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- Publisher
- Wiley
- Copyright
- Copyright © 2013 Wiley Subscription Services, Inc., A Wiley Company
- ISSN
- 2193-5807
- eISSN
- 2193-5815
- DOI
- 10.1002/ajoc.201390009
- Publisher site
- See Article on Publisher Site
Abstract
Transition‐metal‐catalyzed direct CH arylations have emerged as ideally efficient transformations in organic synthesis. In their Full Paper on page 320 ff, Atsuhiro Osuka et al. report palladium‐catalyzed, β‐selective, direct arylations of 5,10,15‐triarylporphyrins with π‐extended aryl bromides, such as 2‐bromonaphthalene and 9‐bromoanthracene. The β‐arylation of the porphyrins proceeds without any additional phosphine ligands and is, thus, an efficient and user‐friendly arylation of the porphyrin core.
Journal
Asian Journal of Organic Chemistry – Wiley
Published: Apr 1, 2013
Keywords: ; ; ; ;