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Kylee Harris, R. Grim, Zhe Huang, Ling Tao (2021)
A comparative techno-economic analysis of renewable methanol synthesis from biomass and CO2: Opportunities and barriers to commercializationApplied Energy, 303
Qinglei Wu, Chenyang Shen, Ning Rui, Kaihang Sun, Chang-jun Liu (2021)
Experimental and theoretical studies of CO2 hydrogenation to methanol on Ru/In2O3Journal of CO2 Utilization
M. Wagner, B. Meyer, M. Setvín, M. Schmid, U. Diebold (2021)
Direct assessment of the acidity of individual surface hydroxylsNature, 592
H. Idriss (2021)
On the wrong assignment of the XPS O1s signal at 531–532 eV attributed to oxygen vacancies in photo- and electro-catalysts for water splitting and other materials applicationsSurface Science, 712
Ning Rui, Feng Zhang, Kaihang Sun, Zongyuan Liu, Wenqian Xu, E. Stavitski, S. Senanayake, J. Rodríguez, Chang-jun Liu (2020)
Hydrogenation of CO2 to Methanol on a Auδ+–In2O3–x CatalystACS Catalysis, 10
(1994)
Lide, CRC Handbook of Chemistry and Physics
Goeppert A. (2014)
7995Chem. Soc. Rev., 43
Ning Rui, Zongyuan Wang, Kaihang Sun, Jingyun Ye, Q. Ge, Chang-jun Liu (2017)
CO2 hydrogenation to methanol over Pd/In2O3: effects of Pd and oxygen vacancyApplied Catalysis B-environmental, 218
Shipeng Ding, Hsi-An Chen, O. Mekasuwandumrong, Max Hülsey, Xinpu Fu, Qian He, J. Panpranot, Chia‐Min Yang, N. Yan (2021)
High-temperature flame spray pyrolysis induced stabilization of Pt single-atom catalystsApplied Catalysis B-environmental, 281
Boreum Lee, Hyunjun Lee, Dongjun Lim, B. Brigljević, W. Cho, Hyun-Seok Cho, Chang‐Hee Kim, Hankwon Lim (2020)
Renewable methanol synthesis from renewable H2 and captured CO2: How can power-to-liquid technology be economically feasible?Applied Energy, 279
M. Álvarez-Moreno, C. Graaf, N. López, F. Maseras, J. Poblet, C. Bo (2015)
Managing the Computational Chemistry Big Data Problem: The ioChem-BD PlatformJournal of chemical information and modeling, 55 1
González‐Garay A. (2019)
3425Energy Environ. Sci., 12
Xinyu Jia, Kaihang Sun, Jing Wang, Chenyang Shen, Chang-jun Liu (2020)
Selective hydrogenation of CO2 to methanol over Ni/In2O3 catalystJournal of Energy Chemistry, 50
G. Kresse, J. Furthmüller (1996)
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis setComputational Materials Science, 6
A. Bavykina, I. Yarulina, Abdullah Abdulghani, L. Gevers, M. Hedhili, Xiaohe Miao, A. Galilea, A. Pustovarenko, A. Dikhtiarenko, A. Cadiau, A. Aguilar-Tapia, J. Hazemann, S. Kozlov, Samy Oud-Chikh, L. Cavallo, J. Gascón (2019)
Turning a Methanation Co Catalyst into an In–Co Methanol ProducerACS Catalysis
A. Gröhn, S. Pratsinis, A. Sánchez‐Ferrer, R. Mezzenga, K. Wegner (2014)
Scale-up of Nanoparticle Synthesis by Flame Spray Pyrolysis: The High-Temperature Particle Residence TimeIndustrial & Engineering Chemistry Research, 53
Sun K. (2020)
5059Green Chem., 22
M. Frei, Marçal Capdevila-Cortada, R. Garcı́a-Muelas, C. Mondelli, N. López, J. Stewart, D. Ferré, J. Pérez–Ramírez (2018)
Mechanism and microkinetics of methanol synthesis via CO2 hydrogenation on indium oxideJournal of Catalysis, 361
A. Walsh, C. Catlow (2010)
Structure, stability and work functions of the low index surfaces of pure indium oxide and Sn-doped indium oxide (ITO) from density functional theoryJournal of Materials Chemistry, 20
