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Enantioselektive C‐H‐Aktivierung mit natürlich vorkommenden 3d‐ÜbergangsmetallenAngewandte Chemie
- Publisher
- Wiley
- Copyright
- © 2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
- ISSN
- 2193-5807
- eISSN
- 2193-5815
- DOI
- 10.1002/ajoc.201900565
- Publisher site
- See Article on Publisher Site
Abstract
We report enantioselective 1,4‐addition reactions of indoles to maleimides via a C2‐selective C−H activation catalyzed by an achiral Cp*CoIII/chiral carboxylic acid system. In these reactions, a BINOL‐derived chiral carboxylic acid enables the enantioselective reactions as the sole chiral source.
Journal
Asian Journal of Organic Chemistry – Wiley
Published: Mar 1, 2020
Keywords: ; ; ; ;