Access the full text.
Sign up today, get DeepDyve free for 14 days.
Júlia Diniz, Tatiani Lima, Renan Galaverna, A. Oliveira, Daví Ferreira, F. Gozzo, M. Eberlin, J. Dupont, B. Neto (2018)
Is the formation of N-heterocyclic carbenes (NHCs) a feasible mechanism for the distillation of imidazolium ionic liquids?Physical chemistry chemical physics : PCCP, 20 38
P. Frémont, N. Marion, S. Nolan (2009)
Carbenes : Synthesis, properties, and organometallic chemistryCoordination Chemistry Reviews, 253
C. Iacobucci, S. Reale, F. Angelis (2016)
Elusive Reaction Intermediates in Solution Explored by ESI-MS: Reverse Periscope for Mechanistic Investigations.Angewandte Chemie, 55 9
Z. Kelemen, Barbara Péter-Szabó, E. Székely, Oldamur Hollóczki, D. Firaha, B. Kirchner, J. Nagy, L. Nyulászi (2014)
An abnormal N-heterocyclic carbene-carbon dioxide adduct from imidazolium acetate ionic liquids: the importance of basicity.Chemistry, 20 40
R. Flammang, M. Nguyen, G. Bouchoux, P. Gerbaux (2000)
Characterization of ionized carbenes in the gas phaseInternational Journal of Mass Spectrometry, 202
M. Feroci, I. Chiarotto, A. Inesi (2016)
Advances in the Knowledge of N-Heterocyclic Carbenes Properties. The Backing of the Electrochemical InvestigationCatalysts, 6
Jackson Scholten, G. Ebeling, J. Dupont (2007)
On the involvement of NHC carbenes in catalytic reactions by iridium complexes, nanoparticle and bulk metal dispersed in imidazolium ionic liquids.Dalton transactions, 47
M. Schäfer, Katrin Peckelsen, Mathias Paul, J. Martens, J. Oomens, G. Berden, A. Berkessel, A. Meijer (2017)
Hydrogen Tunneling above Room Temperature Evidenced by Infrared Ion Spectroscopy.Journal of the American Chemical Society, 139 16
Jamal Aldajaei, J. Keeffe, Christopher Swift, S. Gronert (2015)
Are copper(I) carbenes capable intermediates for cyclopropanations? The case for ylide intermediates.Chemistry, 21 36
D. Seebach (1979)
Methods of Reactivity UmpolungAngewandte Chemie, 18
T. Welton (1999)
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis.Chemical reviews, 99 8
C. Heinemann, T. Müller, Y. Apeloig, H. Schwarz (1996)
On the Question of Stability, Conjugation, and “Aromaticity” in Imidazol-2-ylidenes and Their Silicon Analogs†Journal of the American Chemical Society, 118
Nicholas Konstandaras, M. Dunn, Max Guerry, Christopher Barnett, M. Cole, J. Harper (2019)
The impact of cation structure upon the acidity of triazolium salts in dimethyl sulfoxide.Organic & biomolecular chemistry
H. Stetter (1976)
Catalyzed Addition of Aldehydes to Activated Double Bonds—A New Synthetic ApproachAngewandte Chemie, 15
Bengt‐Thomas Gröbel, D. Seebach (1977)
Umpolung of the Reactivity of Carbonyl Compounds Through Sulfur-Containing ReagentsSynthesis, 1977
O. Bortolini, C. Chiappe, M. Fogagnolo, P. Giovannini, A. Massi, C. Pomelli, D. Ragno (2014)
An insight into the mechanism of the aerobic oxidation of aldehydes catalyzed by N-heterocyclic carbenes.Chemical communications, 50 16
M. Yamashita, J. Fenn (1984)
Electrospray ion source: another variation on the free-jet themeThe Journal of Physical Chemistry, 88
Hans‐Werner Wanzlick, B. Lachmann, E. Schikora (1965)
