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A. Bothner-by, R. Stephens, Ju-Myeong Lee, C. Warren, R. Jeanloz (1984)
Structure determination of a tetrasaccharide: transient nuclear Overhauser effects in the rotating frameJournal of the American Chemical Society, 106
István Timári, L. Szilágyi, K. Kövér (2015)
PSYCHE CPMG-HSQMBC: An NMR Spectroscopic Method for Precise and Simple Measurement of Long-Range Heteronuclear Coupling Constants.Chemistry, 21 40
K. Hu, W. Westler, J. Markley (2011)
Two-dimensional concurrent HMQC-COSY as an approach for small molecule chemical shift assignment and compound identificationJournal of Biomolecular Nmr, 49
reichhaltigen Erfahrungsschatz, spektralen Spriinge, spektakularen Anwendungsfelder (1999)
Methods for Structure Elucidation by High-Resolution NMRZeitschrift für Physikalische Chemie, 212
M. García-Jiménez, S. Gil-Caballero, Á. Canales, J. Jiménez‐Barbero, J. Paz, P. Nieto (2017)
Interactions between a Heparin Trisaccharide Library and FGF-1 Analyzed by NMR MethodsInternational Journal of Molecular Sciences, 18
S. Boros, G. Batta (2016)
Offset‐compensated and zero‐quantum suppressed ROESY provides accurate 1H–1H distances in small to medium‐sized moleculesMagnetic Resonance in Chemistry, 54
Fengli Zhang, R. Brüschweiler (2004)
Indirect covariance NMR spectroscopy.Journal of the American Chemical Society, 126 41
T. Skinner, Timo Reiss, B. Luy, N. Khaneja, S. Glaser (2003)
Application of optimal control theory to the design of broadband excitation pulses for high-resolution NMR.Journal of magnetic resonance, 163 1
M. Foroozandeh, R. Adams, M. Nilsson, G. Morris (2014)
Ultrahigh-resolution total correlation NMR spectroscopy.Journal of the American Chemical Society, 136 34
E. Kupče, O. Sørensen (2017)
2BOB – extracting an H2BC and an HSQC‐type spectrum from the same data set, and H2OBC – a fast experiment delineating the protonated 13C backboneMagnetic Resonance in Chemistry, 55
B. Luy, K. Kobzar, T. Skinner, N. Khaneja, S. Glaser (2005)
Construction of universal rotations from point-to-point transformations.Journal of magnetic resonance, 176 2
Jean-Marl Böhlen, Martial Rey, G. Bodenhausen (1989)
Refocusing with chirped pulses for broadband excitation without phase dispersionJournal of Magnetic Resonance, 84
J. Jeener, B. Meier, P. Bachmann, R. Ernst (1979)
Investigation of exchange processes by two‐dimensional NMR spectroscopyJournal of Chemical Physics, 71
L. Lerner, A. Bax (1986)
Sensitivity-enhanced two-dimensional heteronuclear relayed coherence transfer NMR spectroscopyJournal of Magnetic Resonance, 69
G. Bodenhausen, D. Ruben (1980)
Natural abundance nitrogen-15 NMR by enhanced heteronuclear spectroscopyChemical Physics Letters, 69
M. Foroozandeh, R. Adams, Nicola Meharry, D. Jeannerat, M. Nilsson, G. Morris (2014)
Ultrahigh-Resolution NMR Spectroscopy**Angewandte Chemie (International Ed. in English), 53
T. Skinner, Timo Reiss, B. Luy, N. Khaneja, S. Glaser (2004)
Reducing the duration of broadband excitation pulses using optimal control with limited RF amplitude.Journal of magnetic resonance, 167 1
M. Herczeg, L. Lázár, Z. Bereczky, K. Kövér, István Timári, J. Kappelmayer, A. Lipták, S. Antus, A. Borbás (2012)
Synthesis and anticoagulant activity of bioisosteric sulfonic-Acid analogues of the antithrombin-binding pentasaccharide domain of heparin.Chemistry, 18 34
P. Kiraly, R. Adams, Liladhar Paudel, M. Foroozandeh, J. Aguilar, István Timári, M. Cliff, M. Nilsson, P. Sándor, G. Batta, J. Waltho, K. Kövér, G. Morris (2015)
Real-time pure shift 15N HSQC of proteins: a real improvement in resolution and sensitivityJournal of Biomolecular Nmr, 62
Sebastian Ehni, B. Luy (2013)
BEBE(tr) and BUBI: J-compensated concurrent shaped pulses for 1H-13C experiments.Journal of magnetic resonance, 232
R. Brüschweiler, Fengli Zhang (2004)
Covariance nuclear magnetic resonance spectroscopy.The Journal of chemical physics, 120 11
U. Piantini, O. Sørensen, R. Ernst (1982)
Multiple quantum filters for elucidating NMR coupling networksJournal of the American Chemical Society, 104
Az Euphorbia taurinensis diterpénjeinek szerkezetmeghatározása NMRspkektroszkópiával
L. Lázár, M. Herczeg, Anikó Fekete, A. Borbás, A. Lipták, S. Antus (2010)
Synthesis of sulfonic acid analogues of the non-reducing end trisaccharide of the antithrombin binding domain of heparinTetrahedron Letters, 51
Liladhar Paudel, R. Adams, P. Kiraly, J. Aguilar, M. Foroozandeh, M. Cliff, M. Nilsson, P. Sándor, J. Waltho, G. Morris (2013)
Simultaneously Enhancing Spectral Resolution and Sensitivity in Heteronuclear Correlation NMR Spectroscopy**Angewandte Chemie (International Ed. in English), 52
Farmakognóziai Intézet 12:30 Mennyi az annyi -néhány 2D mérés finomparaméterezése Boros Sándor*, Balogh Mária Vichem Chemie Kutató Kft
