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The synthesis of the O‐antigen pentasaccharide repeating unit of the cell wall of Gram‐negative bacteria Escherichia coli O86 is reported. The synthesis features the use of an N‐formylmorpholine (NFM)‐modulated glycosylation method for the construction of 1,2‐cis α‐glycosidic linkages and an [1+1+2] iterative one‐pot α‐glycosylation strategy to accelerate the assembly of the tetrasaccharide backbone.
Asian Journal of Organic Chemistry – Wiley
Published: Aug 1, 2014
Keywords: ; ; ; ;
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