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Chemical Synthesis of the O‐Antigen Repeating Unit of Escherichia coli O86 by an N‐Formylmorpholine‐Modulated One‐Pot Glycosylation Strategy

Chemical Synthesis of the O‐Antigen Repeating Unit of Escherichia coli O86 by an... The synthesis of the O‐antigen pentasaccharide repeating unit of the cell wall of Gram‐negative bacteria Escherichia coli O86 is reported. The synthesis features the use of an N‐formylmorpholine (NFM)‐modulated glycosylation method for the construction of 1,2‐cis α‐glycosidic linkages and an [1+1+2] iterative one‐pot α‐glycosylation strategy to accelerate the assembly of the tetrasaccharide backbone. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Asian Journal of Organic Chemistry Wiley

Chemical Synthesis of the O‐Antigen Repeating Unit of Escherichia coli O86 by an N‐Formylmorpholine‐Modulated One‐Pot Glycosylation Strategy

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References (37)

Publisher
Wiley
Copyright
Copyright © 2014 Wiley Subscription Services, Inc., A Wiley Company
ISSN
2193-5807
eISSN
2193-5815
DOI
10.1002/ajoc.201402057
Publisher site
See Article on Publisher Site

Abstract

The synthesis of the O‐antigen pentasaccharide repeating unit of the cell wall of Gram‐negative bacteria Escherichia coli O86 is reported. The synthesis features the use of an N‐formylmorpholine (NFM)‐modulated glycosylation method for the construction of 1,2‐cis α‐glycosidic linkages and an [1+1+2] iterative one‐pot α‐glycosylation strategy to accelerate the assembly of the tetrasaccharide backbone.

Journal

Asian Journal of Organic ChemistryWiley

Published: Aug 1, 2014

Keywords: ; ; ; ;

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