Access the full text.
Sign up today, get DeepDyve free for 14 days.
Amin Talebian-Kiakalaieh, N. Amin, Neda Najaafi, S. Tarighi (2018)
A Review on the Catalytic Acetalization of Bio-renewable Glycerol to Fuel AdditivesFrontiers in Chemistry, 6
Aaron Pierpont, E. Batista, R. Martin, Wei-zhong Chen, J. Kim, Caroline Hoyt, J. Gordon, R. Michalczyk, L. Silks, Ruilian Wu (2015)
Origins of the Regioselectivity in the Lutetium Triflate Catalyzed Ketalization of Acetone with Glycerol: A DFT StudyACS Catalysis, 5
Yanna Liang, Yi Cui, J. Trushenski, J. Blackburn (2010)
Converting crude glycerol derived from yellow grease to lipids through yeast fermentation.Bioresource technology, 101 19
A. Hasabnis, S. Mahajani (2014)
Acetalization of Glycerol with Formaldehyde by Reactive DistillationIndustrial & Engineering Chemistry Research, 53
K. Pathak, K. Reddy, N. Bakhshi, A. Dalai (2010)
Catalytic conversion of glycerol to value added liquid productsApplied Catalysis A-general, 372
Baithy Mallesham, Putla Sudarsanam, B. Reddy (2014)
Eco-friendly synthesis of bio-additive fuels from renewable glycerol using nanocrystalline SnO2-based solid acidsCatalysis Science & Technology, 4
Z. Ullah, A. Khan, N. Muhammad, R. Ullah, A. Alqahtani, S. Shah, O. Ghanem, M. Bustam, Z. Man (2018)
A review on ionic liquids as perspective catalysts in transesterification of different feedstock oil into biodieselJournal of Molecular Liquids
M. Haas, A. Mcaloon, W. Yee, T. Foglia (2006)
A process model to estimate biodiesel production costs.Bioresource technology, 97 4
Elena-Emilia Oprescu, E. Stepan, Raluca-Elena Dragomir, A. Radu, Paul Rosca (2013)
Synthesis and testing of glycerol ketals as components for diesel fuelFuel Processing Technology, 110
R. Pawar, Sumit Jadhav, H. Bajaj (2014)
Microwave-assisted rapid valorization of glycerol towards acetals and ketalsChemical Engineering Journal, 235
M. Guemez, J. Requies, I. Agirre, P. Arias, V. Barrio, J. Cambra (2013)
Acetalization reaction between glycerol and n-butyraldehyde using an acidic ion exchange resin. Kinetic modellingChemical Engineering Journal, 228
D. He, Zhan-Jiang Li, Z. Li, Yunpeng Liu, Dong-Xu Qiu, M. Cai (1992)
Studies on Carbohydrates X. A New Method for the Preparation of Isopropylidene SaccharidesSynthetic Communications, 22
M. Timofeeva, V. Panchenko, V. Krupskaya, A. Gil, M. Vicente (2017)
Effect of nitric acid modification of montmorillonite clay on synthesis of solketal from glycerol and acetoneCatalysis Communications, 90
I. Agirre, M. Güemez, A. Ugarte, J. Requies, V. Barrio, J. Cambra, P. Arias (2013)
Glycerol acetals as diesel additives: Kinetic study of the reaction between glycerol and acetaldehydeFuel Processing Technology, 116
C. Silva, C. Mota (2011)
The influence of impurities on the acid-catalyzed reaction of glycerol with acetoneBiomass & Bioenergy, 35
X. Hong, Omar McGiveron, A. Kolah, Álvaro Orjuela, Lars Peereboom, C. Lira, Dennis Miller (2013)
Reaction kinetics of glycerol acetal formation via transacetalization with 1,1-diethoxyethaneChemical Engineering Journal, 222
Gervásio Silva, J. Contiero, P. Neto, C. Lima (2014)
1,3-propanodiol: produção, aplicações e potencial biotecnológicoQuímica Nova, 37
A. Rabie, M. Shaban, Mostafa Abukhadra, R. Hosny, S. Ahmed, N. Negm (2019)
Diatomite supported by CaO/MgO nanocomposite as heterogeneous catalyst for biodiesel production from waste cooking oilJournal of Molecular Liquids
