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An N‐methylmorpholine‐catalyzed aminotrifluoromethylthiolation of electron‐withdrawing alkynes leads to α,β‐unsaturated esters bearing a nitrogen and SCF3 groups. Here, N‐trifluoromethylthiophthalimide serves as both the nitrogen and the SCF3 source. This difunctionalization reaction features mild reaction conditions, high atom economy, good yield (up to 93%) and excellent stereoselectivity (Z/E up to 28 : 1). This study provides a versatile approach for the synthesis of −SCF3‐containing molecules (i. e. α‐SCF3‐β‐amino acids).
Asian Journal of Organic Chemistry – Wiley
Published: Sep 1, 2018
Keywords: ; ; ; ;
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