Cover Picture: Synthesis and Thermolysis of the Phosphorus‐Rich Manganese(I) Complex (Mn 2 (μ‐Br){ cyclo ‐(P 4 t Bu 3 )P t Bu}(CO) 6 ): From Complexes to Metal Phosphides (ChemPlusChem 5/2012)
Cover Picture: Synthesis and Thermolysis of the Phosphorus‐Rich Manganese(I) Complex (Mn 2...
Kircali, Aslihan; Frank, René; Gómez‐Ruiz, Santiago; Kirchner, Barbara; Hey‐Hawkins, Evamarie
2012-05-01 00:00:00
The cover picture shows the thermolysis (up to 1000 °C) of the first phosphorus‐rich manganese(I) complex (Mn2(μ‐Br){cyclo‐(P4tBu3)PtBu}(CO)6) with formation of antiferromagnetic (below 103 K) Mn2P as the final product via a phosphorus‐rich phase (calculated as Mn2P5) at 315 °C. In their Full Paper on page 341 ff., E. Hey‐Hawkins et al. describe the synthesis of the molecular precursor from Na(cyclo‐(P5tBu4)) and (MnBr(CO)5). The rearrangement of (cyclo‐(P5tBu4))− into (cyclo‐(P4tBu3)PtBu)− was rationalized by theoretical studies. Cover designed by Volkan Senol.
http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.pngChemPlusChemWileyhttp://www.deepdyve.com/lp/wiley/cover-picture-synthesis-and-thermolysis-of-the-phosphorus-rich-0JIKEKPE4A
Cover Picture: Synthesis and Thermolysis of the Phosphorus‐Rich Manganese(I) Complex (Mn 2 (μ‐Br){ cyclo ‐(P 4 t Bu 3 )P t Bu}(CO) 6 ): From Complexes to Metal Phosphides (ChemPlusChem 5/2012)
The cover picture shows the thermolysis (up to 1000 °C) of the first phosphorus‐rich manganese(I) complex (Mn2(μ‐Br){cyclo‐(P4tBu3)PtBu}(CO)6) with formation of antiferromagnetic (below 103 K) Mn2P as the final product via a phosphorus‐rich phase (calculated as Mn2P5) at 315 °C. In their Full Paper on page 341 ff., E. Hey‐Hawkins et al. describe the synthesis of the molecular precursor from Na(cyclo‐(P5tBu4)) and (MnBr(CO)5). The rearrangement of (cyclo‐(P5tBu4))− into (cyclo‐(P4tBu3)PtBu)− was rationalized by theoretical studies. Cover designed by Volkan Senol.
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