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Estimation of the Kinetic Parameters and the Critical Rate of Temperature Rise in the Thermal Explosion from the Exothermic Autocatalytic Decomposition of 3,4‐Bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) Using Non‐isothermal Differential Scanning Calorimetry

Estimation of the Kinetic Parameters and the Critical Rate of Temperature Rise in the Thermal... A method of estimating the kinetic parameters and the critical rate of temperature rise in the thermal explosion for the autocatalytic decomposition of 3,4‐bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) with non‐isothermal differential scanning calorimetry (DSC) was presented. The rate equation for the decomposition of BNFOF was established, and information was obtained on the rate of temperature increase in BNFOF when the empiric‐order autocatalytic decomposition was converted into thermal explosion. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chinese Journal of Chemistry Wiley

Estimation of the Kinetic Parameters and the Critical Rate of Temperature Rise in the Thermal Explosion from the Exothermic Autocatalytic Decomposition of 3,4‐Bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) Using Non‐isothermal Differential Scanning Calorimetry

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References (2)

Publisher
Wiley
Copyright
Copyright © 2006 Wiley Subscription Services, Inc., A Wiley Company
ISSN
1001-604X
eISSN
1614-7065
DOI
10.1002/cjoc.200690121
Publisher site
See Article on Publisher Site

Abstract

A method of estimating the kinetic parameters and the critical rate of temperature rise in the thermal explosion for the autocatalytic decomposition of 3,4‐bis(4′‐nitrofurazan‐3′‐yl)‐2‐oxofurazan (BNFOF) with non‐isothermal differential scanning calorimetry (DSC) was presented. The rate equation for the decomposition of BNFOF was established, and information was obtained on the rate of temperature increase in BNFOF when the empiric‐order autocatalytic decomposition was converted into thermal explosion.

Journal

Chinese Journal of Chemistry – Wiley

Published: May 1, 2006

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