T. Souza, M. Portilho, Priscila Souza, P. Souza, L. Oliveira (2014)
Modified Niobium Oxyhydroxide Catalyst: An Acetalization Reaction to Produce Bio‐additives for Sustainable Use of Waste GlycerolChemCatChem, 6
Malaya Nanda, Zhongshun Yuan, W. Qin, H. Ghaziaskar, M. Poirier, C. Xu (2014)
A new continuous-flow process for catalytic conversion of glycerol to oxygenated fuel additive: Catalyst screeningApplied Energy, 123
Farook Adam, M. Batagarawa, K. Hello, S. Al-Juaid (2012)
One-step synthesis of solid sulfonic acid catalyst and its application in the acetalization of glycerol: crystal structure of cis-5-hydroxy-2-phenyl-1,3-dioxane trimerChemical Papers, 66
B. Jiang, Lin Li, Zhoufeng Bian, Ziwei Li, Yang Sun, Zhehao Sun, Dawei Tang, S. Kawi, Binlin Dou, M. Goula (2018)
Chemical looping glycerol reforming for hydrogen production by Ni@ZrO2 nanocomposite oxygen carriersInternational Journal of Hydrogen Energy
M. Fazal, A. Haseeb, H. Masjuki (2011)
Biodiesel feasibility study: An evaluation of material compatibility; performance; emission and engine durabilityRenewable & Sustainable Energy Reviews, 15
Imtisal Zahid, M. Ayoub, Bawadi Abdullah, M. Nazir, M. Ameen, Zulqarnain, Mohd Yusoff, A. Inayat, M. Danish (2020)
Production of Fuel Additive Solketal via Catalytic Conversion of Biodiesel-Derived GlycerolIndustrial & Engineering Chemistry Research, 59
T. Souza, Izabela Padula, Mariana Teodoro, Poliane Chagas, J. Resende, P. Souza, L. Oliveira (2015)
Amphiphilic property of niobium oxyhydroxide for waste glycerol conversion to produce solketalCatalysis Today, 254
Duane Johnson, Katherine Taconi (2007)
The glycerin glut: Options for the value‐added conversion of crude glycerol resulting from biodiesel productionEnvironmental Progress, 26
P. Koch, C. Vedder, T. Schaffer (2009)
Propylphosphonic Acid Anhydride: A Highly Expedient and Versatile Coupling AgentChemInform, 40
E. Fischer, Ernst Pfähler (1920)
Über Glycerin-aceton und seine Verwendbarkeit zur Reindarstellung von α-Glyceriden; über eine Phosphorsäure-Verbindung des GlykolsEuropean Journal of Inorganic Chemistry, 53
J. Monbaliu, M. Winter, B. Chevalier, F. Schmidt, Yi Jiang, R. Hoogendoorn, M. Kousemaker, C. Stevens (2011)
Effective production of the biodiesel additive STBE by a continuous flow process.Bioresource technology, 102 19
Fernanda Menezes, Matheus Guimaraes, M. Silva (2013)
Highly Selective SnCl2-Catalyzed Solketal Synthesis at Room TemperatureIndustrial & Engineering Chemistry Research, 52
J. Kowalska‐Kuś, A. Held, M. Frankowski, K. Nowiǹska (2017)
Solketal formation from glycerol and acetone over hierarchical zeolites of different structure as catalystsJournal of Molecular Catalysis A-chemical, 426
G. Nair, E. Adrijanto, A. Alsalme, I. Kozhevnikov, D. Cooke, David Brown, N. Shiju (2012)
Glycerol utilization: solvent-free acetalisation over niobia catalystsCatalysis Science & Technology, 2
Xiaoying Liu, P. Jensen, M. Workman (2012)
Bioconversion of crude glycerol feedstocks into ethanol by Pachysolen tannophilus.Bioresource technology, 104
M. Monteiro, C. Kugelmeier, Rafael Pinheiro, M. Batalha, A. César (2018)
Glycerol from biodiesel production: technological paths for sustainability.Renewable & Sustainable Energy Reviews, 88
Luis Rincón, J. Jaramillo, C. Cardona (2014)