Chemie nucleophiler Carbene, VIII. Zur Bildung und Reaktivität des Bis‐[1.3‐diphenyl‐imidazolidinylidens‐(2)]Chemische Berichte, 98
M. Kuhn, A. Lapis, G. Machado, T. Roisnel, J. Carpentier, Brenno Nedo, O. Casagrande (2011)
Nickel-containing di-charged imidazolium ligand with high crystalline organization. Interception and characterization of a transient carbene/cation speciesInorganica Chimica Acta, 370
Priscila Lalli, T. Rodrigues, A. Arouca, M. Eberlin, B. Neto (2012)
N-heterocyclic carbenes with negative-charge tags: direct sampling from ionic liquid solutionsRSC Advances, 2
A. Troiani, M. Rosi, S. Garzoli, C. Salvitti, G. Petris (2019)
Effective redox reactions by chromium oxide anions: Sulfur dioxide oxidation in the gas phaseInternational Journal of Mass Spectrometry
Thomas Dargel, W. Koch, D. Lavorato, G. McGibbon, J. Terlouw, H. Schwarz (1999)
Pyrazine diradicals, carbenes, ylides, and distonic ions probed by theory and experiment 2 2 DedicatInternational Journal of Mass Spectrometry
M. Denk, Ken Hatano, A. Lough (2003)
Synthesis and Characterization of a Carbene·SO2 Adduct − New Insights into the Structure and Bonding of Thiourea S,S-DioxidesEuropean Journal of Inorganic Chemistry, 2003
Alcalde, Mesquida, Vilaseca (2000)
Imidazolium molecular motifs located on dicationic frameworks. Electrospray mass spectrometric observation of carbenes: imidazolylidenesRapid communications in mass spectrometry : RCM, 14 16
A. Troiani, M. Rosi, C. Salvitti, G. Petris (2014)
The oxidation of sulfur dioxide by single and double oxygen transfer paths.Chemphyschem : a European journal of chemical physics and physical chemistry, 15 13
T. Rodrigues, D. Lesage, Wender Silva, R. Cole, G. Ebeling, J. Dupont, H. Oliveira, M. Eberlin, B. Neto (2017)
Charge-tagged N-heterocyclic carbenes (NHC): Direct transfer from ionic liquid solutions and long-lived nature in the gas phaseJournal of The American Society for Mass Spectrometry, 28
R. Alder, Michael Blake, L. Chaker, J. Harvey, François Paolini, J. Schütz (2004)
When and how do diaminocarbenes dimerize?Angewandte Chemie, 43 44
E. Alcalde, N. Mesquida, L. Pérez-García, Susana Ramos, Montserrat Alemany, M. Rodríguez (2002)
Novel bis-betaines and betaines within [1(4)]meta-heterophane frameworks.Chemistry, 8 2
L. Ott, M. Cline, Maggel Deetlefs, K. Seddon, R. Finke (2005)
Nanoclusters in ionic liquids: evidence for N-heterocyclic carbene formation from imidazolium-based ionic liquids detected by (2)H NMR.Journal of the American Chemical Society, 127 16
G. McGibbon, J. Hrǔsak, D. Lavorato, H. Schwarz, J. Terlouw (1997)
The thiazole ylide: a frequently invoked intermediate is a stable species in the gas phase.Chemistry, 3 2
T. Amyes, S. Diver, J. Richard, Felix Rivas, K. Tóth (2004)
Formation and stability of N-heterocyclic carbenes in water: the carbon acid pKa of imidazolium cations in aqueous solution.Journal of the American Chemical Society, 126 13
D. Chisholm, J. McIndoe (2008)
Charged ligands for catalyst immobilisation and analysis.Dalton transactions, 30
J. Limberger, Bárbara Leal, A. Monteiro, J. Dupont (2014)
Charge-tagged ligands: useful tools for immobilising complexes and detecting reaction species during catalysisChemical Science, 6
N. Mesquida, E. Alcalde (2007)
