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- Publisher
- Wiley
- Copyright
- © 2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 2193-5807
- eISSN
- 2193-5815
- DOI
- 10.1002/ajoc.201500435
- Publisher site
- See Article on Publisher Site
Abstract
A fascinating series of highly fluorescent donor‐acceptor‐appended molecular rotors based on benzocrown ethers has been synthesized. The dimethylamino‐based benzocrown ethers have interesting photophysical properties with good quantum yield and emitted dual fluorescence in polar solvents due to doubly twisted‐intramolecular charge transfer (DT‐ICT) character induced by the dimethylamino group and benzocrown ring. The unique dual fluorescence property of the molecular rotors was explored to develop a ratiometric acidic pH sensor.
Journal
Asian Journal of Organic Chemistry – Wiley
Published: Feb 1, 2016
Keywords: ; ; ; ;