Comparison of feedstocks and technologies for biodiesel production: An environmental and techno-economic evaluationRenewable Energy, 69
M. Torres, Gonzalo Jiménez‐Osés, J. Mayoral, E. Pires (2011)
Fatty acid derivatives and their use as CFPP additives in biodiesel.Bioresource technology, 102 3
P. Dhepe, R. Sahu (2010)
A solid-acid-based process for the conversion of hemicelluloseGreen Chemistry, 12
Nilesh Narkhede, Anjali Patel (2014)
Room temperature acetalization of glycerol to cyclic acetals over anchored silicotungstates under solvent free conditionsRSC Advances, 4
T. Noël, S. Buchwald (2011)
Cross-coupling in flow.Chemical Society reviews, 40 10
Zhenbin Li, Zhichao Miao, Xuan Wang, Jinping Zhao, Jin Zhou, Weijiang Si, Shuping Zhuo (2018)
One-pot synthesis of ZrMo-KIT-6 solid acid catalyst for solvent-free conversion of glycerol to solketalFuel
Siqian Zhang, Zhenbo Zhao, Y. Ao (2015)
Design of highly efficient Zn-, Cu-, Ni- and Co-promoted M-AlPO4 solid acids: The acetalization of glycerol with acetoneApplied Catalysis A-general, 496
Jesús Esteban, M. González-Miquel (2018)
Thermodynamic insights on the viscometric and volumetric properties of binary mixtures of ketals and polyolsJournal of Molecular Liquids
Subhash Magar, G. Mohanraj, S. Jana, C. Rode (2020)
Synthesis and characterization of supported heteropoly acid: Efficient solid acid catalyst for glycerol esterification to produce biofuel additivesInorganic and Nano-Metal Chemistry, 50
Jaturong Jitputti, B. Kitiyanan, P. Rangsunvigit, Kunchana Bunyakiat, L. Attanatho, P. Jenvanitpanjakul (2006)
Transesterification of crude palm kernel oil and crude coconut oil by different solid catalystsChemical Engineering Journal, 116
Bo Wang, Yue Shen, Jiankui Sun, Feng Xu, R. Sun (2014)
Conversion of platform chemical glycerol to cyclic acetals promoted by acidic ionic liquidsRSC Advances, 4
M. Khayoon, A. Abbas, B. Hameed, S. Triwahyono, A. Jalil, A. Harris, A. Minett (2014)
Selective Acetalization of Glycerol with Acetone Over Nickel Nanoparticles Supported on Multi-Walled Carbon NanotubesCatalysis Letters, 144
J. Deutsch, Andreas Martin, H. Lieske (2007)
Investigations on heterogeneously catalysed condensations of glycerol to cyclic acetalsJournal of Catalysis, 245
Marcio Silva, A. Rodrigues, P. Pinheiro (2020)
Solketal synthesis from glycerol and acetone in the presence of metal salts: A Lewis or Brønsted acid catalyzed reaction?Fuel, 276
Benjamin Wegenhart, Shuo Liu, M.M.M. Thom, David Stanley, M. Abu‐Omar (2012)
Solvent-Free Methods for Making Acetals Derived from Glycerol and Furfural and Their Use as a Biodiesel Fuel ComponentACS Catalysis, 2
M. Newman, M. Renoll (1945)
Improved Preparation of Isopropylidene GlycerolJournal of the American Chemical Society, 67
P. Manjunathan, S. Maradur, A. Halgeri, G. Shanbhag (2015)
Room temperature synthesis of solketal from acetalization of glycerol with acetone: Effect of crystallite size and the role of acidity of beta zeoliteJournal of Molecular Catalysis A-chemical, 396
Malaya Nanda, Zhongshun Yuan, W. Qin, H. Ghaziaskar, M. Poirier, C. Xu (2014)
Thermodynamic and kinetic studies of a catalytic process to convert glycerol into solketal as an oxygenated fuel additiveFuel, 117
S. Umbarkar, Trupti Kotbagi, Ankush Biradar, R. Pasricha, Jyoti Chanale, M. Dongare, A. Mamede, C. Lancelot, E. Payen (2009)
