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Dibromometallyl‐iron complexes generated by the recombination of an alumanyl‐iron complex with EBr3 (E = Al, Ga)

Dibromometallyl‐iron complexes generated by the recombination of an alumanyl‐iron complex with... The first dibromoalumanyl‐iron complex [Br2Al–FeCp(CO)2] was synthesized by the reaction of monobromoalumanyl‐iron complex bearing a bulky substituent on aluminum atom with AlBr3, whose structure was determined by the X‐ray crystallographic analysis and the NMR measurement. The reactions monobromoalumanyl‐iron complex with GaBr3 show that these reactions would proceed by the mutual recombination of substituents. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Dibromometallyl‐iron complexes generated by the recombination of an alumanyl‐iron complex with EBr3 (E = Al, Ga)

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References (28)

Publisher
Wiley
Copyright
"Copyright © 2018 Wiley Periodicals, Inc."
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.21465
Publisher site
See Article on Publisher Site

Abstract

The first dibromoalumanyl‐iron complex [Br2Al–FeCp(CO)2] was synthesized by the reaction of monobromoalumanyl‐iron complex bearing a bulky substituent on aluminum atom with AlBr3, whose structure was determined by the X‐ray crystallographic analysis and the NMR measurement. The reactions monobromoalumanyl‐iron complex with GaBr3 show that these reactions would proceed by the mutual recombination of substituents.

Journal

Heteroatom ChemistryWiley

Published: Dec 1, 2018

Keywords: ; ;

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