Access the full text.
Sign up today, get DeepDyve free for 14 days.
Z. J. Lin, Z. Yang, T. F. Liu, Y. B. Huang, R. Cao (2012)
Microwave‐assisted synthesis of a series of lanthanide metal‐organic frameworks and gas sorption properties, 51
A. Li, Q. Chu, H. Zhou, Z. Yang, B. Liu, J. Zhang (2021)
Effective nitenpyram detection in a dual‐walled nitrogen‐rich In (III)/Tb (III)‐organic framework, 8
S. M. Kloek, D. M. Heinekey, K. I. Goldberg (2007)
C‐H bond activation by rhodium hydroxide and phenoxide complexes, 46
Z. Li, Z. Wang, N. Chekshin, S. Qian, J. X. Qiao, P. T. Cheng, K. S. Yeung, W. R. Ewing, J. Q. Yu (2021)
A tautomeric ligand enables directed C‐H hydroxylation with molecular oxygen, 372
M. Shibasaki, M. Kanai, S. Matsunaga, N. Kumagai (2009)
Rencent progress in asymmetric bifunctional catalysis using multimetallic systems, 42
L. W. K. Moodie, S. Chammaa, T. Kindahl, C. Hedberg (2017)
Palladium‐ mediated approach to coumarin‐functionalized amino acids, 19
X. Ma, P. Wang, Z. Liu, C. Xin, S. Wang, J. Jia, P. Ma, J. Niu, J. Wang (2020)
Oxyfunctionalization of alkanes based on a tricobalt(II)‐substituted Dawson‐type rhenium carbonyl derivative as catalyst, 59
D. Shi, Y. Ren, H. Jiang, J. Lu, X. Cheng (2013)
A new three‐dimensional metal‐organic framework constructed from 9,10‐anthracene dibenzoate and Cd(II) as a highly active heterogeneous catalyst for oxidation of alkylbenzenes, 42
M. Gustafsson, A. Bartoszewicz, B. Martín‐Matute, J. Sun, J. Grins, T. Zhao, Z. Li, G. Zhu, X. Zou (2010)
A family of highly stable lanthanide metal‐organic frameworks: structural evolution and catalytic activity, 22
L. Hu, K. Li, W. Shang, X. Zhu, M. Liu (2020)
Emerging cubic chirality in γ‐CD‐MOF for fabricating circularly polarized luminescent crystalline materials and the size effect, 59
G. Li, S. Zhao, Y. Zhang, Z. Tang (2018)
Metal‐organic frameworks encapsulating active nanoparticles as emerging composites for catalysis: rencent progress and perspectives, 30
R. Dun, X. Wang, M. Tan, Z. Huang, X. Huang, W. Ding, X. Lu (2013)
Quantitative aerobic oxidation of primary benzylic alcohols to aldehydes catalyzed by highly efficient and recyclable P123‐stabilized Pd nanoclusters in acidic aqueous solution, 3
G. M. Sheldrick (2015)
Crystal structure refinement with SHELXL, C71
Z. M. Ren, L. L. Wang, J. M. Wang, B. Zhu, Q. Gao, M. Wang, F. Shao, Y. H. Fan (2021)
Five novel MOFs with various dimensions as efficient catalysts for oxygen evolution reactions, 23
H. Yu, Q. Zhao, Z. Wei, Z. Wu, Q. Li, S. Han, Y. Wei (2019)
Iron‐catalyzed oxidative functionalization of C(sp3)–H bonds under bromide‐synergized mild conditions, 55
M. Liu, J. Wu, H. Hou (2018)
Metal‐organic framework (MOF)‐based materials as heterogeneous catalysts for C‐H bond activation, 25
R. Y. Tang, G. Li, J. Q. Yu (2014)
Conformation‐induced remote meta‐C–H activation of amines, 507
Y. Li, H. Song, Q. Liang, R. He, Z. Wei (2009)
Synthesis, crystal structure and photoluminescent properties of two novel two‐dimensional coordination networks assembled by lanthanide salts and carboxylate ligand, 27
T. Gensch, M. N. Hopkinson, F. Glorius, J. Wencel‐Delord (2016)
Mild metal‐catalyzed C‐H activation: examples and concepts, 45
S. Fukui, A. Kajihara, T. Hirano, F. Sato, N. Suzuki, H. Nagao (2011)
Synthesis and characterization of ethylbis(2‐pyridylethyl)amineruthenium complexes and two different types of C‐H bond cleavage at an ethylene arm, 50
H. Xu, C. S. Cao, X. M. Kang, B. Zhao (2016)
Lanthanide based metal‐ organic frameworks as luminescent probes, 45
Y. S. Wei, M. Zhang, R. Zou, Q. Xu (2020)
Metal‐organic framework‐based catalysts with single metal sites, 120
