Access the full text.
Sign up today, get DeepDyve free for 14 days.
Jeon H. B. (2014)
10.1016/j.tetlet.2014.05.080Tetrahedron, 55
Surur A. S. (2018)
10.1002/ardp.201800248Arch. Pharm., 352
Brinshma J. (2001)
10.1016/S0040-4039(01)00626-8Tetrahedron Lett., 42
Hetzel D. J. (1998)
10.1016/0016-5085(88)90162-XGastroenterology, 95
Capaldo L. (2022)
10.1021/acs.chemrev.1c00263Chem. Rev., 122
Dell’ Anna M. M. (1996)
10.1016/1381-1169(95)00302-9J. Mol. Catal. A, 108
Zhang H. (2014)
10.1016/j.tetlet.2013.10.102Tetrahedron, 55
Zhang B. (2015)
10.1016/j.jcat.2015.08.029J. Catal., 323
Sulfoxides constitute one of the most important functional groups in organic chemistry found in numerous pharmaceuticals and natural products. Sulfoxides are usually obtained from the oxidation of the corresponding sulfides. Among various oxidants, oxygen or air are considered the greenest and most sustainable reagent. Photochemistry and photocatalysis is increasingly applied in new, as well as traditional, yet demanding, reaction, like the aerobic oxidation of sulfides to sulfoxides, since photocatalysis has provided the means to access them in mild and effective ways. In this review, we will summarize the photochemical protocols that have been developed for the oxidation of sulfides to sulfoxides, employing air or oxygen as the oxidant. The aim of this review is to present: i) a historical overview, ii) the key mechanistic studies and proposed mechanisms and iii) categorize the different catalytic systems in literature.
ChemPlusChem – Wiley
Published: Apr 1, 2022
Keywords: aerobic oxidations; green chemistry; photocatalysis; photochemistry; sulfoxides
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.