Access the full text.
Sign up today, get DeepDyve free for 14 days.
A. Weber, M. Mench, J. Meyers, P. Ross, J. Gostick, Qinghua Liu (2011)
Redox flow batteries: a reviewJournal of Applied Electrochemistry, 41
Xin Xu, Haining Wang, Shanfu Lu, Si-kan Peng, Yan Xiang (2016)
A phosphotungstic acid self-anchored hybrid proton exchange membrane for direct methanol fuel cellsRSC Advances, 6
Zhizhang Yuan, Yinqi Duan, Hongzhang Zhang, Xianfeng Li, Huamin Zhang, I. Vankelecom (2016)
Advanced porous membranes with ultra-high selectivity and stability for vanadium flow batteriesEnergy and Environmental Science, 9
L. Zeng, T. Zhao, Lei Wei, Yikai Zeng, Zhihui Zhang (2016)
Highly stable pyridinium-functionalized cross-linked anion exchange membranes for all vanadium redox flow batteriesJournal of Power Sources, 331
Xuelong Zhou, T. Zhao, L. An, Yikai Zeng, Xingbao Zhu (2016)
Performance of a vanadium redox flow battery with a VANADion membraneApplied Energy, 180
Qinglong Tan, Shanfu Lu, Jiangju Si, Haining Wang, Chunxiao Wu, Xianfeng Li, Yan Xiang (2017)
A Bunch-Like Tertiary Amine Grafted Polysulfone Membrane for VRFBs with Simultaneously High Proton Conductivity and Low Vanadium Ion Permeability.Macromolecular rapid communications, 38 8
K. Ngamsai, A. Arpornwichanop (2015)
Analysis and measurement of the electrolyte imbalance in a vanadium redox flow batteryJournal of Power Sources, 282
Hongzhang Zhang, Huamin Zhang, Xianfeng Li, Z. Mai, Jianlu Zhang (2011)
Nanofiltration (NF) membranes: the next generation separators for all vanadium redox flow batteries (VRBs)?Energy and Environmental Science, 4
Zhibin Guo, Ruijie Xiu, Shanfu Lu, Xin Xu, Shichun Yang, Yan Xiang (2015)
Submicro-pore containing poly(ether sulfones)/polyvinylpyrrolidone membranes for high-temperature fuel cell applicationsJournal of Materials Chemistry, 3
Wenjing Lu, Xianfeng Li, Huamin Zhang (2017)
The next generation vanadium flow batteries with high power density - a perspective.Physical chemistry chemical physics : PCCP, 20 1
Steffen Hink, Katrine Elsøe, L. Cleemann, D. Henkensmeier, J. Jang, Hyoung‐Juhn Kim, Jonghee Han, S. Nam, Qingfeng Li (2015)
Phosphoric acid doped polysulfone membranes with aminopyridine pendant groups and imidazole cross-linksEuropean Polymer Journal, 72
Zhimin Fu, Jinying Liu, Qifeng Liu (2015)
SPEEK/PVDF/PES Composite as Alternative Proton Exchange Membrane for Vanadium Redox Flow BatteriesJournal of Electronic Materials, 45
Shanfu Lu, L. Zhuang, Juntao Lu (2007)
Homogeneous blend membrane made from poly(ether sulphone) and poly(vinylpyrrolidone) and its application to water electrolysisJournal of Membrane Science, 300
K. Ishikawa, K. Kaneko, Y. Takeoka, M. Rikukawa, K. Sanui, Iko Ito, Y. Kanzaki (2003)
Synthesis of novel proton conducting polymer electrolytes containing phosphoric acidSynthetic Metals
Chi Xu, Xiaofei Yang, Xianfeng Li, Tao Liu, Huamin Zhang (2017)
Ultrathin free-standing electrospun carbon nanofibers web as the electrode of the vanadium flow batteriesJournal of Energy Chemistry, 26
Yuyue Zhao, Mingrun Li, Zhizhang Yuan, Xianfeng Li, Huamin Zhang, I. Vankelecom (2016)
Advanced Charged Sponge‐Like Membrane with Ultrahigh Stability and Selectivity for Vanadium Flow BatteriesAdvanced Functional Materials, 26
Chunxiao Wu, Shanfu Lu, Haining Wang, Xin Xu, Si-kan Peng, Qinglong Tan, Yan Xiang (2016)
A novel polysulfone–polyvinylpyrrolidone membrane with superior proton-to-vanadium ion selectivity for vanadium redox flow batteriesJournal of Materials Chemistry, 4
Qinglong Tan, Shanfu Lu, Yang Lv, Xin Xu, Jiangju Si, Yan Xiang (2016)
Doping structure and degradation mechanism of polypyrrole–Nafion® composite membrane for vanadium redox flow batteriesRSC Advances, 6
M. Dassisti, G. Cozzolino, M. Chimienti, A. Rizzuti, P. Mastrorilli, P. L'Abbate (2016)
Sustainability of vanadium redox-flow batteries: Benchmarking electrolyte synthesis proceduresInternational Journal of Hydrogen Energy, 41
