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From heterobimetallic transition metal complexes to linear coordination polymers based on cis ‐ and trans ‐L 2 Pt(CCPh) 2

From heterobimetallic transition metal complexes to linear coordination polymers based on cis ‐... The reaction of cis‐(2,2′‐bipyridine) Pt(CCPh)2 cis‐(4,4′‐dimethyl‐2,2′‐bipyridine) Pt‐(CCPh)2 and trans‐(Ph3P)2Pt(CCPh)2 towards different group 11 transition‐metal salts (M′X) (M′ = Cu, Ag; X = inorganic ligand) to give heterobimetallic or linear oligomeric and polymeric transition metal complexes is described. Different coordination modes for M′, PhCC, PPh3, and X were found in these species. The structural aspects as well as the preference for one coordination mode over another is discussed. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:521–533, 2002; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10097 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

From heterobimetallic transition metal complexes to linear coordination polymers based on cis ‐ and trans ‐L 2 Pt(CCPh) 2

Heteroatom Chemistry , Volume 13 (6) – Jan 1, 2002

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References (87)

Publisher
Wiley
Copyright
Copyright © 2002 Wiley Periodicals, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.10097
Publisher site
See Article on Publisher Site

Abstract

The reaction of cis‐(2,2′‐bipyridine) Pt(CCPh)2 cis‐(4,4′‐dimethyl‐2,2′‐bipyridine) Pt‐(CCPh)2 and trans‐(Ph3P)2Pt(CCPh)2 towards different group 11 transition‐metal salts (M′X) (M′ = Cu, Ag; X = inorganic ligand) to give heterobimetallic or linear oligomeric and polymeric transition metal complexes is described. Different coordination modes for M′, PhCC, PPh3, and X were found in these species. The structural aspects as well as the preference for one coordination mode over another is discussed. © 2002 Wiley Periodicals, Inc. Heteroatom Chem 13:521–533, 2002; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10097

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 2002

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