Acetalization of glycerol using mesoporous MoO3/SiO2 solid acid catalystJournal of Molecular Catalysis A-chemical, 310
K. Jähnisch, V. Hessel, H. Löwe, M. Baerns (2004)
Chemistry in microstructured reactors.Angewandte Chemie, 43 4
G. Vicente, J. Melero, G. Morales, M. Paniagua, Eric Martín (2010)
Acetalisation of bio-glycerol with acetone to produce solketal over sulfonic mesostructured silicas.Green Chemistry, 12
Malaya Nanda, Zhongshun Yuan, W. Qin, H. Ghaziaskar, M. Poirier, C. Xu (2014)
Catalytic conversion of glycerol to oxygenated fuel additive in a continuous flow reactor: Process optimizationFuel, 128
Luqian Chen, Jun Liang, Hong Lin, W. Weng, H. Wan, J. Védrine (2005)
MCM41 and silica supported MoVTe mixed oxide catalysts for direct oxidation of propane to acroleinApplied Catalysis A-general, 293
Jean-Pierre Mbakidi, S. Bouquillon (2018)
Glycerol-based ionic liquids: Crucial microwaves-assisted synthetic step for solketal aminesJournal of Molecular Liquids, 252
C. Mota, C. Silva, Nilton Rosenbach, Jair Costa, Flávia Silva (2010)
Glycerin Derivatives as Fuel Additives: The Addition of Glycerol/Acetone Ketal (Solketal) in GasolinesEnergy & Fuels, 24
J. Thompson, B. He (2006)
Characterization of crude glycerol from biodiesel production from multiple feedstocks.Applied Engineering in Agriculture, 22
P. Saxena, S. Jawale, Milind Joshipura (2013)
A Review on Prediction of Properties of Biodiesel and Blends of BiodieselProcedia Engineering, 51
H. Prakruthi, B. Chandrashekara, B. Prakash, Y. Bhat (2015)
Microwave rehydrated Mg–Al-LDH as base catalyst for the acetalization of glycerolCatalysis Science & Technology, 5
M. Silva, F. Rodrigues, A. Júlio (2017)
SnF2-catalyzed glycerol ketalization: A friendly environmentally process to synthesize solketal at room temperature over on solid and reusable Lewis acidChemical Engineering Journal, 307
M. Silva, Diego Chaves, A. Júlio, F. Rodrigues, C. Bruziquesi (2020)
Sn(II)-Exchanged Keggin Silicotungstic Acid-Catalyzed Etherification of Glycerol and Ethylene Glycol with Alkyl AlcoholsIndustrial & Engineering Chemistry Research, 59
G. Silva, C. Lima, J. Contiero (2015)
Production and productivity of 1,3-propanediol from glycerol by Klebsiella pneumoniae GLC29Catalysis Today, 257
M. Torres, Gonzalo Jiménez‐Osés, J. Mayoral, E. Pires, M. Santos (2012)
Glycerol ketals: Synthesis and profits in biodiesel blendsFuel, 94
Sugeng Mujiyanto, G. Tiess (2013)
Secure energy supply in 2025: Indonesia's need for an energy policy strategyEnergy Policy, 61
C. Callam, S. Singer, T. Lowary, C. Hadad (2001)
Computational analysis of the potential energy surfaces of glycerol in the gas and aqueous phases: effects of level of theory, basis set, and solvation on strongly intramolecularly hydrogen-bonded systems.Journal of the American Chemical Society, 123 47
A. Trifoi, P. Agachi, T. Pap (2016)
Glycerol acetals and ketals as possible diesel additives. A review of their synthesis protocolsRenewable & Sustainable Energy Reviews, 62
Violeta Ruiz, A. Velty, Laura Santos, A. Leyva–Pérez, M. Sabater, S. Iborra, A. Corma (2010)
Gold catalysts and solid catalysts for biomass transformations: Valorization of glycerol and glycerol–water mixtures through formation of cyclic acetalsJournal of Catalysis, 271
C. Zhou, C. Zhou, J. Beltramini, Yong-xian Fan, G. Lu (2008)
Chemoselective catalytic conversion of glycerol as a biorenewable source to valuable commodity chemicals.Chemical Society reviews, 37 3
