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- Publisher
- Wiley
- Copyright
- Copyright © 2004 Wiley Subscription Services, Inc., A Wiley Company
- ISSN
- 0323-4320
- eISSN
- 1521-401X
- DOI
- 10.1002/aheh.200400530
- Publisher site
- See Article on Publisher Site
Abstract
Two main routes of methods for the preparation of photocatalytic active titanium dioxide films on glass substrates were investigated: (1) the use of titanium dioxide powder and (2) the in situ generation of the catalyst via hydrolysis of titanium tetraisopropoxide (TTIP) or TiCl4. The activities of the catalyst films were evaluated by measuring the degradation of dichloroacetic acid (DCA), clofibric acid, and terbuthylazine used as model organic compounds. The concentration decrease of DCA and the concentration increase of chloride ions as the decomposition product allowed to distinguish between photocatalytic degradation of DCA and adsorption onto the TiO2 films. Furthermore, TiO2 films of the commercially available materials P25 (Degussa) and Hombikat UV100 (Sachtleben Chemie) were used to investigate whether there was a difference in the degradation pathways of terbuthylazine as a model compound. For the experiments mini flow‐through reactors were constructed.
Journal
Acta hydrochimica et hydrobiologica – Wiley
Published: Sep 1, 2004
Keywords: ; ; ; ; ; ; ; ; ; ;