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CF3 Substitution of [Cu(P^P)(bpy)][PF6] Complexes: Effects on Photophysical Properties and Light‐Emitting Electrochemical Cell Performance

CF3 Substitution of [Cu(P^P)(bpy)][PF6] Complexes: Effects on Photophysical Properties and... How did you come to collaborate together?The Basel team has a strong tradition of coordination chemistry linked to materials science, and over the last 20 years, has developed programs applied to sustainable energy. The birth of the extremely fruitful Basel–Valencia collaboration was the EU FP6‐funded HETEROMOLMAT project (2004–2006) on the use of nanocrystalline semiconductor materials for optoelectronic applications. The collaboration pulls together synthetic, materials, and computational chemistries, small‐molecule crystallography and device physics and has matured through EU funded projects (CELLO, HYSENS and LiLo) and projects funded by the Swiss and Spanish national funding agencies.What motivates you for the current project?Solid‐state technologies now dominate in the lighting industry. Our contributions to solid‐state lighting centre on emissive molecular materials for LECs. LECs use ionic materials such as ionic transition metal complexes as the electroluminescent component and offer advantages over OLEDs, having simpler device construction which can be solution processed. Our focus is on achieving sustainable components for devices by using materials based on copper(I) emitters rather than the more established iridium(III) complexes. A success of the Basel–Valencia collaboration is that we work in an iterative manner, feeding performance data back to the synthetic bench for compound optimization. A major challenge is to overcome the trade‐off between luminance and device lifetime. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png ChemPlusChem Wiley

CF3 Substitution of [Cu(P^P)(bpy)][PF6] Complexes: Effects on Photophysical Properties and Light‐Emitting Electrochemical Cell Performance

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Publisher
Wiley
Copyright
© 2018 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2192-6506
eISSN
2192-6506
DOI
10.1002/cplu.201800112
Publisher site
See Article on Publisher Site

Abstract

How did you come to collaborate together?The Basel team has a strong tradition of coordination chemistry linked to materials science, and over the last 20 years, has developed programs applied to sustainable energy. The birth of the extremely fruitful Basel–Valencia collaboration was the EU FP6‐funded HETEROMOLMAT project (2004–2006) on the use of nanocrystalline semiconductor materials for optoelectronic applications. The collaboration pulls together synthetic, materials, and computational chemistries, small‐molecule crystallography and device physics and has matured through EU funded projects (CELLO, HYSENS and LiLo) and projects funded by the Swiss and Spanish national funding agencies.What motivates you for the current project?Solid‐state technologies now dominate in the lighting industry. Our contributions to solid‐state lighting centre on emissive molecular materials for LECs. LECs use ionic materials such as ionic transition metal complexes as the electroluminescent component and offer advantages over OLEDs, having simpler device construction which can be solution processed. Our focus is on achieving sustainable components for devices by using materials based on copper(I) emitters rather than the more established iridium(III) complexes. A success of the Basel–Valencia collaboration is that we work in an iterative manner, feeding performance data back to the synthetic bench for compound optimization. A major challenge is to overcome the trade‐off between luminance and device lifetime.

Journal

ChemPlusChem – Wiley

Published: Jan 1, 2018

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