E. Mertsoy, E. Sert, S. Atalay, F. Atalay (2021)
Fabrication of chromium based metal organic framework (MIL-101)/activated carbon composites for acetylation of glycerolJournal of The Taiwan Institute of Chemical Engineers
Mahboube Shirani, H. Ghaziaskar, C. Xu (2014)
Optimization of glycerol ketalization to produce solketal as biodiesel additive in a continuous reactor with subcritical acetone using Purolite® PD206 as catalystFuel Processing Technology, 124
Malaya Nanda, Yongsheng Zhang, Zhongshun Yuan, W. Qin, H. Ghaziaskar, C. Xu (2016)
Catalytic conversion of glycerol for sustainable production of solketal as a fuel additive: A reviewRenewable & Sustainable Energy Reviews, 56
S. Sandesh, A. Halgeri, G. Shanbhag (2015)
Utilization of renewable resources: Condensation of glycerol with acetone at room temperature catalyzed by organic–inorganic hybrid catalystJournal of Molecular Catalysis A-chemical, 401
Teresa Cablewski, A. Faux, C. Strauss (1994)
Development and Application of a Continuous Microwave Reactor for Organic SynthesisJournal of Organic Chemistry, 59
C. Silva, Valter Gonçalves, C. Mota (2009)
Water-tolerant zeolite catalyst for the acetalisation of glycerolGreen Chemistry, 11
Y. Izumi, Katsunori Hisano, Tomoko Hida (1999)
Acid catalysis of silica-included heteropolyacid in polar reaction mediaApplied Catalysis A-general, 181
S. Chavan, P. Zubaidha, S. Dantale, A. Keshavaraja, A. Ramaswamy, T. Ravindranathan (1996)
Use of solid superacid (sulphated SnO2) as efficient catalyst in tacile transesterification of ketoestersTetrahedron Letters, 37
M. Khayoon, B. Hameed (2013)
Solventless acetalization of glycerol with acetone to fuel oxygenates over Ni–Zr supported on mesoporous activated carbon catalystApplied Catalysis A-general, 464
A. Maksimov, A. Nekhaev, D. Ramazanov, Y. Arinicheva, A. Dzyubenko, S. Khadzhiev (2011)
Preparation of high-octane oxygenate fuel components from plant-derived polyolsPetroleum Chemistry, 51
C. Crotti, Erica Farnetti, N. Guidolin (2010)
Alternative intermediates for glycerol valorization: iridium-catalyzed formation of acetals and ketalsGreen Chemistry, 12
J. Clarkson, A. Walker, M. Wood (2001)
Continuous Reactor Technology for Ketal Formation: An Improved Synthesis of SolketalOrganic Process Research & Development, 5
Narinthorn Suriyaprapadilok, B. Kitiyanan (2011)
Synthesis of solketal from glycerol and its reaction with benzyl alcoholEnergy Procedia, 9
Chunni Fan, Cheng-hua Xu, Chuanqi Liu, Zun-Yu Huang, Jianying Liu, Zhixiang Ye (2012)
Catalytic acetalization of biomass glycerol with acetone over TiO2–SiO2 mixed oxidesReaction Kinetics, Mechanisms and Catalysis, 107
L. Roldán, R. Mallada, J. Fraile, J. Mayoral, M. Menéndez (2009)
Glycerol upgrading by ketalization in a zeolite membrane reactorAsia-Pacific Journal of Chemical Engineering, 4
Marcio Silva, Matheus Guimaraes, A. Júlio (2015)
A Highly Regioselective and Solvent-Free Sn(II)-Catalyzed Glycerol Ketals Synthesis at Room TemperatureCatalysis Letters, 145
T. Illg, P. Löb, V. Hessel (2010)
Flow chemistry using milli- and microstructured reactors-from conventional to novel process windows.Bioorganic & medicinal chemistry, 18 11
Eva García, Miriam Laca, E. Pérez, A. Garrido, J. Peinado (2008)
New Class of Acetal Derived from Glycerin as a Biodiesel Fuel ComponentEnergy & Fuels, 22
