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Contents: Chin. J. Chem. 08/2020

Contents: Chin. J. Chem. 08/2020 中 国 化 学 Concise Reports Radical Heteroarylalkylation of Alkenes via Three-Component Docking-Migration Thio- etherification Cascade A novel, rational-designed approach to access various heteroaryl-substituted alkyl thioethers was developed via docking-migration cascade process. By utilizing three components involving alkene, dual-function reagent, and thioetherificating reagent, radical heteroarylalkylation of alkenes fol- lowed by thiolation of the alkyl radical intermediates proceeded smoothly, manifesting well com- patibility of substrates and cascade transformations. Furthermore, this protocol also features mild Tao Niu, Jige Liu, Xinxin Wu, Chen Zhu* conditions, broad substrate scope, and wide product diversity. Sequential Ir-Catalyzed Allylation/2-aza-Cope Rearrangement Strategy for the Construction of Chiral Homoallylic Amines Sequential Ir-catalyzed asymmetric allylation/2-aza-Cope rearrangement of arylidene ami- no-malonates with allylic carbonates was successfully developed, and a variety of enantioenriched homoallylic amine derivatives were obtained in high yields with good chirality transfer and excel- Ruo-Qing Wang, Chong Shen, Xiang Cheng, lent E/Z-geometry control (up to 99% yield, 96% ee). Compared with previous dual catalytic system Zuo-Fei Wang, Hai-Yan Tao, Xiu-Qin Dong,* established for this transformation, the current mono metal catalytic system provides a simpler Chun-Jiang Wang* and more practical protocol employing the readily available starting materials. Structurally Interesting Diarymethane Deriva- tives from Securidaca inappendiculata Bin Zhou, Yan Wu, http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Chinese Journal of Chemistry Wiley

Contents: Chin. J. Chem. 08/2020

Chinese Journal of Chemistry , Volume 38 (8) – Aug 1, 2020

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Publisher
Wiley
Copyright
© 2020 SIOC, CAS, Shanghai, & WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
1001-604X
eISSN
1614-7065
DOI
10.1002/cjoc.202090083
Publisher site
See Article on Publisher Site

Abstract

中 国 化 学 Concise Reports Radical Heteroarylalkylation of Alkenes via Three-Component Docking-Migration Thio- etherification Cascade A novel, rational-designed approach to access various heteroaryl-substituted alkyl thioethers was developed via docking-migration cascade process. By utilizing three components involving alkene, dual-function reagent, and thioetherificating reagent, radical heteroarylalkylation of alkenes fol- lowed by thiolation of the alkyl radical intermediates proceeded smoothly, manifesting well com- patibility of substrates and cascade transformations. Furthermore, this protocol also features mild Tao Niu, Jige Liu, Xinxin Wu, Chen Zhu* conditions, broad substrate scope, and wide product diversity. Sequential Ir-Catalyzed Allylation/2-aza-Cope Rearrangement Strategy for the Construction of Chiral Homoallylic Amines Sequential Ir-catalyzed asymmetric allylation/2-aza-Cope rearrangement of arylidene ami- no-malonates with allylic carbonates was successfully developed, and a variety of enantioenriched homoallylic amine derivatives were obtained in high yields with good chirality transfer and excel- Ruo-Qing Wang, Chong Shen, Xiang Cheng, lent E/Z-geometry control (up to 99% yield, 96% ee). Compared with previous dual catalytic system Zuo-Fei Wang, Hai-Yan Tao, Xiu-Qin Dong,* established for this transformation, the current mono metal catalytic system provides a simpler Chun-Jiang Wang* and more practical protocol employing the readily available starting materials. Structurally Interesting Diarymethane Deriva- tives from Securidaca inappendiculata Bin Zhou, Yan Wu,

Journal

Chinese Journal of ChemistryWiley

Published: Aug 1, 2020

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