Imidazolium scaffolds: Electrospray mass spectrometric observation of N-heterocyclic carbenes in posInternational Journal of Mass Spectrometry
Christopher Swift, S. Gronert (2014)
Formation and Reactivity of Gold Carbene Complexes in the Gas PhaseOrganometallics, 33
R. Alder, Paul Allen, Stuart Williams (1995)
Stable carbenes as strong basesJournal of The Chemical Society, Chemical Communications
S. Taylor, Matthew McClung, C. McReynolds, H. Daly, Adam Greer, J. Jacquemin, C. Hardacre (2018)
Understanding the Competitive Gas Absorption of CO2 and SO2 in Superbase Ionic LiquidsIndustrial & Engineering Chemistry Research
Yaoyun Chen, F. Jordan (1991)
Reactivity of the thiazolium C2 ylide in aprotic solvents: novel experimental evidence for addition rather than insertion reactivityJournal of Organic Chemistry, 56
Suman Sarkar, Anup Biswas, Ramesh Samanta, A. Studer (2013)
Catalysis with N-heterocyclic carbenes under oxidative conditions.Chemistry, 19 15
R. Jothibasu, H. Huynh, L. Koh (2008)
Au(I) and Au(III) complexes of a sterically bulky benzimidazole-derived N-heterocyclic carbeneJournal of Organometallic Chemistry, 693
Nataliya Lyapchenko, R. Frański, G. Schroeder, T. Kozik, O. Shvaika, A. Kiselyov, N. Korotkikh (2003)
Electrospray ionization and liquid secondary ion mass spectrometric study of N-heterocyclic carbenes and their 1,2,4-triazolium salt precursorsInternational Journal of Mass Spectrometry, 228
Karma Sawyer, J. Cahoon, Jennifer Shanoski, E. Glascoe, M. Kling, Jacob Schlegel, M. Zoerb, M. Hapke, J. Hartwig, C. Webster, C. Harris (2010)
Time-resolved IR studies on the mechanism for the functionalization of primary C-H bonds by photoactivated Cp*W(CO)3(Bpin).Journal of the American Chemical Society, 132 6
A. Arduengo, J. Goerlich, W. Marshall (1997)
A STABLE THIAZOL-2-YLIDENE AND ITS DIMERLiebigs Annalen, 1997
J. Hallett, T. Welton (1999)
Room-temperature ionic liquids: solvents for synthesis and catalysis. 2.Chemical reviews, 111 5
Hao Chen, D. Justes, R. Cooks (2005)
Proton affinities of N-heterocyclic carbene super bases.Organic letters, 7 18
Hans‐Werner Wanzlick, E. Schikora (1961)
Ein nucleophiles CarbenChemische Berichte, 94
G. Cheng, Xinhao Zhang, L. Chung, Liping Xu, Yundong Wu (2015)
Computational organic chemistry: bridging theory and experiment in establishing the mechanisms of chemical reactions.Journal of the American Chemical Society, 137 5
D. Nelson, S. Nolan (2013)
Quantifying and understanding the electronic properties of N-heterocyclic carbenes.Chemical Society reviews, 42 16
I. Chiarotto, L. Mattiello, Fabiana Pandolfi, D. Rocco, M. Feroci (2018)
NHC in Imidazolium Acetate Ionic Liquids: Actual or Potential Presence?Frontiers in Chemistry, 6
M. Feroci, I. Chiarotto, F. D’Anna, F. Gala, R. Noto, Luigi Ornano, G. Zollo, A. Inesi (2016)
N‐Heterocyclic Carbenes and Parent Cations: Acidity, Nucleophilicity, Stability, and Hydrogen Bonding—Electrochemical Study and Ab Initio Calculations, 3
Xin Zhao, Zhaosheng Li, Tao Yu, Z. Zou (2013)
Tunable orange red phosphors: S2−-doped high temperature phase Ca3SiO4Cl2:Eu2+ for solid-state lightingRSC Advances, 3
R. Giernoth (2010)
Task-specific ionic liquids.Angewandte Chemie, 49 16