Q. Han, B. Qi, W. Ren, C. He, J. Niu, C. Duan (2015)
Polyoxometalate‐ based homochiral metal‐organic frameworks for tandem asymmetric transformation of cyclic carbonates from olefins, 6
X. Liu, J. Li, N. Li, B. Li, X. H. Bu (2021)
Recent advances on metal‐organic frameworks in the conversion of carbon dioxide, 39
P. Wang, L. Deng (2018)
Recent advances in iron‐catalyzed C‐H bond amination via iron imido intermediate, 36
X. Zhang, X. Wei, S. L. Huang, G. Y. Yang (2021)
Selective photocatalytic oxidation of sulfides in lanthanide metal‐organic frameworks incorporating Ru(2,2′‐bpy)3 photosensitizer, 16
J. N. Hao, B. Yan (2015)
Ag+‐Sensitized lanthanide luminescence in Ln3+ post‐functionalized metal‐organic frameworks and Ag+ sensing, 3
A. Bhunia, M. A. Gotthardt, M. Yadav, M. T. Gamer, A. Eichhofer, W. Kleist, P. W. Roesky (2013)
Salen‐based coordination polymers of manganese and the rare‐earth elements: synthesis and catalytic aerobic epoxidation of olefins, 19
R. R. Karimov, J. F. Hartwig (2018)
Transition‐metal‐catalyzed selective functionalization of C(sp3)–H bonds in natural products, 57
M. Zhao, S. Ou, C. D. Wu (2014)
Porous metal‐organic frameworks for heterogeneous biomimetic catalysis, 47
C. Guo (2018)
An efficient approach for enhancing the catalytic activity of Ni‐MOF‐74 via a relay catalyst system for the selective oxidation of benzylic C‐H bonds under mild conditions, 54
J. Yamaguchi, A. D. Yamaguchi, K. Itami (2012)
C‐H bond functionalization: emerging synthetic tools for natural products and pharmaceuticals, 51
Z. Shi, C. Zhang, C. Tang, N. Jiao (2012)
Recent advances in transition‐ metal catalyzed reactions using molecular oxygen as the oxidant, 41
D. Shi, X. Yang, H. Chen, D. Jiang, J. Liu, Y. Ma, D. Schipper, R. A. Jones (2019)
Large Ln42 coordination nanorings: NIR luminescence sensing of metal ions and nitro explosives, 55
J. A. Labinger, J. E. Bercaw (2002)
Understanding and exploiting C‐H bond activation, 417
Y. Zhang, S. Liu, Z. S. Zhao, Z. Wang, R. Zhang, L. Liu, Z. B. Han (2021)
Recent progress in lanthanide metal‐organic frameworks and their derivatives in catalytic applications, 8
M. H. Xie, X. Y. Liu, S. W. Wang, L. Liu, Y. Y. Wu, G. S. Yang, S. L. Zhou, E. H. Sheng, Z. X. Huang (2010)
Synthesis, structure and catalytic activity comparison of tris‐ and tetracoordinated lanthanide amides, 22
L. V. Meyer, F. Schoenfeld, K. Mueller‐Buschbaum (2014)
Lanthanide based tuning of luminescence in MOFs and dense frameworks ‐ from mono‐ and multimetal systems to sensors and films, 50
L. Cao, T. Wang, C. Wang (2018)
Synthetic strategies for constructing two‐ dimensional metal‐organic layers (MOLs): a tutorial review, 36
C. Zou, Z. Zhang, X. Xu, Q. Gong, J. Li, C. D. Wu (2012)
A multifunctional organic‐inorganic hybrid structure based on MnIII‐porphyrin and polyoxometalate as a highly effective dye scavenger and heterogeneous catalytst, 134
G. Pandey, R. Laha, D. Singh (2016)
Benzylic C(sp3)–H functionalization for C‐N and C‐O bond formation via visible‐light‐photoredox catalysis, 81
X. Q. Song, H. H. Meng, Z. G. Lin, L. Wang (2020)
2D lanthanide coordination polymers: synthesis, structure, luminescent properties and ratiometric sensing application in the hydrostable PMMA‐doped hybrid films, 2
N. Sauermann, T. Meyer, C. Tian, L. Ackermann (2017)
Electrochemical cobalt‐catalyzed C‐H oxygenation at room temperature, 139
S. Biswas, H. S. Jena, A. Adhikary, S. Konar (2014)
Two isostructural 3D lanthanide coordination networks (Ln = Gd3+, Dy3+) with squashed cuboid‐type nanoscopic cages showing significant cryogenic magnetic refrigeration and slow magnetic relaxation, 53