M. Garwood, Y. Ke (1991)
Symmetric pulses to induce arbitrary flip angles with compensation for rf inhomogeneity and resonance offsetsJournal of Magnetic Resonance, 94
Jean-Marl Böhlen, I. Burghardt, Martial Rey, G. Bodenhausen (1990)
Frequency-modulated “Chirp” pulses for broadband inversion recovery in magnetic resonanceJournal of Magnetic Resonance, 90
Szymon Buda, Mirosław Nawój, J. Młynarski (2016)
Recent Advances in NMR Studies of CarbohydratesAnnual reports on NMR spectroscopy, 89
Martin Koos, Grit Kummerlöwe, Lukas Kaltschnee, Christine Thiele, B. Luy (2016)
CLIP‐COSY: Reine Inphase‐Signale und schnelle Akquisition COSY‐artiger KorrelationenAngewandte Chemie, 128
K. Kobzar, T. Skinner, N. Khaneja, S. Glaser, B. Luy (2008)
Exploring the limits of broadband excitation and inversion: II. Rf-power optimized pulses.Journal of magnetic resonance, 194 1
A. Davis, J. Keeler, E. Laue, D. Moskau (1992)
Experiments for recording pure-absorption heteronuclear correlation spectra using pulsed field gradientsJournal of Magnetic Resonance, 98
W. Bubb (2003)
NMR spectroscopy in the study of carbohydrates: Characterizing the structural complexityConcepts in Magnetic Resonance Part A, 19
V. Kakita, R. Hosur (2016)
Non-Uniform-Sampling Ultrahigh Resolution TOCSY NMR: Analysis of Complex Mixtures at Microgram Levels.Chemphyschem : a European journal of chemical physics and physical chemistry, 17 15
J. Schmidt, O. Sørensen, R. Ernst (1994)
Measurement of homonuclear long-range J couplings by relayed E. COSYJournal of Magnetic Resonance, Series A, 109
L. Lázár, Erika Mező, M. Herczeg, A. Lipták, S. Antus, A. Borbás (2012)
Synthesis of the non-reducing end trisaccharide of the antithrombin-binding domain of heparin and its bioisosteric sulfonic acid analoguesTetrahedron, 68
Martin Koos, G. Kummerlöwe, L. Kaltschnee, C. Thiele, B. Luy (2016)
CLIP-COSY: A Clean In-Phase Experiment for the Rapid Acquisition of COSY-type Correlations.Angewandte Chemie, 55 27
J. Duus, C. Gotfredsen, K. Bock (2000)
Carbohydrate structural determination by NMR spectroscopy: modern methods and limitations.Chemical reviews, 100 12
M. Thrippleton, J. Keeler (2003)
Elimination of zero-quantum interference in two-dimensional NMR spectra.Angewandte Chemie, 42 33
G. Eich, G. Bodenhausen, R. Ernst (1982)
Exploring nuclear spin systems by relayed magnetization transferJournal of the American Chemical Society, 104
N. Nyberg, J. Duus, O. Sørensen (2005)
Heteronuclear two-bond correlation: suppressing heteronuclear three-bond or higher NMR correlations while enhancing two-bond correlations even for vanishing 2J(CH).Journal of the American Chemical Society, 127 17
K. Kobzar, T. Skinner, N. Khaneja, S. Glaser, B. Luy (2004)
Exploring the limits of broadband excitation and inversion pulses.Journal of magnetic resonance, 170 2
L. Braunschweiler, R. Ernst (1983)
Coherence transfer by isotropic mixing: Application to proton correlation spectroscopyJournal of Magnetic Resonance, 53
N. Gershenzon, T. Skinner, B. Brutscher, N. Khaneja, Manoj Nimbalkar, B. Luy, S. Glaser (2008)
Linear phase slope in pulse design: application to coherence transfer.Journal of magnetic resonance, 192 2
N. Nyberg, J. Duus, O. Sørensen (2005)
Editing of H2BC NMR spectraMagnetic Resonance in Chemistry, 43
R. Staewen, ANTON Johnson, BRIAN Ross, Todd Parrish, H. Merkle, Michael Garwood (1990)
3-D FLASH imaging using a single surface coil and a new adiabatic pulse, BIR-4.Investigative radiology, 25 5
Novel CLIP‐COSY based homo‐ and heteronuclear correlation experiments are reported for the rapid, semi‐automated NMR assignment of small to medium‐sized molecules. The homonuclear CLIP‐COSY and corresponding relayed experiments employ the perfect‐echo based mixing sequence for in‐phase coherence transfer between directly and/or indirectly coupled proton spins. The combined analysis of the resulting CLIP‐COSY and relayed spectra made it possible to easily track down, layer by layer, the proton–proton connectivity network. In larger molecules the narrow chemical shift range of protons may, however, compromise the efficacy of the homonuclear correlation based assignment strategy. To overcome this limitation, an HSQC variant of the CLIP‐COSY experiment has now been devised. Combined treatment of HSQC‐CLIP‐COSY (relayed) and standard HSQC spectra facilitates simultaneous and semi‐automatic assignment of 1H and 13C resonances of medium‐sized molecules, such as pentasaccharides. The recently introduced PSYCHE broadband homonuclear decoupling scheme has been also implemented into the devised homo‐ and heteronuclear CLIP‐COSY based experiments, resulting in fully decoupled high‐resolution pure‐shift correlation spectra.
ChemPlusChem – Wiley
Published: Jan 1, 2018
Keywords: ; ; ;
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