M. Kosmulski, J. Gustafsson, J. Rosenholm (2004)
Thermal stability of low temperature ionic liquids revisitedThermochimica Acta, 412
S. Meyer, R. Koch, J. Metzger (2002)
Investigation of reactive intermediates of chemical reactions in solution by electrospray ionization mass spectrometry: radical cation chain reactions.Angewandte Chemie, 42 38
M. Dunn, M. Cole, J. Harper (2012)
Effects of an ionic liquid solvent on the synthesis of γ-butyrolactones by conjugate addition using NHC organocatalystsRSC Advances, 2
D. Rocco, I. Chiarotto, F. D’Anna, L. Mattiello, Fabiana Pandolfi, C. Rizzo, M. Feroci (2019)
Cathodic Behaviour of Dicationic Imidazolium Bromides: The Role of the SpacerChemElectroChem
F. Coelho, M. Eberlin (2011)
The bridge connecting gas-phase and solution chemistries.Angewandte Chemie, 50 23
Krista Vikse, Z. Ahmadi, J. McIndoe (2014)
The Application of Electrospray Ionization Mass Spectrometry to Homogeneous CatalysisChemInform, 46
G. McGibbon, C. Heinemann, D. Lavorato, H. Schwarz (1997)
Imidazol-2-ylidene: Generation of a Missing Carbene and Its Dication by Neutralization–Reionizatin and Charge-Stripping Mass Spectrometry†‡Angewandte Chemie, 36
D. Ringger, Peter Chen (2013)
Rational design of a gold carbene precursor complex for a catalytic cyclopropanation reaction.Angewandte Chemie, 52 17
P. Gerbaux, M. Barbieux-Flammang, Y. Haverbeke, R. Flammang (1999)
Characterization of ionized heterocyclic carbenes by ion-molecule reactions.Rapid communications in mass spectrometry : RCM, 13 17
Krzysztof Dzieszkowski, Z. Rafiński (2018)
N-Heterocyclic Carbene Catalysis under Oxidizing ConditionsCatalysts
W. Schrader, P. Handayani, Christian Burstein, F. Glorius (2007)
Investigating organocatalytic reactions: mass spectrometric studies of a conjugate umpolung reaction.Chemical communications, 7
R. Flammang, M. Barbieux-Flammang, H. Le, M. Nguyen, J. Berthelot, J. Tortajada (2000)
Dehalogenation of protonated C-halogeno-1,2,4-triazoles: synthesis of new heterocyclic carbenic and ylid radical cations and contrasting behaviour of collision gasesInternational Journal of Mass Spectrometry, 199
O. Bortolini, C. Chiappe, M. Fogagnolo, A. Massi, C. Pomelli (2017)
Formation, Oxidation, and Fate of the Breslow Intermediate in the N-Heterocyclic Carbene-Catalyzed Aerobic Oxidation of Aldehydes.The Journal of organic chemistry, 82 1
D. Lemal, Roger Lovald, Kenneth Kawano (1964)
Tetraaminoethylenes. The Question of DissociationJournal of the American Chemical Society, 86
Leonardo Santos, C. Pavam, W. Almeida, F. Coelho, M. Eberlin (2004)
Probing the mechanism of the Baylis-Hillman reaction by electrospray ionization mass and tandem mass spectrometry.Angewandte Chemie, 43 33
D. Kaczmarek, K. Czerniak, T. Klejdysz (2018)
Dicationic ionic liquids as new feeding deterrentsChemicke Zvesti, 72
Yuri Corilo, F. Nachtigall, P. Abdelnur, G. Ebeling, J. Dupont, M. Eberlin (2011)
Charge-tagged N-heterocyclic carbenesRSC Advances, 1
Yan-xia Zhao, Qing-Yu Liu, Mei-Qi Zhang, Sheng‐Gui He (2016)
Reactions of metal cluster anions with inorganic and organic molecules in the gas phase.Dalton transactions, 45 28
Y. Kim, A. Streitwieser (2002)