C. Janowitz, Valentina Scherer, M. Mohamed, A. Krapf, H. Dwelk, R. Manzke, Z. Galazka, R. Uecker, K. Irmscher, R. Fornari, M. Michling, D. Schmeißer, J. Weber, J. Varley, C. Walle (2011)
Experimental electronic structure of In2O3 and Ga2O3New Journal of Physics, 13
G. Henkelman, B. Uberuaga, H. Jónsson (2000)
A climbing image nudged elastic band method for finding saddle points and minimum energy pathsJournal of Chemical Physics, 113
D. Schanke, S. Vada, E. Blekkan, A. Hilmen, A. Hoff, A. Holmen (1995)
Study of Pt-promoted cobalt CO hydrogenation catalystsJournal of Catalysis, 156
E. Athanassiou, R. Grass, W. Stark (2010)
Chemical Aerosol Engineering as a Novel Tool for Material Science: From Oxides to Salt and Metal NanoparticlesAerosol Science and Technology, 44
T. Araújo, A. Shah, C. Mondelli, J. Stewart, D. Ferré, J. Pérez–Ramírez (2021)
Impact of hybrid CO2-CO feeds on methanol synthesis over In2O3-based catalystsApplied Catalysis B-environmental, 285
W. Teoh, R. Amal, L. Mädler (2010)
Flame spray pyrolysis: An enabling technology for nanoparticles design and fabrication.Nanoscale, 2 8
Dieterich V. (2020)
3207Energy Environ. Sci., 13
Zhisheng Shi, Qingqing Tan, Dongfang Wu (2019)
A novel Core–Shell structured CuIn@SiO 2 catalyst for CO 2 hydrogenation to methanolAIChE Journal
Chenyang Shen, Kaihang Sun, Zhitao Zhang, Ning Rui, Xinyu Jia, Donghai Mei, Chang-jun Liu (2021)
Highly Active Ir/In2O3 Catalysts for Selective Hydrogenation of CO2 to Methanol: Experimental and Theoretical StudiesACS Catalysis, 11
Alvaro Posada-Borbón, H. Grönbeck (2021)
A First-Principles-Based Microkinetic Study of CO2 Reduction to CH3OH over In2O3(110)ACS Catalysis
M. Frei, C. Mondelli, R. Garcı́a-Muelas, Klara Kley, B. Puértolas, N. López, O. Safonova, J. Stewart, D. Ferré, J. Pérez–Ramírez (2019)
Atomic-scale engineering of indium oxide promotion by palladium for methanol production via CO2 hydrogenationNature Communications, 10
O. Martin, A. Martín, C. Mondelli, S. Mitchell, T. Segawa, R. Hauert, C. Drouilly, D. Curulla-Ferré, J. Pérez–Ramírez (2016)
Indium Oxide as a Superior Catalyst for Methanol Synthesis by CO2 Hydrogenation.Angewandte Chemie, 55 21
P. Abdala, O. Safonova, Geir Wiker, W. Beek, H. Emerich, J. Bokhoven, Jacinto Sá, J. Szlachetko, M. Nachtegaal (2012)
Scientific opportunities for heterogeneous catalysis research at the SuperXAS and SNBL beam lines.Chimia, 66 9
Jiadong Zhu, F. Cannizzaro, Liang-Chi Liu, Hao Zhang, N. Kosinov, I. Filot, J. Rabeah, A. Brückner, E. Hensen (2021)
Ni–In Synergy in CO2 Hydrogenation to MethanolACS Catalysis, 11
Chenyang Shen, Q. Bao, Wenjuan Xue, Kaihang Sun, Zhitao Zhang, Xinyu Jia, Donghai Mei, Chang‐jun Liu
Synergistic effect of the metal-support interaction and interfacial oxygen vacancy for CO2 hydrogenation to methanol over Ni/In2O3 catalyst: a theoretical studyJournal of Energy Chemistry, 65
Ning Rui, Kaihang Sun, Chenyang Shen, Chang-jun Liu (2020)
Density functional theoretical study of Au4/In2O3 catalyst for CO2 hydrogenation to methanol: The strong metal-support interaction and its effectJournal of CO 2 Utilization, 42
D. Albani, Marçal Capdevila-Cortada, G. Vilé, S. Mitchell, O. Martin, N. López, J. Pérez–Ramírez (2017)
Semihydrogenation of Acetylene on Indium Oxide: Proposed Single-Ensemble Catalysis.Angewandte Chemie, 56 36
S. Pokhrel, L. Mädler (2020)
