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References (12)
-
J. Kollonitsch, S. Marburg, L. Perkins (1976)
Fluorodesulfurization. A new reaction for the formation of carbon-fluorine bondsJournal of Organic Chemistry, 41
-
D. Matthews, J. Whitten, J. Mccarthy (1986)
A facile synthesis of aromatic trifluoromethyl compounds via orthothio estersTetrahedron Letters, 27
-
S. Knapp, Adrea Trope, R. Ornaf (1981)
Ring expansion of ketones to 1,2-keto-thioketalsTetrahedron Letters, 21
-
M. Ramezanian, A. Padías, F. Saeva, H. Hall (1990)
Synthesis and reactions of highly electrophilic imines containing the N-cyano groupJournal of Organic Chemistry, 55
-
Susan Sondej, J. Katzenellenbogen (1986)
gem-Difluoro compounds: a convenient preparation from ketones and aldehydes by halogen fluoride treatment of 1,3-dithiolanesJournal of Organic Chemistry, 51
-
S. Purrington, J. Pittman (1987)
The Preparation of α-Fluorosulfoxides and Vinyl FluoridesTetrahedron Letters, 28
-
Kyung-Il Kim, J. Mccarthy (1996)
A new route to 1,1-difluoroolefins from carboxylic acidsTetrahedron Letters, 37
-
R. Damon, R. Schlessinger (1976)
An efficient and stereospecific total synthesis of dl-protolichesterinic acidTetrahedron Letters, 17
-
W. Bunnelle, B. McKinnis, B. Narayanan (1990)
Difluorination of esters. Preparation of .alpha.,.alpha.-difluoro ethersJournal of Organic Chemistry, 55
-
M. Kuroboshi*, Satoru Furuta, T. Hiyama (1995)
Oxidative Desulfurization-Fluorination of 1-Substituted 2,2,2-Tris( methylthio)ethanol Induces Difluorination under Oxidation or Rearrangement.ChemInform, 26
-
K. Nicolaou, E. DolleRoland, D. Papahatjis (1984)
Practical synthesis of oligosaccharides. Partial synthesis of avermectin B1aChemInform, 15
-
Satoru Furuta, T. Hiyama (1996)
Difluorination of 2-substituted 1,1,1-tris(methylthio)ethanes by oxidative desulfurization-fluorination. A new route to partially fluorinated olefinsTetrahedron Letters, 37
- Publisher
- Wiley
- Copyright
- Copyright © 1999 John Wiley & Sons, Inc.
- ISSN
- 1042-7163
- eISSN
- 1098-1071
- DOI
- 10.1002/(SICI)1098-1071(1999)10:1<31::AID-HC6>3.0.CO;2-6
- Publisher site
- See Article on Publisher Site
Abstract
In contrast with aromatic orthothio esters that undergo desulfurative fluorination to produce trifluoromethyl substituted aromatics, aliphatic orthothio esters react with BrF with replacement of only one or two methylthio groups by fluorine. An elimination step often follows the first sulfur replacement to produce novel unsaturated fluorinated systems. © 1999 John Wiley & Sons, Inc. Heteroatom Chem 10: 31–34, 1999
Journal
Heteroatom Chemistry – Wiley
Published: Jan 1, 1999