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Contents FEATURED ARTICLES 3-Alkyloxycyclobutanones are highly reactive due to the strain energy in the cyclobutane ring. They also form zwitterionic intermediates in the presence of Lewis-acid catalysts, which makes them highly suitable for cycloaddition reactions. In their Focus Review on page 16, Yu Rao and co-workers discuss synthetic approaches to 3-ethoxycyclobutanones and the applications of these compounds and their derivatives, especially in formal [4+2], [3+2], and [3+3] annulations. FOCUS REVIEWS Heterocycles Shi Chen, Gang Shan, Pengju Nie, Yu Rao* .................................. 16 – 26 3-Alkyloxycyclobutanones as Useful Synthons for Heterocycle and Be there and square: Substituted 3- Lewis acid catalysis, 3-alkyloxycyclobuta- Carbocycle Synthesis alkyloxycyclobutanones are highly val- nones can form zwitterionic intermedi- uable intermediates in organic synthe- ates and participate in a series of cyclo- sis, which demonstrate interesting and addition reactions as three- or four- rich reactivity in different types of reac- carbon synthons. tions due to the strain energy. Under COMMUNICATIONS Cycloaddition Wen-Ke Li, Ze-Shui Liu, Long He,* Tai-Ran Kang,* Quan-Zhong Liu* . 28 – 32 Enantioselective Cycloadditions of Vinyl Cyclopropanes and Nitroolefins for Functionally and Optically Enriched Nitrocyclopentanes Spinning the vinyl: Palladium catalyzed nitroolefins were realized for construct- enantioselective (3+2) cycloadditions of ing structurally and optically enriched
Asian Journal of Organic Chemistry – Wiley
Published: Jan 1, 2015
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