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Cover Picture: Synthesis and Thermolysis of the Phosphorus‐Rich Manganese(I) Complex (Mn 2 (μ‐Br){ cyclo ‐(P 4 t Bu 3 )P t Bu}(CO) 6 ): From Complexes to Metal Phosphides (ChemPlusChem 5/2012)

Cover Picture: Synthesis and Thermolysis of the Phosphorus‐Rich Manganese(I) Complex (Mn 2... The cover picture shows the thermolysis (up to 1000 °C) of the first phosphorus‐rich manganese(I) complex (Mn2(μ‐Br){cyclo‐(P4tBu3)PtBu}(CO)6) with formation of antiferromagnetic (below 103 K) Mn2P as the final product via a phosphorus‐rich phase (calculated as Mn2P5) at 315 °C. In their Full Paper on page 341 ff., E. Hey‐Hawkins et al. describe the synthesis of the molecular precursor from Na(cyclo‐(P5tBu4)) and (MnBr(CO)5). The rearrangement of (cyclo‐(P5tBu4))− into (cyclo‐(P4tBu3)PtBu)− was rationalized by theoretical studies. Cover designed by Volkan Senol. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png ChemPlusChem Wiley

Cover Picture: Synthesis and Thermolysis of the Phosphorus‐Rich Manganese(I) Complex (Mn 2 (μ‐Br){ cyclo ‐(P 4 t Bu 3 )P t Bu}(CO) 6 ): From Complexes to Metal Phosphides (ChemPlusChem 5/2012)

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Publisher
Wiley
Copyright
Copyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2192-6506
eISSN
2192-6506
DOI
10.1002/cplu.201290020
Publisher site
See Article on Publisher Site

Abstract

The cover picture shows the thermolysis (up to 1000 °C) of the first phosphorus‐rich manganese(I) complex (Mn2(μ‐Br){cyclo‐(P4tBu3)PtBu}(CO)6) with formation of antiferromagnetic (below 103 K) Mn2P as the final product via a phosphorus‐rich phase (calculated as Mn2P5) at 315 °C. In their Full Paper on page 341 ff., E. Hey‐Hawkins et al. describe the synthesis of the molecular precursor from Na(cyclo‐(P5tBu4)) and (MnBr(CO)5). The rearrangement of (cyclo‐(P5tBu4))− into (cyclo‐(P4tBu3)PtBu)− was rationalized by theoretical studies. Cover designed by Volkan Senol.

Journal

ChemPlusChemWiley

Published: May 1, 2012

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