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Bernhardt (1986)
The chemical composition of natural cylindritesN. Jb. Miner. Abh., 153
Coulon (1961)
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Mosburg Mosburg, Ross Ross, Betheke Betheke, Toulmin Toulmin (1961)
X‐ray powder data for herzenbergite, teallite, and trisulfideU.S. Geol. Surv., Prof. Paper
Wang Wang (1982)
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Amthauer (1986)
Crystal chemistry and valencies of iron, antimony and tin in franckeitesN. Jb. Miner. Abh., 153
Bernhardt (1984)
The composition of natural franckeiteN. Jb. Miner. Abh., 150
Jiuling Jiuling (1986)
Cylindrite syntheses and relation to franckeiteN. Jb. Miner. Abh., 153
Makovicky Makovicky (1976)
Crystallography of cylindrite. Part 1: Crystal lattices of cylindrite and incaiteN. Jb. Miner. Abh., 126
Abstract Experimental studies on the two solid solutions franckeite s.s. and cylindrite s.s. yielded among others the Pb‐free endmembers of franckeite and cylindrite respectively. In these endmembers the lead content of the two mineral phases are completely substituted by bivalent tin. A third phase, ottemannite s.s. with (Fe, Sb)‐bearing compositions, was further identified in the Pb‐free 4‐component system Fe‐Sn‐Sb‐S. Pb‐free franckeite and cylindrite could only be synthesized as homogeneous phases at high temperatures. The ottemannite s.s. was obtained at 600°C but an extensive existing range was also confirmed at temperatures below 500°C. The phase relations were discussed in the pseudoternary subsystem SnS‐SnS2‐FeSb2S4. The following sequence of Pb‐ free phases and phase assemblages were observed under increasing Sn4+ content at 600°C : herzenbergite (SnS)+franckeite, franckeite, franckeite+cylindrite, cylindrite, cylindrite+(Fe, Sb)‐ottemannite, (Fe, Sb)‐ottemannite, (Fe, Sb)‐ ottemannite+berndtite (SnS2). The assemblage cylindrite+berndtite was identified in synthetic systems involving Pb. The phase Fe, Sb‐ottemannite s.s. appears to be stable only under Pb‐de‐ficient and high sulfur fugacity conditions.
Acta Geologica Sinica (English Edition) – Wiley
Published: Dec 1, 1988
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