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Christian Matheis, Bilguun Bayarmagnai, Kévin Jouvin, L. Goossen (2016)
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An expedient one‐pot synthesis of (diethylphosphono) difluoromethyl thioethers is described consisting of a Sandmeyer thiocyanation with in situ‐fluoroalkylation using TMS‐CF2PO(OEt)2 as the fluorine source. Both steps are mediated by copper(I) thiocyanate. The reaction is applicable to a wide range of functional groups, as demonstrated by 22 examples.
Asian Journal of Organic Chemistry – Wiley
Published: May 1, 2019
Keywords: ; ; ; ;
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