Access the full text.
Sign up today, get DeepDyve free for 14 days.
Loading next page...
/lp/wiley/experimental-and-theoretical-studies-on-the-controlled-synthesis-of-KMyx6e0T0r
References (32)
-
Shengbai Zhang, J. Northrup (1991)
Chemical potential dependence of defect formation energies in GaAs: Application to Ga self-diffusion.Physical review letters, 67 17
-
Qilin Dai, Hongwei Song, Meiyuan Wang, X. Bai, Biao Dong, Ruifei Qin, Xuesong Qu, Hui Zhang (2008)
Size and Concentration Effects on the Photoluminescence of La2O2S:Eu3+ NanocrystalsJournal of Physical Chemistry C, 112
-
B. Henderson, G. Imbusch (1989)
Optical spectroscopy of inorganic solids -
R. Si, Ya‐Wen Zhang, Huanping Zhou, Ling-Dong Sun, Chunhua Yan (2007)
Controlled-Synthesis, Self-Assembly Behavior, and Surface-Dependent Optical Properties of High-Quality Rare-Earth Oxide NanocrystalsChemistry of Materials, 19
-
Yi-fan Ding, J. Gu, Jun Ke, Ya‐Wen Zhang, Chunhua Yan (2011)
Sodium doping controlled synthesis of monodisperse lanthanide oxysulfide ultrathin nanoplates guided by density functional calculations.Angewandte Chemie, 50 51
-
J. Boyer, F. Vetrone, L. Cuccia, J. Capobianco (2006)
Synthesis of colloidal upconverting NaYF4 nanocrystals doped with Er3+, Yb3+ and Tm3+, Yb3+ via thermal decomposition of lanthanide trifluoroacetate precursors.Journal of the American Chemical Society, 128 23
-
G. Yi, W. Lee, G. Chow (2007)
Synthesis of LiYF4, BaYF5, and NaLaF4 optical nanocrystals.Journal of nanoscience and nanotechnology, 7 8
-
Guofeng Wang, Q. Peng, Yadong Li (2011)
Lanthanide-doped nanocrystals: synthesis, optical-magnetic properties, and applications.Accounts of chemical research, 44 5
-
R. Vali (2006)
Electronic, dynamical, and dielectric properties of lanthanum oxysulfideComputational Materials Science, 37
-
Yaping Du, Ya‐Wen Zhang, A. Sun, Chunhua Yan (2008)
Luminescent Monodisperse Nanocrystals of Lanthanide Oxyfluorides Synthesized from Trifluoroacetate Precursors in High-Boiling SolventsJournal of Physical Chemistry C, 112
-
Yi Ding, J. Gu, Zhang Tao, An-Xiang Yin, Lu Yang, Ya‐Wen Zhang, Chunhua Yan (2012)
Chemoaffinity-mediated synthesis of NaRES2-based nanocrystals as versatile nano-building blocks and durable nano-pigments.Journal of the American Chemical Society, 134 6
-
Ya‐Wen Zhang, X. Sun, R. Si, L. You, Chunhua Yan (2005)
Single-crystalline and monodisperse LaF3 triangular nanoplates from a single-source precursor.Journal of the American Chemical Society, 127 10
-
Yaping Du, Ya‐Wen Zhang, Ling-Dong Sun, Chunhua Yan (2009)
Atomically efficient synthesis of self-assembled monodisperse and ultrathin lanthanide oxychloride nanoplates.Journal of the American Chemical Society, 131 9
-
Zhigang Liu, Xudong Sun, Shukun Xu, J. Lian, Xiaodong Li, Z. Xiu, Qiang Li, and Huo, Ji-guang Li (2008)
Tb3+- and Eu3+-Doped Lanthanum Oxysulfide Nanocrystals. Gelatin-Templated Synthesis and Luminescence PropertiesJournal of Physical Chemistry C, 112
-
Rachel Selinsky, Jae Han, Elvin Pérez, I. Guzei, Song Jin (2010)
Synthesis and magnetic properties of Gd doped EuS nanocrystals with enhanced Curie temperatures.Journal of the American Chemical Society, 132 45
-
Feng Wang, Xiaogang Liu (2009)
Recent advances in the chemistry of lanthanide-doped upconversion nanocrystals.Chemical Society reviews, 38 4
-
J. Gu, Yi Ding, Jun Ke, Ya‐Wen Zhang, Chun-Hua Yan (2013)
Controllable Synthesis of Monodispersed Middle and Heavy Rare Earth Oxysulfide Nanoplates Based on the Principles of HSAB TheoryActa Chimica Sinica, 71
-
S. Wei, Shengbai Zhang, A. Zunger (1999)
Effects of Na on the electrical and structural properties of CuInSe2Journal of Applied Physics, 85
-
S. Eliseeva, J. Bünzli (2010)
