Ji‐Yong Shin, C. Erk, F. Chesneau, B. Markovsky, D. Aurbach (2017)
Review—Recent Advances and Remaining Challenges for Lithium Ion Battery Cathodes II. Lithium-Rich, xLi2MnO3⋅(1-x)LiNiaCobMncO2Journal of The Electrochemical Society, 164
-
K. Kang, G. Ceder (2006)
Factors that affect Li mobility in layered lithium transition metal oxidesPhysical Review B, 74
-
K. Gallagher, J. Croy, M. Balasubramanian, M. Bettge, D. Abraham, A. Burrell, M. Thackeray (2013)
Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodesElectrochemistry Communications, 33
-
M. Ates, S. Mukerjee, K. Abraham (2015)
A high rate Li-rich layered MNC cathode material for lithium-ion batteriesRSC Advances, 5
-
D. Mohanty, S. Kalnaus, R. Meisner, K. Rhodes, Jianlin Li, E. Payzant, David Wood, Claus Daniel (2013)
Structural transformation of a lithium-rich Li1.2Co0.1Mn0.55Ni0.15O2 cathode during high voltage cycling resolved by in situ X-ray diffractionJournal of Power Sources, 229
-
Evan Erickson, F. Schipper, Ruiyuan Tian, Ji‐Yong Shin, C. Erk, F. Chesneau, J. Lampert, B. Markovsky, D. Aurbach (2017)
Enhanced capacity and lower mean charge voltage of Li-rich cathodes for lithium ion batteries resulting from low-temperature electrochemical activationRSC Advances, 7
-
Francis Amalraj, D. Kovacheva, M. Talianker, L. Zeiri, J. Grinblat, N. Leifer, G. Goobes, B. Markovsky, D. Aurbach (2010)
Synthesis of Integrated Cathode Materials xLi2MnO3⋅ ( 1 − x ) LiMn1 / 3Ni1 / 3Co1 / 3O2 ( x = 0.3 , 0.5 , 0.7 ) and Studies of Their Electrochemical BehaviorJournal of The Electrochemical Society, 157
- Publisher
- Wiley
- Copyright
- © 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 1614-6832
- eISSN
- 1614-6840
- DOI
- 10.1002/aenm.201700708
- Publisher site
- See Article on Publisher Site
Abstract
Li‐rich electrode materials of the family xLi2MnO3·(1−x)LiNiaCobMncO2 (a + b + c = 1) suffer a voltage fade upon cycling that limits their utilization in commercial batteries despite their extremely high discharge capacity, ≈250 mA h g−1. Li‐rich, 0.35Li2MnO3·0.65LiNi0.35Mn0.45Co0.20O2, is exposed to NH3 at 400 °C, producing materials with improved characteristics: enhanced electrode capacity and a limited average voltage fade during 100 cycles in half cells versus Li. Three main changes caused by NH3 treatment are established. First, a general bulk reduction of Co and Mn is observed via X‐ray photoelectron spectroscopy and X‐ray absorption near edge structure. Next, a structural rearrangement lowers the coordination number of CoO and MnO bonds, as well as formation of a surface spinel‐like structure. Additionally, Li+ removal from the bulk causes the formation of surface LiOH, Li2CO3, and Li2O. These structural and surface changes can enhance the voltage and capacity stability of the Li‐rich material electrodes after moderate NH3 treatment times of 1–2 h.
Journal
Advanced Energy Materials – Wiley
Published: Sep 1, 2017
Keywords: ; ; ; ; ;