Basicity of a stable carbene, 1,3-di-tert-butylimidazol-2-ylidene, in THF.Journal of the American Chemical Society, 124 20
M. Eberlin (2007)
Electrospray Ionization Mass Spectrometry: A Major Tool to Investigate Reaction Mechanisms in Both Solution and the Gas PhaseEuropean Journal of Mass Spectrometry, 13
Y. Chu, H. Deng, Jin‐Pei Cheng (2007)
An acidity scale of 1,3-dialkylimidazolium salts in dimethyl sulfoxide solution.The Journal of organic chemistry, 72 20
M. Hopkinson, C. Richter, M. Schedler, F. Glorius (2014)
An overview of N-heterocyclic carbenesNature, 510
Erik Couzijn, Eva Zocher, A. Bach, Peter Chen (2010)
Gas-phase energetics of reductive elimination from a palladium(II) N-heterocyclic carbene complex.Chemistry, 16 18
E. Alcalde, N. Mesquida, Montserrat Alemany, C. Alvarez-Rúa, S. García‐Granda, P. Pacheco, L. Pérez-García (2002)
Open‐Chain Dications and Betaines with Imidazolium Molecular Motifs: Synthesis and Structural AspectsEuropean Journal of Organic Chemistry, 2002
Gregorio García, M. Atilhan, S. Aparicio (2017)
Simultaneous CO2 and SO2 capture by using ionic liquids: a theoretical approach.Physical chemistry chemical physics : PCCP, 19 7
Ning Wang, Jeehiun Lee (2019)
Gas-Phase and Ionic Liquid Experimental and Computational Studies of Imidazole Acidity and Carbon Dioxide Capture.The Journal of organic chemistry
I. Chiarotto, M. Feroci, G. Sotgiu, A. Inesi (2013)
The dual role of ionic liquid BmimBF4, precursor of N-heterocyclic carbene and solvent, in the oxidative esterification of aldehydesTetrahedron, 69
Lu Lin, Yi Li, Wenting Du, W. Deng (2010)
The NHCs-mediated cross-coupling of aromatic aldehydes with benzyl halides: synthesis of α-aryl ketonesTetrahedron Letters, 51
Jacob Przyojski, H. Arman, Zachary Tonzetich (2013)
NHC Complexes of Cobalt(II) Relevant to Catalytic C–C Coupling ReactionsOrganometallics, 32
Yuan Tian, Jeehiun Lee (2015)
Gas Phase Studies of N-Heterocyclic Carbene-Catalyzed Condensation Reactions.The Journal of organic chemistry, 80 13
A. Mattson, A. Bharadwaj, A. Zuhl, K. Scheidt (2006)
Thiazolium-catalyzed additions of acylsilanes: a general strategy for acyl anion addition reactions.The Journal of organic chemistry, 71 15
A. Arduengo, R. Harlow, Mike Kline (1991)
A stable crystalline carbeneJournal of the American Chemical Society, 113
De-qiang Ma, Yulong Song, C. Fu, Fang Zhang, Yinlong Guo, Xin Huang, Shengming Ma (2018)
E-Selective N-heterocyclic carbene-catalyzed reaction of aldehydes and butadienoates: effect of water and chloroform as the proton shuttleOrganic chemistry frontiers, 5
M. Feroci, I. Chiarotto, G. Forte, A. Inesi (2013)
An electrochemical methodology for the cyclic CO2 “catch and release”. The role of the electrogenerated N-heterocyclic carbene in BMIm-BF4Journal of CO 2 Utilization, 2
Nick Polfer (2011)
Infrared multiple photon dissociation spectroscopy of trapped ions.Chemical Society reviews, 40 5
Darrin Flanigan, Fedor Romanov-Michailidis, Nicholas White, T. Rovis (2015)
Organocatalytic Reactions Enabled by N-Heterocyclic Carbenes.Chemical reviews, 115 17
Oldamur Hollóczki, D. Gerhard, Klemens Massone, László Szarvas, Balázs Németh, T. Veszprémi, L. Nyulászi (2010)
Carbenes in ionic liquidsNew Journal of Chemistry, 34
