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Cationic Iron(III) Salt as an Initiator for Radical Cation‐induced [4+2] Cycloaddition

Cationic Iron(III) Salt as an Initiator for Radical Cation‐induced [4+2] Cycloaddition We developed a cationic iron(III) salt initiator for radical cation‐induced [4+2] cycloaddition. Fe(OTf)3 [or Fe(ClO4)3] behaves as a highly active oxidant for both electron‐deficient and electron‐rich dienophiles. The scope of substrates is much broader than with FeCl3 reported previously. With highly active Fe(OTf)3, we demonstrate a formal total synthesis of Heitziamide A. http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Asian Journal of Organic Chemistry Wiley

Cationic Iron(III) Salt as an Initiator for Radical Cation‐induced [4+2] Cycloaddition

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References (67)

Publisher
Wiley
Copyright
© 2020 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim
ISSN
2193-5807
eISSN
2193-5815
DOI
10.1002/ajoc.201900749
Publisher site
See Article on Publisher Site

Abstract

We developed a cationic iron(III) salt initiator for radical cation‐induced [4+2] cycloaddition. Fe(OTf)3 [or Fe(ClO4)3] behaves as a highly active oxidant for both electron‐deficient and electron‐rich dienophiles. The scope of substrates is much broader than with FeCl3 reported previously. With highly active Fe(OTf)3, we demonstrate a formal total synthesis of Heitziamide A.

Journal

Asian Journal of Organic ChemistryWiley

Published: Mar 1, 2020

Keywords: ; ; ; ;

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