Lanthanide luminescence for functional materials and bio-sciences.Chemical Society reviews, 39 1
-
Yaping Du, Ya‐Wen Zhang, Zheng-Guang Yan, Ling-Dong Sun, Chunhua Yan (2009)
Highly luminescent self-organized sub-2-nm EuOF nanowires.Journal of the American Chemical Society, 131 45
-
Y. Cao (2004)
Synthesis of square gadolinium-oxide nanoplates.Journal of the American Chemical Society, 126 24
-
X. Sun, Ya‐Wen Zhang, Yaping Du, Zheng-Guang Yan, R. Si, L. You, Chunhua Yan (2007)
From trifluoroacetate complex precursors to monodisperse rare-earth fluoride and oxyfluoride nanocrystals with diverse shapes through controlled fluorination in solution phase.Chemistry, 13 8
-
J. Bünzli (2010)
Lanthanide luminescence for biomedical analyses and imaging.Chemical reviews, 110 5
-
H. Mai, Ya‐Wen Zhang, R. Si, Zheng-Guang Yan, Ling-Dong Sun, L. You, Chunhua Yan (2006)
High-quality sodium rare-earth fluoride nanocrystals: controlled synthesis and optical properties.Journal of the American Chemical Society, 128 19
-
Hongshang Peng, Shi-hua Huang, Fang-tian You, Jianjun Chang, Shaozhe Lu, L. Cao (2005)
Preparation and surface effect analysis of trivalent europium-doped nanocrystalline La2O2S.The journal of physical chemistry. B, 109 12
-
F. Zhao, M. Yuan, Wen Zhang, Song Gao (2006)
Monodisperse lanthanide oxysulfide nanocrystals.Journal of the American Chemical Society, 128 36
-
J. Dhanaraj, M. Geethalakshmi, R. Jagannathan, T. Kutty (2004)
Eu3+ doped yttrium oxysulfide nanocrystals – crystallite size and luminescence transition(s)Chemical Physics Letters, 387
-
F. Zhao, Song Gao (2008)
Pyrolysis of single molecular precursor for monodisperse lanthanide sulfide/oxysulfide nanocrystalsJournal of Materials Chemistry, 18
-
T. Mirkovic, M. Hines, and Nair, G. Scholes (2005)
Single-Source Precursor Route for the Synthesis of EuS NanocrystalsChemistry of Materials, 17
-
R. Pearson (1963)
HARD AND SOFT ACIDS AND BASESJournal of the American Chemical Society, 85
-
R. Si, Ya‐Wen Zhang, L. You, Chunhua Yan (2005)
Rare-earth oxide nanopolyhedra, nanoplates, and nanodisks.Angewandte Chemie, 44 21
-
R. Shannon (1976)
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenidesActa Crystallographica Section A, 32
- Publisher
- Wiley
- Copyright
- Copyright © 2013 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 2192-6506
- eISSN
- 2192-6506
- DOI
- 10.1002/cplu.201300092
- Publisher site
- See Article on Publisher Site
Abstract
Alkali‐metal (Li, Na, K)‐doped lanthanum oxysulfide nanoplates were obtained in the hexagonal phase by thermolysis of metal acetylacetonates in organic solvents with high boiling points and sulfurization using sulfur powders. The characterization results showed that the size, shape, crystallinity, composition, and phase stability of the La2O2S nanocrystals were affected by the doped alkali metals. Combined with first‐principles calculations of the formation energy of anionic defects in the lattices, the ternary phase diagrams for the formation of rare‐earth oxysulfides (RE2O2S) were calculated. Both the experimental results and the phase diagrams have demonstrated that the doped alkali metals are capable of promoting the formation of RE2O2S nanocrystals in the order of K≈Na>Li. With K acting as the doping alkali metal, the phase‐formation capability for different RE2O2S (e.g., Eu, Gd, Yb, Lu) along the lanthanide series was also explored under the guidance of the hard and soft acid and base (HSAB) theory. Moreover, the as‐developed synthetic route could be applied also to the production of K/Eu‐ and K/Tb‐codoped La2O2S nanoplates, which displayed intense red and green emissions, respectively, under ultraviolet‐light excitations.
Journal
ChemPlusChem – Wiley
Published: Jun 1, 2013