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BOOK REVIEW

BOOK REVIEW Heteroatom Chemistry Volume 1, Number 4, 1990 Joyce Y. Corey, Book Review Editor LITHIUM CHEMISTRY olithium reagents including the standard methods: reaction of an organic halide with lithium, metal­ Organollthium Methods. By B. J. Wakefield. Aca­ halogen exchange, and metallation (12 worked-out demic Press, New York. 1988. $62.00. examples including one lithium enolate). Examples Preparative Polar Organometallic Chemistry 1. By of lesser strategies are also presented including the L. Brandsma and H. Verkruijsse. Springer-Verlag: use of lithium salts of radical anions, transmetal­ lation, and preparation from ethers, thioethers, and New York. 1987. $45.00. sulphonylhydrazones (7 preparations). Six tables in The synthetic chemist, regardless of area of em­ this chapter provide additional examples, and each general method includes many references for re­ phasis, will eventually require the use of an orga­ noalkali reagent in a reaction. Reliable and repro­ lated systems. ducible methods for a specific reagent are not always Chapters 4 through 7 deal with the addition of obvious or available. In the published literature de­ organolithium reagents to carbon-element multiple tails of a particular synthesis are often implied or bonds (C=C, C=N, C=O and C=S). Chapters 8 are automatic to the expert organometallic chem­ and 9 discuss alkylation http://www.deepdyve.com/assets/images/DeepDyve-Logo-lg.png Heteroatom Chemistry Wiley

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Publisher
Wiley
Copyright
© Wiley Periodicals, Inc.
ISSN
1042-7163
eISSN
1098-1071
DOI
10.1002/hc.1990.1.4.349
Publisher site
See Article on Publisher Site

Abstract

Heteroatom Chemistry Volume 1, Number 4, 1990 Joyce Y. Corey, Book Review Editor LITHIUM CHEMISTRY olithium reagents including the standard methods: reaction of an organic halide with lithium, metal­ Organollthium Methods. By B. J. Wakefield. Aca­ halogen exchange, and metallation (12 worked-out demic Press, New York. 1988. $62.00. examples including one lithium enolate). Examples Preparative Polar Organometallic Chemistry 1. By of lesser strategies are also presented including the L. Brandsma and H. Verkruijsse. Springer-Verlag: use of lithium salts of radical anions, transmetal­ lation, and preparation from ethers, thioethers, and New York. 1987. $45.00. sulphonylhydrazones (7 preparations). Six tables in The synthetic chemist, regardless of area of em­ this chapter provide additional examples, and each general method includes many references for re­ phasis, will eventually require the use of an orga­ noalkali reagent in a reaction. Reliable and repro­ lated systems. ducible methods for a specific reagent are not always Chapters 4 through 7 deal with the addition of obvious or available. In the published literature de­ organolithium reagents to carbon-element multiple tails of a particular synthesis are often implied or bonds (C=C, C=N, C=O and C=S). Chapters 8 are automatic to the expert organometallic chem­ and 9 discuss alkylation

Journal

Heteroatom ChemistryWiley

Published: Jan 1, 1990

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