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- Publisher
- Wiley
- Copyright
- Copyright © 1991 Wiley Subscription Services
- ISSN
- 1042-7163
- eISSN
- 1098-1071
- DOI
- 10.1002/hc.520020607
- Publisher site
- See Article on Publisher Site
Abstract
Allylic phosphine systems were studied as phosphorus–carbon double bond precursors. 1‐Phenyl and 1‐butyl‐1‐phospha‐1,3‐dienes were generated by pyrolysis at 350–460°C of the corresponding diallyl phosphines in a stirred‐flow reactor. The unsubstituted phosphadienes generated in this manner dimerized; the formation of [4 + 2] cycloaddition products was confirmed by NMR and mass spectroscopic analysis. 31P NMR data of the 1‐phospha‐1,3‐dienes were obtained.
Journal
Heteroatom Chemistry – Wiley
Published: Jan 1, 1991