E. Fischer
Ueber die Verbindungen der Zucker mit den Alkoholen und KetonenEuropean Journal of Inorganic Chemistry, 28
Huy Nguyen-Phu, E. Shin (2018)
Investigating time-dependent Zn species over Zn-based catalysts in glycerol carbonylation with urea and their roles in the reaction mechanismApplied Catalysis A: General
M. Gonçalves, R. Rodrigues, Thalita Galhardo, W. Carvalho (2016)
Highly selective acetalization of glycerol with acetone to solketal over acidic carbon-based catalysts from biodiesel wasteFuel, 181
H. Serafim, I. Fonseca, A. Ramos, J. Vital, J. Castanheiro (2011)
Valorization of glycerol into fuel additives over zeolites as catalystsChemical Engineering Journal, 178
P. Ferreira, I. Fonseca, A. Ramos, J. Vital, J. Castanheiro (2010)
Valorisation of glycerol by condensation with acetone over silica-included heteropolyacidsApplied Catalysis B-environmental, 98
T. Razzaq, C. Kappe (2010)
Continuous flow organic synthesis under high-temperature/pressure conditions.Chemistry, an Asian journal, 5 6
M. Pagliaro, R. Ciriminna, H. Kimura, M. Rossi, C. Pina (2007)
From glycerol to value-added products.Angewandte Chemie, 46 24
Lujie Liu, Takehiro Asano, Y. Nakagawa, M. Tamura, K. Okumura, K. Tomishige (2019)
Selective Hydrogenolysis of Glycerol to 1,3-Propanediol over Rhenium-Oxide-Modified Iridium Nanoparticles Coating Rutile Titania SupportACS Catalysis
K. Alali, F. Lebsir, Sondes Amri, A. Rahmouni, E. Srasra, N. Besbes (2019)
Algerian Acid Activated Clays as Efficient Catalysts for a Green Synthesis of Solketal by Chemoselective Acetalization of Glycerol with AcetoneBulletin of Chemical Reaction Engineering & Catalysis
I. Agirre, I. Garcia, J. Requies, V. Barrio, M. Güemez, J. Cambra, P. Arias (2011)
Glycerol acetals, kinetic study of the reaction between glycerol and formaldehydeBiomass & Bioenergy, 35
Brendan Smith, T. Kubczyk, A. Graham (2012)
Metal triflate catalysed acetal exchange reactions of glycerol under solvent-free conditionsRSC Advances, 2
V. Hessel, Iris Vural Gürsel, Qi Wang, Timothy Noël, Jürgen Lang (2012)
Potenzialanalyse von Milli- und Mikroprozesstechniken für die Verkürzung von Prozessentwicklungszeiten : Chemie und Prozessdesign als IntensivierungsfelderChemie Ingenieur Technik, 84
Ryan Hartman, J. McMullen, K. Jensen (2011)
Deciding whether to go with the flow: evaluating the merits of flow reactors for synthesis.Angewandte Chemie, 50 33
A significant amount of glycerol has been generated by the epidemic increment in several biodiesel industries globally, which should be utilized for the biodiversity of biodiesel. The synthesis of Solketal‐acetone glycerol as a possible fuel additive is one of the most crucial glycerol recovery paths. State‐of‐the‐art reviews on batch and continuous processes to produce Solketal and possible reaction mechanisms are presented. The design of reactors and catalysts is taken into consideration and the factors influencing the yield of the Solketal process are discussed in detail. Finally, conclusions with future recommendations are reported. The utility of glycerol for acetals and ketals is of current importance for scientists seeking to find the best working conditions by testing the different catalysts, reactants, temperatures, and reactor designs.
Chembioeng Reviews – Wiley
Published: Jun 1, 2021
Keywords: ; ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.