Z. Zhang, Y. Tao, H. Tian, Q. Yue, S. Liu, Y. Liu, X. Li, Y. Lu, Z. Sun, E. Kraka, S. Liu (2020)
Chelation‐assisted selective etching construction of hierarchical polyoxometalate‐based metal‐organic framework, 32
P. C. Junk, C. J. Kepert, B. W. Skelton, A. H. White (1999)
(Maximally) Hydrated rare earth sulfates and the double sulfates (NH4)Ln(SO4)2·4H2O (Ln = La, Tb), 52
Q. Wang, B. Xu, Y. Wang, H. Wang, X. Hu, P. Ma, J. Niu, J. Wang (2021)
Polyoxometalate‐incorporated framework as a heterogeneous catalyst for selective oxidation of C‐H bonds of alkylbenzenes, 60
J. Liu, X. Zhang, H. Yi, C. Liu, R. Liu, H. Zhang, K. Zhuo, A. Lei (2015)
Chloroacetate‐promoted selective oxidation of heterobenzylic methylene under copper catalysis, 54
W. M. Wang, L. Y. He, X. X. Wang, Y. Shi, Z. L. Wu, J. Z. Cui (2019)
Linear‐ shaped Ln4III and Ln6III clusters constructed by a polydentate Schiff base ligand and a β‐diketone co‐ligand: structures, fluorescence properties, magnetic refrigeration and single‐molecule magnet behavior, 48
X. Y. Ren, L. H. Lu (2015)
Luminescent nanoscale metal‐organic frameworks for chemical sensing, 26
T. Q. Song, J. Dong, A. F. Yang, X. J. Che, H. L. Gao, J. Z. Cui, B. Zhao (2018)
Wheel‐like Ln18 cluster organic frameworks for magnetic refrigeration and conversion of CO2, 57
M. S. Chen, M. C. White (2010)
Combined effects on selectivity in Fe‐catalyzed methylene oxidation, 327
C. G. Zheng, J. Zhang, Z. F. Chen, Z. J. Guo, R. G. Xiong, X. Z. You (2002)
A novel three‐dimensional network isophthalato‐bridged lanthanide complex: {Ln[C6H4(COO‐)2‐1,3](CH3COO‐)(H2O)}·H2O, 55
C. Huang, G. Li, L. Zhang, Y. Zhang, L. Mi, H. Hou (2019)
Reversible structural transformations of metal‐organic frameworks as artificial switchable catalysts for dynamic control of selectively cyanation Reaction, 25
D. Li, X. Ma, Q. Wang, P. Ma, J. Niu, J. Wang (2019)
Copper‐containing polyoxometalate‐based metal‐organic frameworks as highly efficient heterogeneous catalysts toward selective oxidation of alkylbenzenes, 58
J. B. Xia, K. W. Cormier, C. Chen (2012)
A highly selective vanadium catalyst for benzylic C‐H oxidation, 3
A. N. Campbell, S. S. Stahl (2012)
Overcoming the "oxidant problem": strategies to use o‐2 as the oxidant in organometallic C‐H oxidation reactions catalyzed by Pd (and Cu), 45
X. Feng, Y. Song, W. Bin (2021)
Dimensional reduction of lewis acidic metal‐organic frameworks for multicomponent reactions, 143
Developing new catalysts for highly selectivity and conversion of saturated C(sp3)–H bonds is of great significance. In order to obtain catalysts with high catalytic performance, six Eu‐based MOFs with different structural characteristics were obtained by using europium ions and different organic acid ligands, namely Eu‐1~Eu‐6. Eu‐1, Eu‐2 and Eu‐3 featured three‐dimensional structures, while Eu‐4 and Eu‐5 featured two‐dimensional structures. Differently, a one‐dimensional chain structure of Eu‐6 was obtained by changing the ligand. All the six MOFs were applied to the catalytic reaction of C(sp3)–H bond, and it was found that the catalytic effect was gradually enhanced with the decrease of dimension and the increase of the size of channels. As expected, Eu‐6 showed the highest selectivity (~99%) and conversion (~99%). Moreover, catalytic cycling and stability tests showed Eu‐6 can be a reliable catalyst.
Chinese Journal of Chemistry – Wiley
Published: Feb 15, 2022
Keywords: Metal‐organic frameworks; Heterogeneous catalysis; Rare earths; Dimensional reduction; Selectively oxidize C(sp 3 )–H
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.