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Copper complexes of chiral quinolinyl‐oxazoline have been studied as the catalysts for enantioselective allylic oxidation of cycloalkenes with tert‐butyl perbenzoate. Using 5 mol% of these chiral catalysts, optical active allylic benzoates were obtained in moderate enantiomeric excesses. CuOTf prepared in situ, CuClO4 and CuPF6 were found to be good precatalysts in acetone.
Chinese Journal of Chemistry – Wiley
Published: Jan 1, 2001
Keywords: ; ;
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