Flame-made Particles for Sensors, Catalysis, and Energy Storage ApplicationsEnergy & Fuels, 34
Zhe Han, Chizhou Tang, Jijie Wang, Landong Li, Can Li (2020)
Atomically dispersed Ptn+ species as highly active sites in Pt/In2O3 catalysts for methanol synthesis from CO2 hydrogenationJournal of Catalysis
J. Pérez–Ramírez, N. López (2019)
Strategies to break linear scaling relationshipsNature Catalysis
R. Grass, S. Tsantilis, S. Pratsinis (2006)
Design of high-temperature, gas-phase synthesis of hard or soft TiO2 agglomeratesAiche Journal, 52
Thomas Rudin, K. Wegner, S. Pratsinis (2011)
Uniform nanoparticles by flame-assisted spray pyrolysis (FASP) of low cost precursorsJournal of Nanoparticle Research, 13
S. Ashcroft, E. Schwarzmann (1972)
Standard enthalpy of formation of crystalline gold(III) oxideJournal of the Chemical Society, Faraday Transactions, 68
Chi Vo, C. Mondelli, Homa Hamedi, J. Pérez–Ramírez, S. Farooq, I. Karimi (2021)
Sustainability Assessment of Thermocatalytic Conversion of CO2 to Transportation Fuels, Methanol, and 1-PropanolACS Sustainable Chemistry & Engineering
M. Frei, C. Mondelli, R. Garcı́a-Muelas, Jordi Morales‐Vidal, Michelle Philipp, O. Safonova, N. López, J. Stewart, D. Ferré, J. Pérez–Ramírez (2021)
Nanostructure of nickel-promoted indium oxide catalysts drives selectivity in CO2 hydrogenationNature Communications, 12
Jing Wang, Kaihang Sun, Xinyu Jia, Chang‐jun Liu (2020)
CO2 hydrogenation to methanol over Rh/In2O3 catalystCatalysis Today
C. Bo, F. Maseras, N. López (2018)
The role of computational results databases in accelerating the discovery of catalystsNature Catalysis, 1
P. Morrison, R. Raghavan, Andrew Timpone, C. Artelt, S. Pratsinis (1997)
In Situ Fourier Transform Infrared Characterization of the Effect of Electrical Fields on the Flame Synthesis of TiO2 ParticlesChemistry of Materials, 9
A plethora of metal promoters have been applied to enhance the performance of In2O3 in CO2 hydrogenation to methanol, a prospective energy carrier. However, the lack of systematic catalyst preparation and evaluation precludes a direct comparison of their speciation and promotional effects, and consequently, the design of an optimal system. Herein, flame spray pyrolysis (FSP) is employed as a standardized synthesis method to introduce nine metal promoters (0.5 wt.%) into In2O3. Methanol productivity generally increased on M‐In2O3 with selectivity following Pd ≈ Pt > Rh ≈ Ru ≈ Ir > Ni ≈ Co > Ag ≈ In2O3 > Au. In‐depth characterization, kinetic analyses, and theoretical calculations reveal a range of metal‐dependent speciation which dictate catalyst architecture and degree of promotion. Atomically‐dispersed promoters (Pd, Pt, Rh, Ru, and Ir) grant the highest improvement in performance, particularly Pd and Pt, which markedly promote hydrogen activation while hindering undesired CO formation. In contrast, metals in clustered (Ni and Co) and nanoparticle (Ag and Au) forms display moderate and no promotion, respectively. This study provides an atomic‐level understanding of In2O3 promotion based on a unified protocol, and highlights the potential of FSP to engineer complex catalytic systems toward more efficient energy transformations.
Advanced Energy Materials – Wiley
Published: Apr 1, 2022
Keywords: CO 2 hydrogenation; green methanol; indium oxide; metal speciation; promotion
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