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Graphical Abstract: ChemPlusChem 5/2012

Graphical Abstract: ChemPlusChem 5/2012 wileyonlinelibrary.com Most of the articles in this issue have already appeared online on wileyonlinelibrary.com. See http://www.chempluschem.org under EarlyView COVER PICTURE The cover picture shows the thermolysis (up to 1000 8C) of the first phosphorusrich manganese(I) complex [Mn2(m-Br){cyclo-(P4tBu3)PtBu}(CO)6] with formation of antiferromagnetic (below 103 K) Mn2P as the final product via a phosphorus-rich phase (calculated as Mn2P5) at 315 8C. In their Full Paper on page 341 ff., E. HeyHawkins et al. describe the synthesis of the molecular precursor from Na[cyclo(P5tBu4)] and [MnBr(CO)5]. The rearrangement of [cyclo-(P5tBu4)]À into [cyclo(P4tBu3)PtBu]À was rationalized by theoretical studies. Cover designed by Volkan Senol. NEWS Spotlights on our sister journals 338 – 340 ChemPlusChem 2012, 77, 333 – 337  2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim COMMUNICATIONS A. Kircali, R. Frank, S. Gómez-Ruiz, B. Kirchner, E. Hey-Hawkins* 341 – 344 Synthesis and Thermolysis of the Phosphorus-Rich Manganese(I) Complex [Mn2ACHTUNGRE(m-Br)ACHTUNGRE{cyclo-ACHTUNGRE(P4tBu3)PtBu}(CO)6]: From Complexes to Metal Phosphides A complex matter: NaACHTUNGRE[cyclo-ACHTUNGRE(P5tBu4)] reacts with two equivalents of [MnBr(CO)5] to give the phosphorus-rich manganese(I) complex [Mn2ACHTUNGRE(m-Br)ACHTUNGRE{cyclo-ACHTUNGRE(P4tBu3)PtBu}(CO)6] (see structure) containing a [{cyclo-(P4tBu3)}PtBu]À ligand. The rearrangement of [cyclo(P5tBu4)]À to [cyclo-(P4tBu3)PtBu]À was rationalized by theoretical studies. Thermolysis of up to 1000 8C gives Mn2P. E. Amigues, J. Schulz, M. Szlosek-Pinaud,* http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png ChemPlusChem Wiley

Graphical Abstract: ChemPlusChem 5/2012

ChemPlusChem , Volume 77 (5) – May 1, 2012
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Publisher
Wiley
Copyright
Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2192-6506
eISSN
2192-6506
DOI
10.1002/cplu.201290022
Publisher site
See Article on Publisher Site

Abstract

wileyonlinelibrary.com Most of the articles in this issue have already appeared online on wileyonlinelibrary.com. See http://www.chempluschem.org under EarlyView COVER PICTURE The cover picture shows the thermolysis (up to 1000 8C) of the first phosphorusrich manganese(I) complex [Mn2(m-Br){cyclo-(P4tBu3)PtBu}(CO)6] with formation of antiferromagnetic (below 103 K) Mn2P as the final product via a phosphorus-rich phase (calculated as Mn2P5) at 315 8C. In their Full Paper on page 341 ff., E. HeyHawkins et al. describe the synthesis of the molecular precursor from Na[cyclo(P5tBu4)] and [MnBr(CO)5]. The rearrangement of [cyclo-(P5tBu4)]À into [cyclo(P4tBu3)PtBu]À was rationalized by theoretical studies. Cover designed by Volkan Senol. NEWS Spotlights on our sister journals 338 – 340 ChemPlusChem 2012, 77, 333 – 337  2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim COMMUNICATIONS A. Kircali, R. Frank, S. Gómez-Ruiz, B. Kirchner, E. Hey-Hawkins* 341 – 344 Synthesis and Thermolysis of the Phosphorus-Rich Manganese(I) Complex [Mn2ACHTUNGRE(m-Br)ACHTUNGRE{cyclo-ACHTUNGRE(P4tBu3)PtBu}(CO)6]: From Complexes to Metal Phosphides A complex matter: NaACHTUNGRE[cyclo-ACHTUNGRE(P5tBu4)] reacts with two equivalents of [MnBr(CO)5] to give the phosphorus-rich manganese(I) complex [Mn2ACHTUNGRE(m-Br)ACHTUNGRE{cyclo-ACHTUNGRE(P4tBu3)PtBu}(CO)6] (see structure) containing a [{cyclo-(P4tBu3)}PtBu]À ligand. The rearrangement of [cyclo(P5tBu4)]À to [cyclo-(P4tBu3)PtBu]À was rationalized by theoretical studies. Thermolysis of up to 1000 8C gives Mn2P. E. Amigues, J. Schulz, M. Szlosek-Pinaud,*

Journal

ChemPlusChem – Wiley

Published: May 1, 2012

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