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Chemo‐ and regioselective allylic oxidation: Oxo‐derivatives of 2‐phospholene sugar analogs

Chemo‐ and regioselective allylic oxidation: Oxo‐derivatives of 2‐phospholene sugar analogs A convenient and facile chemo‐ and regioselective oxidation of the allylic methylene group in a 2‐phospholene ring system afforded the novel carbonyl derivatives of 2‐phospholenes (2a–i). The method gives high conversion and selectivity in the formation of allylic ketones. The advantages of this oxidation method in such a five‐membered pseudo sugar 2‐phospholene ring are mentioned, and the oxidation is examined on several substituted 2‐phospholenes (1a–i). © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:320–325, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10154 http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

Chemo‐ and regioselective allylic oxidation: Oxo‐derivatives of 2‐phospholene sugar analogs

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References (31)

Publisher
Wiley
Copyright
Copyright © 2003 Wiley Periodicals, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.10154
Publisher site
See Article on Publisher Site

Abstract

A convenient and facile chemo‐ and regioselective oxidation of the allylic methylene group in a 2‐phospholene ring system afforded the novel carbonyl derivatives of 2‐phospholenes (2a–i). The method gives high conversion and selectivity in the formation of allylic ketones. The advantages of this oxidation method in such a five‐membered pseudo sugar 2‐phospholene ring are mentioned, and the oxidation is examined on several substituted 2‐phospholenes (1a–i). © 2003 Wiley Periodicals, Inc. Heteroatom Chem 14:320–325, 2003; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/hc.10154

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 2003

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