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www.AsianJOC.org Redox Chemistry Nitroxides are organic spin compounds that are used as antioxidants because of their ability to react with superoxide. In their Communication on page 388 ff. featured on the inside cover, Ken-ichi Yamada and co-workers evaluate the effect of changing the C4 substituents on the redox potential of piperidine nitroxides with the aim of identifying a good index for developing better superoxide dismutase (SOD) mimics. The redox potential of a nitroxide/N-oxoammonium cation couple correlates strongly with their reactivity towards superoxide. Thus, the SOD-mimicking activity of a nitroxide can be controlled based on its redox potential. Porphyrin Modification Porphyrin modification and C H activation are two important areas of research, but they have not necessarily been closely related concepts in the past. However, as methods for direct C H activation have become more advanced, these techniques have become ever more intertwined. In their Focus Review on page 356 ff., Atsuhiro Osuka and Hideki Yorimitsu discuss the meeting of these two technologies, the recent successes of the combination, and its implications for the development of porpyhrin chemistry in the future. Diversity Oriented Synthesis Isatins are known as versatile building blocks for complex organic synthesis. In particular, they are good
Asian Journal of Organic Chemistry – Wiley
Published: May 1, 2013
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