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www.AsianJOC.org Indoles are frequently found … … as components in natural products, pharmaceuticals, and agrochemicals. A convenient way to access one class of indoles, that is, 3-indolyl derivatives, is to trap alkylideneindoleninium ions and alkylideneindolenine species with nucleophiles. In their Focus Review on page 1036 ff., Jian Xiao and co-workers discuss the many catalytic, asymmetric methods of using alkylideneindoleninium ions and alkylideneindolenine intermediates to produce chiral 3-indolyl derivatives, with particular emphasis on the leaving groups that can be used and the methods for controlling the stereochemistry of their reactions. FOCUS REVIEWS Boxing clever: This Focus Review Aziridine Chemistry highlights the chemistry of chiral aziri- dine-2-carboxylates as building blocks Hyun-Joon Ha,* Jae-Hoon Jung, based on regio- and stereoselective Won Koo Lee* 1020 – 1035 functional group transformations of Application of Regio- and the carboxylate group and aziridine Stereoselective Functional Group ring. This chemistry is exemplified by Transformations of Chiral Aziridine-2- the efficient and highly stereoselective carboxylates synthesis of many biologically impor- tant amines, including several natural products. Synthetic Methods Liang Wang, Yuye Chen, Jian Xiao* 1036 – 1052 Alkylideneindoleninium Ions and Alkylideneindolenines: Key Intermediates for the Asymmetric Long words, short routes: This Focus ation strategies for alkylideneindoleni- Synthesis of 3-Indolyl
Asian Journal of Organic Chemistry – Wiley
Published: Oct 1, 2014
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