Get 20M+ Full-Text Papers For Less Than $1.50/day. Start a 14-Day Trial for You or Your Team.

Learn More →

Domain formation and phase transitions in the wurtzite‐based heterovalent ternaries: a Landau theory analysis

Domain formation and phase transitions in the wurtzite‐based heterovalent ternaries: a Landau... Characterizing the crystalline disorder properties of heterovalent ternary semiconductors continues to challenge solid‐state theory. Here, a Landau theory is developed for the wurtzite‐based ternary semiconductor ZnSnN2. It is shown that the symmetry properties of two nearly co‐stable phases, with space groups Pmc21 and Pbn21, imply that a reconstructive phase transition is the source of crystal structure disorder via a mixture of phase domains. The site exchange defect, which consists of two adjacent antisite defects, is identified as the nucleation mechanism of the transition. A Landau potential based on the space‐group symmetries of the Pmc21 and Pbn21 phases is constructed from the online databases in the ISOTROPY software suite and this potential is consistent with a system that undergoes a paraelectric to antiferroelectric phase transition. It is hypothesized that the low‐temperature Pbn21 phase is antiferroelectric within the c‐axis basal plane. The dipole arrangements within the Pbn21 basal plane yield a nonpolar spontaneous polarization and the electrical susceptibility derived from the Landau potential exhibits a singularity at the Néel temperature characteristic of antiferroelectric behavior. These results inform the study of disorder in the broad class of heterovalent ternary semiconductors, including those based on the zincblende structure, and open the door to the application of the ternaries in new technology spaces. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Acta Crystallographica Section A Foundations of Crystallography Wiley

Domain formation and phase transitions in the wurtzite‐based heterovalent ternaries: a Landau theory analysis

Loading next page...
 
/lp/wiley/domain-formation-and-phase-transitions-in-the-wurtzite-based-BAApisgHzB

References (76)

Publisher
Wiley
Copyright
Copyright © 2020 Wiley Subscription Services, Inc., A Wiley Company
ISSN
0108-7673
eISSN
1600-5724
DOI
10.1107/S2053273320003095
Publisher site
See Article on Publisher Site

Abstract

Characterizing the crystalline disorder properties of heterovalent ternary semiconductors continues to challenge solid‐state theory. Here, a Landau theory is developed for the wurtzite‐based ternary semiconductor ZnSnN2. It is shown that the symmetry properties of two nearly co‐stable phases, with space groups Pmc21 and Pbn21, imply that a reconstructive phase transition is the source of crystal structure disorder via a mixture of phase domains. The site exchange defect, which consists of two adjacent antisite defects, is identified as the nucleation mechanism of the transition. A Landau potential based on the space‐group symmetries of the Pmc21 and Pbn21 phases is constructed from the online databases in the ISOTROPY software suite and this potential is consistent with a system that undergoes a paraelectric to antiferroelectric phase transition. It is hypothesized that the low‐temperature Pbn21 phase is antiferroelectric within the c‐axis basal plane. The dipole arrangements within the Pbn21 basal plane yield a nonpolar spontaneous polarization and the electrical susceptibility derived from the Landau potential exhibits a singularity at the Néel temperature characteristic of antiferroelectric behavior. These results inform the study of disorder in the broad class of heterovalent ternary semiconductors, including those based on the zincblende structure, and open the door to the application of the ternaries in new technology spaces.

Journal

Acta Crystallographica Section A Foundations of CrystallographyWiley

Published: May 1, 2020

Keywords: ; ; ; ;

There are no references for this article.