D. Lavorato, Thomas Dargel, W. Koch, G. McGibbon, H. Schwarz, J. Terlouw (2001)
Pyrimidine-ylidenes produced using neutralization–reionization mass spectrometry and probed by density functional methodsInternational Journal of Mass Spectrometry, 210
Krista Vikse, J. McIndoe (2015)
Mechanistic insights from mass spectrometry: examination of the elementary steps of catalytic reactions in the gas phasePure and Applied Chemistry, 87
Y. Kayaki, Masafumi Yamamoto, T. Ikariya (2009)
N-heterocyclic carbenes as efficient organocatalysts for CO2 fixation reactions.Angewandte Chemie, 48 23
C. Adlhart, Peter Chen (2000)
Fishing for Catalysts: Mechanism‐Based Probes for Active Species in SolutionHelvetica Chimica Acta, 83
F. Bernardi, Jackson Scholten, G. Fecher, J. Dupont, J. Morais (2009)
Probing the chemical interaction between iridium nanoparticles and ionic liquid by XPS analysisChemical Physics Letters, 479
A. Kanu, P. Dwivedi, M. Tam, L. Matz, H. Hill (2008)
Ion mobility-mass spectrometry.Journal of mass spectrometry : JMS, 43 1
R. Menon, A. Biju, V. Nair (2016)
Recent advances in N-heterocyclic carbene (NHC)-catalysed benzoin reactionsBeilstein Journal of Organic Chemistry, 12
D. Pasto, J. Freeman (1985)
Electronic and structural requirements for ring opening of azacyclopentadiene carbenesJournal of the American Chemical Society, 107
Weitao Zhu, Yu Yuan, Peng Zhou, Le Zeng, Hua Wang, L. Tang, Bin Guo, Bo Chen (2012)
The Expanding Role of Electrospray Ionization Mass Spectrometry for Probing Reactive Intermediates in SolutionMolecules, 17
R. O'hair (2006)
The 3D quadrupole ion trap mass spectrometer as a complete chemical laboratory for fundamental gas-phase studies of metal mediated chemistry.Chemical communications, 14
G. Cheng, Xiu‐Mei Zhong, Yundong Wu, Xinhao Zhang (2019)
Mechanistic understanding of catalysis by combining mass spectrometry and computation.Chemical communications
S. Nazari, S. Cameron, Michel Johnson, K. Ghandi (2013)
Physicochemical properties of imidazo-pyridine protic ionic liquidsJournal of Materials Chemistry, 1
Mathias Paul, Eric Detmar, Maria Schlangen, M. Breugst, J. Neudörfl, H. Schwarz, A. Berkessel, M. Schäfer (2019)
Intermediates of N-Heterocyclic Carbene (NHC) Dimerization Probed in the Gas Phase by Ion Mobility Mass Spectrometry: C-H⋅⋅⋅:C Hydrogen Bonding Versus Covalent Dimer Formation.Chemistry, 25 10
D. Ringger, Ilia Kobylianskii, D. Serrã, Peter Chen (2014)
Quantitative description of structural effects on the stability of gold(I) carbenes.Chemistry, 20 44
R. Frański, B. Gierczyk, G. Schroeder, Stefan Pieper, A. Springer, M. Linscheid (2007)
Electrospray ionization mass spectrometric study of mercury complexes of N-heterocyclic carbenes derived from 1,2,4-triazolium salt precursorsCentral European Journal of Chemistry, 5
A. Berkessel, Silvia Elfert, Kerstin Etzenbach‐Effers, J. Teles (2010)
Aldehyde umpolung by N-heterocyclic carbenes: NMR characterization of the Breslow intermediate in its keto form, and a spiro-dioxolane as the resting state of the catalytic system.Angewandte Chemie, 49 39
J. Fenn, M. Mann, C. Meng, Shek-Fu Wong, C. Whitehouse (1989)
Electrospray ionization for mass spectrometry of large biomolecules.Science, 246 4926
