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References (4)
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F. Pietra (1965)
The relative reactivity of fluoro- and chloro-2,4-dinitrobenzenes in their reactions with aminesTetrahedron Letters, 6
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K. Tang, Tianbing Xia, Xianglin Jin, Youqi Tang (1993)
Formation and x-ray structure of a novel tetradecanuclear copper(I) cluster complex Cu14(μ2-S)(SPh)12(PPh3)6Polyhedron, 12
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P. Eller, R. Ryan (1977)
Bis(triphenylphosphine)(phenyl trithiocarbonato)copper(I) hemi(carbon disulfide)Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 33
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K. Peters, W. Ott, H. Schnering (1982)
[Ag5I6]−, A One‐Dimensional Infinite Anion with 105 mc SymmetryAngewandte Chemie, 21
- Publisher
- Wiley
- Copyright
- Copyright © 1995 Wiley Subscription Services
- ISSN
- 1042-7163
- eISSN
- 1098-1071
- DOI
- 10.1002/hc.520060110
- Publisher site
- See Article on Publisher Site
Abstract
Compounds [(Ph3P)2AgS2CSR (R = But, TIPT(2,4,6‐triisopropylthiophenolato))], formed by inserting CS2 into the Ag–S bond in AgSR in the presence of PPh3, react with CH2I2 to give pale yellow crystals of (Ag5I6)n(Ph3PCH2I)n, which consist of the polymeric anion (Ag5I6)n− and the cation (Ph3PCH2)+. The polyanion (Ag5I6)n− is composed of alternate I5‐pentagons and Ag5‐pentagons that are connected by Ag–I bonds along the C axis to form a layered “pagoda” structure, in which there exists an unusual stereochemistry of iodine. Crystal data: monoclinic, space group P21/c, a = 15.004(12) Å, b = 27.19(2) Å, c = 7.898 Å, β = 97.18(5)°, V = 3205(4) Å3, Z = 4, R = 0.0673 for 2726 observed reflections.
Journal
Heteroatom Chemistry – Wiley
Published: Jan 1, 1995