Tao Luo, Oana David, Y. Gendel, Matthias Wessling (2016)
Porous poly(benzimidazole) membrane for all vanadium redox flow batteryJournal of Power Sources, 312
B. Schwenzer, Jianlu Zhang, Soowhan Kim, Liyu Li, Jun Liu, Z. Yang (2011)
Membrane development for vanadium redox flow batteries.ChemSusChem, 4 10
T. Sukkar, M. Skyllas-Kazacos (2003)
Water transfer behaviour across cation exchange membranes in the vanadium redox batteryJournal of Membrane Science, 222
Shanfu Lu, Chunxiao Wu, Da-wei Liang, Qinglong Tan, Yan Xiang (2014)
Layer-by-layer self-assembly of Nafion–[CS–PWA] composite membranes with suppressed vanadium ion crossover for vanadium redox flow battery applicationsRSC Advances, 4
Mette Kristensen, Sofie Haldrup, J. Christensen, J. Catalano, A. Bentien (2016)
Sulfonated poly(arylene thioether sulfone) cation exchange membranes with improved permselectivity/ion conductivity trade-offJournal of Membrane Science, 520
Sangshan Peng, Xiaoming Yan, Daishuang Zhang, Xuemei Wu, Yongliang Luo, G. He (2016)
A H3PO4 preswelling strategy to enhance the proton conductivity of a H2SO4-doped polybenzimidazole membrane for vanadium flow batteriesRSC Advances, 6
Yikai Zeng, T. Zhao, L. An, Xuelong Zhou, Lei Wei (2015)
A comparative study of all-vanadium and iron-chromium redox flow batteries for large-scale energy storageJournal of Power Sources, 300
Daishuang Zhang, Xiaoming Yan, G. He, Le Zhang, Xinhong Liu, Fengxiang Zhang, Mengmeng Hu, Yan Dai, Sangshan Peng (2015)
An integrally thin skinned asymmetric architecture design for advanced anion exchange membranes for vanadium flow batteriesJournal of Materials Chemistry, 3
Bengui Zhang, E. Zhang, Guosheng Wang, Ping Yu, Qiu-xiang Zhao, F. Yao (2015)
Poly(phenyl sulfone) anion exchange membranes with pyridinium groups for vanadium redox flow battery applicationsJournal of Power Sources, 282
J. Weber, K. Kreuer, J. Maier, Arne Thomas (2008)
Proton Conductivity Enhancement by Nanostructural Control of Poly(benzimidazole)‐Phosphoric Acid AdductsAdvanced Materials, 20
Daohui Wang, Xianfeng Li, Qing Li, Zhen Liu, Nana Li, Qinglin Huang, Yufeng Zhang, C. Xiao (2018)
Antioxidation performance of poly(vinyl alcohol) modified poly(vinylidene fluoride) membranesApplied Surface Science, 435
An acid pretreatment strategy is developed to enhance the proton transport of polysulfone‐polyvinylpyrrolidone (PSF‐PVP) membranes for application in vanadium redox flow batteries (VRFB). The acid pretreatment leads to the formation of ionic conducting clusters with a size of around d=15.41 nm in the membrane (p‐PSF‐PVP). As a result, the proton conductivity and proton/vanadium ion selectivity of the p‐PSF‐PVP membrane increases to 6.60×10−2 S cm−1 and 10.63×107 S min cm−3, respectively, values significantly higher than 2.30×10−2 S cm−1 and 6.67×107 S min cm−3 of the pristine PSF‐PVP membrane. Moreover, a VRFB assembled with the p‐PSF‐PVP membrane exhibits a high coulombic efficiency of 98.6 % and an outstanding energy efficiency of 88.5 %. The results indicate that treatment with either sulfuric acid or phosphoric acid leads to an improvement of membrane properties, and the acid pretreatment is a promising strategy to significantly enhance the performance of the PSF‐PVP membrane for VRFB application.
ChemPlusChem – Wiley
Published: Oct 1, 2018
Keywords: ; ; ; ;
Read and print from thousands of top scholarly journals.
Already have an account? Log in
Bookmark this article. You can see your Bookmarks on your DeepDyve Library.
To save an article, log in first, or sign up for a DeepDyve account if you don’t already have one.
Copy and paste the desired citation format or use the link below to download a file formatted for EndNote
Access the full text.
Sign up today, get DeepDyve free for 14 days.
All DeepDyve websites use cookies to improve your online experience. They were placed on your computer when you launched this website. You can change your cookie settings through your browser.