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Heteroatom Chemistry Volume 1, Number 4, 1990 Joyce Y. Corey, Book Review Editor LITHIUM CHEMISTRY olithium reagents including the standard methods: reaction of an organic halide with lithium, metal Organollthium Methods. By B. J. Wakefield. Aca halogen exchange, and metallation (12 worked-out demic Press, New York. 1988. $62.00. examples including one lithium enolate). Examples Preparative Polar Organometallic Chemistry 1. By of lesser strategies are also presented including the L. Brandsma and H. Verkruijsse. Springer-Verlag: use of lithium salts of radical anions, transmetal lation, and preparation from ethers, thioethers, and New York. 1987. $45.00. sulphonylhydrazones (7 preparations). Six tables in The synthetic chemist, regardless of area of em this chapter provide additional examples, and each general method includes many references for re phasis, will eventually require the use of an orga noalkali reagent in a reaction. Reliable and repro lated systems. ducible methods for a specific reagent are not always Chapters 4 through 7 deal with the addition of obvious or available. In the published literature de organolithium reagents to carbon-element multiple tails of a particular synthesis are often implied or bonds (C=C, C=N, C=O and C=S). Chapters 8 are automatic to the expert organometallic chem and 9 discuss alkylation
Heteroatom Chemistry – Wiley
Published: Jan 1, 1990
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