L. Batiste, Peter Chen (2014)
Coinage-metal mediated ring opening of cis-1,2-dimethoxycyclopropane: trends from the gold, copper, and silver Fischer carbene bond strength.Journal of the American Chemical Society, 136 26
R. Breslow (1958)
On the Mechanism of Thiamine Action. IV.1 Evidence from Studies on Model SystemsJournal of the American Chemical Society, 80
Yue-ting Wang, K. Jin, S. Leopold, Jin Wang, Huo-Lei Peng, M. Platz, J. Xue, D. Phillips, S. Glover, M. Novak (2008)
Characterization of reactive intermediates generated during photolysis of 4-acetoxy-4-aryl-2,5-cyclohexadienones: oxenium ions and aryloxy radicals.Journal of the American Chemical Society, 130 47
R. Alder, L. Chaker, François Paolini (2004)
Bis(diethylamino)carbene and the mechanism of dimerisation for simple diaminocarbenes.Chemical communications, 19
H. Zeng, Kai Wang, Yuan Tian, Yijie Niu, Landon Greene, Zhichao Hu, Jeehiun Lee (2014)
The benzoin condensation: Charge tagging of the catalyst allows for tracking by mass spectrometryInternational Journal of Mass Spectrometry, 369
A. Troiani, G. Petris, F. Pepi, S. Garzoli, C. Salvitti, M. Rosi, A. Ricci (2019)
Base‐Assisted Conversion of Protonated d‐Fructose to 5‐HMF: Searching for Gas‐Phase Green ModelsChemistryOpen, 8
D. Tempel, P. Henderson, Jeffrey Brzozowski, R. Pearlstein, Hansong Cheng (2008)
High gas storage capacities for ionic liquids through chemical complexation.Journal of the American Chemical Society, 130 2
Christiane Knappke, A. Imami, Axel Jacobi von Wangelin (2012)
Oxidative N‐Heterocyclic Carbene CatalysisChemCatChem, 4
Yugen Zhang, J. Chan (2010)
Sustainable chemistry: imidazolium salts in biomass conversion and CO2 fixationEnergy and Environmental Science, 3
A. Mattson, A. Bharadwaj, K. Scheidt (2004)
The thiazolium-catalyzed Sila-Stetter reaction: conjugate addition of acylsilanes to unsaturated esters and ketones.Journal of the American Chemical Society, 126 8
D. Enders, K. Breuer, G. Raabe, J. Runsink, J. Teles, Johann‐Peter Melder, K. Ebel, S. Brode (1995)
Preparation, Structure, and Reactivity of 1,3,4-Triphenyl-4,5-dihydro-1H-1,2,4-triazol-5-ylidene, a New Stable Carbene†Angewandte Chemie, 34
H. Stetter, Manfred Schreckenberg (1973)
A New Method for Addition of Aldehydes to Activated Double BondsAngewandte Chemie, 12
N‐heterocyclic carbenes (NHCs) are key intermediates in a variety of chemical reactions. Owing to their transient nature, the interception and characterization of these reactive species have always been challenging. Similarly, the study of reaction mechanisms in which carbenes act as catalysts is still an active research field. This Minireview describes the contribution of electrospray ionization mass spectrometry (ESI‐MS) to the detection of charge‐tagged NHCs resulting from the insertion of an ionic group into the molecular scaffold. The use of different mass spectrometric techniques, combined with the charge‐tagging strategy, allowed clarification of the involvement of NHCs in archetypal reactions and the study of their intrinsic chemistry.
ChemPlusChem – Wiley
Published: Feb 1, 2021
Keywords: ; ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.