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COMMUNICATION www.advenergymat.de www.MaterialsViews.com Constructive Effects of Alkyl Chains: A Strategy to Design Simple and Non-Spiro Hole Transporting Materials for High-Effi ciency Mixed-Ion Perovskite Solar Cells Jinbao Zhang , Bo Xu , Malin B. Johansson , Mahboubeh Hadadian , Juan Pablo Correa Baena , Peng Liu , Yong Hua , Nick Vlachopoulos , Erik M. J. Johansson , * Gerrit Boschloo , Licheng Sun , and Anders Hagfeldt * Organic–inorganic metal halide perovskite solar cells (PSCs) Therein, hole transporting materials (HTMs), as an important have attracted a great attention in the fi eld of photovoltaics by interface contact between the perovskite crystals and the metal demonstrating power conversion effi ciencies (PCEs) soaring electrode (back contact), have been desirably developed and [ 1,2 ] from 3.9% to above 21% during the past few years. The investigated. The structures of the HTM play crucial roles in remarkable photovoltaic performance of PSCs is resulting determining the hole transfer kinetics at the interface between from the unique properties of the organic–inorganic trihalide HTM and perovskite, as well as affecting the rate of hole trans- perovskite semiconductors, such as the direct bandgap, high port through the HTM to the metal contact. These in turn affect
Advanced Energy Materials – Wiley
Published: Jul 1, 2016
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