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CommuniCtion www.advenergymat.de www.MaterialsViews.com Encapsulating Sn Nanoparticles in Amorphous Carbon Nanotubes for Enhanced Lithium Storage Properties Xiaosi Zhou, Le Yu, Xin-Yao Yu, and Xiong Wen (David) Lou* −1 Lithium-ion batteries (LIBs) have received growing interest reversible capacity as high as 648 mA h g after 140 cycles at −1 [23] in the areas of electrochemical energy storage including port- a current density of 0.1 A g . Wang co-worker demonstrated able electronic devices, electric vehicles, and grid-scale energy that Sn nanoparticles (≈10 nm) evenly dispersed in a spherical storage systems in view of their high energy density and conductive carbon framework could retain a reversible capacity [1–3] −1 −1 [24] long lifespan. However, the dominant commercially used of 710 mA h g after 130 cycles at 0.2 A g . More recently, anode material, graphite, has a low theoretical capacity of ultrafine Sn nanoparticles (≈5 nm) embedded in nitrogen- −1 [4–6] 372 mA h g . To satisfy the increasing needs for renew- doped porous carbon matrix has been fabricated by carbon- able energy utilization, tremendous efforts have been devoted izing a divalent Sn complex, exhibiting a specific capacity of −1 −1 [27] to developing novel anode materials with high
Advanced Energy Materials – Wiley
Published: Nov 1, 2016
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